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1. 发明授权

US5145914A Polyacrylate esters with ammonium salt groups 失效
标题翻译：具有氨基酸盐的聚丙烯酸酯
公开(公告)号：US5145914A
公开(公告)日：1992-09-08
申请号：US665778
申请日：1991-03-07
申请人： Eberhard Esselborn , Jurgen Fock , Helmut Lammerting
发明人： Eberhard Esselborn , Jurgen Fock , Helmut Lammerting
IPC分类号： B01F17/52 , C08F8/44 , C08F20/34 , D06M13/02 , D06M13/322 , D06M13/467 , D06M13/47 , D06M13/477 , D06M15/267
CPC分类号： C08F8/44
摘要： Polyacrylate esters with ammonium salt groups obtained by the transesterification of alkyl polyacrylates produced by free radical polymerization are disclosed, wherein the alkyl groups of the acrylate esters have 1 to 8 carbon atoms, up to 50% of the acrylate esters can be replaced by the corresponding methacrylate esters and the transesterification is carried out witha) compounds of the formula ##STR1## b) saturated or unsaturated aliphatic alcohols having 8 to 22 carbon atoms or alkoxylated alkylphenols having 9 to 27 carbon atoms in the alkylphenol group,wherein the molar ratio of component a) to component b) is 1:9 to 9:1, in such amount that 5 to 70% of the ester groups are transesterified and subsequently, the transesterification product is transformed into a salt. The new polyacrylate esters with ammonium salt groups are distinguished by containing a lesser amount of low molecular weight compounds than products obtained through copolymerization and can be used as cationic surfactants and particularly, as active ingredients of metal adjuvants.
摘要翻译：公开了通过通过自由基聚合制备的烷基聚丙烯酸酯的酯交换获得的具有铵盐基团的聚丙烯酸酯，其中丙烯酸酯的烷基具有1至8个碳原子，至多50％的丙烯酸酯可以被相应的甲基丙烯酸酯和酯交换是用下列化合物进行的：a）下式化合物：b）烷基酚基中具有8-22个碳原子的饱和或不饱和脂族醇或具有9至27个碳原子的烷氧基化烷基酚，其中摩尔比组分a）至组分b）为1:9至9:1，其用量为5至70％的酯基酯交换，随后将酯交换产物转化为盐。具有铵盐基团的新的聚丙烯酸酯通过含有比通过共聚获得的产物更少量的低分子量化合物来区分，并且可以用作阳离子表面活性剂，特别是作为金属助剂的活性成分。

2. 发明授权

US5338485A Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups and their use as surface active substances 失效
标题翻译：具有长链烃和聚氧化烯基团的聚丙烯酸酯及其作为表面活性物质的用途
公开(公告)号：US5338485A
公开(公告)日：1994-08-16
申请号：US843912
申请日：1992-02-27
申请人： Jurgen Fock , Eberhard Esselborn , Dietmar Schaefer
发明人： Jurgen Fock , Eberhard Esselborn , Dietmar Schaefer
IPC分类号： B01F17/00 , B01F17/42 , C08F8/14 , C08F20/18 , C08F120/18
CPC分类号： B01F17/0028 , C08F8/14 , C08F2810/30 , Y10S516/06
摘要： Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups are disclosed, which are prepared by transesterification of polyacrylate alkyl esters, the alkyl groups of which have 1 to 4 carbon atoms and which were obtained by free radical polymerization, wherein the transesterification is carried out with a mixture of selected alcohols and polyoxyalkylene monools. Compared to products obtained by copolymerization, the transesterification products are largely free of undesirable low molecular weight components, have a narrow molecular weight distribution and exhibit excellent surfactant properties. They are useful especially as W/O emulsifiers for natural and synthetic oils.
摘要翻译：公开了具有长链烃和聚氧化烯基团的聚丙烯酸酯，其通过聚丙烯酸酯烷基酯（其烷基具有1至4个碳原子并通过自由基聚合获得）的酯交换制备，其中酯交换反应是用选择的醇和聚氧化烯一元醇的混合物。与通过共聚获得的产物相比，酯交换产物大部分没有不期望的低分子量组分，具有窄的分子量分布并且表现出优异的表面活性剂性质。它们特别适用于天然和合成油的W / O乳化剂。

3. 发明授权

US5115039A Polyacrylate esters with quaternary ammonium groups 失效
公开(公告)号：US5115039A
公开(公告)日：1992-05-19
申请号：US711364
申请日：1991-06-05
申请人： Jurgen Fock , Dietmar Schaefer , Eberhard Esselborn
发明人： Jurgen Fock , Dietmar Schaefer , Eberhard Esselborn
IPC分类号： A61K8/00 , A61K8/72 , A61Q5/00 , A61Q5/02 , B01F17/18 , C08F8/02 , C08F8/14 , C08F8/30 , C08F8/32 , C08F8/44 , C08F20/34 , C08F220/34 , C08G81/02 , C09K3/16 , D06M15/267
CPC分类号： A61Q5/02 , A61K8/8152 , A61Q5/12 , C08F8/14 , C08F8/44 , C08F2810/30
摘要： Polyacrylate esters with quaternary ammonium groups are disclosed. The esters are obtained by transesterifying alkyl polyacrylate esters with a mixture of dialkylaminoalkanols and saturated or unsaturated aliphatic alcohols with 8 to 22 carbon atoms, followed by quaternization.The polymers are free of physiologically questionable components and can therefore be used for the preparation of cosmetic products, preferably for hair cosmetics. The polymers furthermore are suitable for finishing fibers or of textile products.The invention is furthermore directed to polyacrylate esters with tertiary amino groups, which are formed as intermediates in the preparation of polyacrylate esters with quaternary ammonium groups.

4. 发明授权

US5693848A .alpha., .omega.-polymethacrylate dicarboxylic acids, their synthesis and use as dicarboxylic acid components for the synthesis or modification of polyesters, polyurethanes or polyepoxides 失效
标题翻译： α，ω-聚甲基丙烯酸酯二羧酸，它们的合成和用作二羧酸组分用于合成或改性聚酯，聚氨酯或聚环氧化物
公开(公告)号：US5693848A
公开(公告)日：1997-12-02
申请号：US544507
申请日：1995-10-18
申请人： Eberhard Esselborn , Jurgen Fock
发明人： Eberhard Esselborn , Jurgen Fock
IPC分类号： C08F2/38 , C08F2/44 , C08F8/00 , C08F8/12 , C08F20/10 , C08F220/10 , C08G18/62 , C08G59/40 , C08G63/00 , C07C321/00
CPC分类号： C08G63/00 , C08F2/38 , C08F8/00 , C08F8/12 , C08F8/44 , C08G18/625 , C08F2800/10 , C08F2800/20 , C08F2810/40
摘要： .alpha.,.omega.-polymethacrylate dicarboxylic acids of the general formula ##STR1## wherein R.sup.1 is an optionally halogenated alkyl group with 1 to 22 carbon atoms, wherein the R1 group can assume different meanings in the polymer molecule, R.sup.2 is the group of a known chain transfer agent, which has a terminal --COOH croup and a has a value not less than 4. The invention furthermore relates to the synthesis of these compounds and their use as sole or partial components for the synthesis or modification of polyepoxides, polyesters, polyamides, alkyd resins or polyurethanes.
摘要翻译： α，ω-聚甲基丙烯酸酯二羧酸，其中R 1是任选卤代的具有1至22个碳原子的烷基，其中R 1基团可以在聚合物分子中具有不同的含义，R 2是已知的链转移基团其具有末端-COOH缩合物并且具有不小于4的值。本发明还涉及这些化合物的合成及其作为用于合成或改性聚环氧化物，聚酯，聚酰胺，醇酸树脂的唯一或部分组分的用途树脂或聚氨酯。

5. 发明授权

US5087687A Polyethers containing perfluoroalkyl groups, methods for their synthesis and their use as surfactants and as polyol components in the preparation of polyurethanes 失效
标题翻译：含有全氟代基团的聚醚，其合成方法及其作为表面活性剂和作为多元醇组分在制备聚氨酯中的用途
公开(公告)号：US5087687A
公开(公告)日：1992-02-11
申请号：US470932
申请日：1990-01-26
申请人： Jurgen Fock , Eberhard Esselborn
发明人： Jurgen Fock , Eberhard Esselborn
IPC分类号： B01F17/42 , C08G18/50 , C08G65/26 , C08G65/331
CPC分类号： C08G65/2639 , C08G18/5015 , C08G65/3312
摘要： Polyethers are disclosed which contain perfluoroalkyl groups and have the average formula ##STR1## wherein R.sup.1 is the same or different in the polymer mixture and represents hydrogen or a fluoro group,n has an average value of 4 to 12,a has an average value of 0 to 4,m has an average value of 2 to 18,x has an average value of 2 to 50 andy has an average value of 0 to 3.A method for the synthesis of the new polyols, which are usefull as surfactants and, with respect to the compounds of formula I, as polyol components in the synthesis of polyurethanes, is also disclosed.
摘要翻译：公开了含有全氟烷基并且具有平均分子式R 1（C n F 2n）（CH 2）a O（C m H 2 m O）x（CH 2）2和R 1（C n F 2n）（CH 2）a O（C m H 2 m O）x（CH 2 II） R1在聚合物混合物中相同或不同，表示氢或氟基，n的平均值为4〜12，a的平均值为0〜4，m的平均值为2〜18，x为平均值为2〜50，y的平均值为0〜3。合成新的多元醇的方法，其可用作表面活性剂，对于式I化合物，作为合成中的多元醇成分的聚氨酯。

6. 发明授权

US4880906A Fiber finishing agents and compositions containing them 失效
公开(公告)号：US4880906A
公开(公告)日：1989-11-14
申请号：US219715
申请日：1988-07-15
申请人： Eberhard Esselborn , Jurgen Fock
发明人： Eberhard Esselborn , Jurgen Fock
IPC分类号： D06M15/19 , D06M15/263 , D06M15/347 , D06M15/53 , D06M15/55
CPC分类号： D06M15/263 , D06M15/19 , D06M15/347 , D06M15/53 , D06M15/55 , D06M2101/06 , D06M2101/28 , D06M2101/32 , D06M2101/34 , D06M2200/00 , D06M2200/11 , D06M2200/25 , D06M2200/50 , Y10T428/2913 , Y10T428/2931
摘要： A finishing agent for finishing fibers or fiber products is disclosed. The agent is a mixture of the following components:(a) 34 to 99% by weight of a polymer of the general formula ##STR1## in which R.sup.1 is a z-hybric aliphatic alcohol, z=2 to 9, m=20 to 75, n=0 to 10, p=0 to 3,(b) 0 to 55% by weight of a copolymer, obtained by copolymerization of(b.sub.1) one mole of a macromonomer of the general formula ##STR2## in which q=5 to 75, r=0 to 10, s=0 to 3, with (b.sub.2) 2 to 12 moles of a vinyl ester of the general formula CH.sub.2 .dbd.CHOCOR.sup.2, in which R.sup.2 is an alkyl group with 1 to 4 carbon atoms,(b.sub.3) 1 to 6 moles of N-vinylpyrrolidone,(b.sub.4) 0 to 6 moles of an acrylate or methacrylate ester of the general formula CH.sub.3 .dbd.CR.sup.3 --COOR.sup.4, in which R.sup.3 .dbd.H or CH.sub.3, R.sup.4 is an alkyl group with 1 to 4 carbon atoms, the quotient of the average molecular weight of the monomer (b.sub.1) and the number of moles of the monomers (b.sub.2), (b.sub.3) and (b.sub.4) being 20 to 500and(c) 1 to 35% by weight of a compound, which is reactive with respect to the oxiran group and brings about the cross linking reaction,the sum of the components (a), (b) and (c) yielding 100% by weight.Especially preferred is a finishing agent mixture of34 to 73% by weight of component (a)24 to 55% by weight of component (b) and2 to 30% by weight of component (c)the sum of components (a), (b) and (c) yielding 100% by weight.The invention also discloses a finishing composition in the form of an aqueous solution comprising 0.1 to 10% by weight of the finishing agent as active ingredient with the remainder being water. A method for fixing fibers and fiber products with the inventive composition is also disclosed.The finishing agent and composition of the invention improve the handle, the hydrophilicity and the soil release of treated textile material. At the same time, the soilability, graying and the tendency to develop electrostatic charges are reduced.

7. 发明授权

US4868262A Copolymers with epoxide groups, their synthesis and use for finishing textile fibers or fiber products 失效
标题翻译：具有环氧基团的共聚物，它们的合成和用于整理纺织纤维或纤维产品的用途
公开(公告)号：US4868262A
公开(公告)日：1989-09-19
申请号：US199001
申请日：1988-05-26
申请人： Eberhard Esselborn , Jurgen Fock
发明人： Eberhard Esselborn , Jurgen Fock
IPC分类号： C08F216/14 , C08F218/04 , C08F290/06 , D06M15/21 , D06M15/347
CPC分类号： D06M15/21 , C08F216/1416 , C08F218/04 , C08F290/062 , D06M15/347 , D06M2101/06 , D06M2101/28 , D06M2101/32 , D06M2101/34 , D06M2200/12
摘要： Copolymers having epoxide groups are disclosed which are obtained by the copolymerization of(a.sub.1) one mole of a macromonomer of the general formula ##STR1## in which m=5 to 75, n=0 to 10 and p=0 to 3; (a.sub.2) 2 to 12 moles of a vinyl ester of the general formula CH.sub.2 .dbd.CHOCOR.sup.1, wherein R.sup.1 is an alkyl group with 1 to 4 carbon atoms;(a.sub.3) 0 to 6 moles of N-vinylpyrrolidone; and(a.sub.4) 0 to 6 moles of an acrylate or methacrylate ester of the general formula CH.sub.2 .dbd.CR.sup.2 --COOR.sup.3, wherein R.sup.2 =H or CH.sub.3, R.sup.3 =alkyl with 1 to 4 carbon atoms, the quotient formed from the average molecular weight of monomer (a.sub.1) and the sum of the number of moles of the monomers (a.sub.2), (a.sub.3) and (a.sub.4) being 20 to 500.The invention moreover relates to the synthesis of these copolymers by copolymerization of appropriate comonomer mixture and to the use of the copolymers for finishing textile fibers or fiber products.
摘要翻译：公开了具有环氧基团的共聚物，其通过（a1）1摩尔通式为“IMAGE”的大分子单体（其中m = 5至75，n = 0至10和p = 0至3）的共聚获得; （a2）2〜12摩尔通式CH 2 = CHOCOR 1的乙烯基酯，其中R 1是具有1至4个碳原子的烷基; （a3）0〜6摩尔N-乙烯基吡咯烷酮; 和（a4）0至6摩尔通式CH 2 = CR 2 -COOR 3的丙烯酸酯或甲基丙烯酸酯，其中R 2 = H或CH 3，R 3 =具有1至4个碳原子的烷基，所述商由平均分子量单体（a1）和单体（a2），（a3）和（a4）的摩尔数之和为20-500。本发明还涉及通过合适的共聚单体混合物与使用共聚物来整理纺织纤维或纤维制品。

8. 发明授权

US5990245A .alpha., .omega.-polymethacrylate glycols, methods for their synthesis and their use for the preparation of polymers, particularly polyurethanes and polyesters 失效
标题翻译： α，ω-聚甲基丙烯酸酯二醇，其合成方法及其用于制备聚合物，特别是聚氨酯和聚酯的用途
公开(公告)号：US5990245A
公开(公告)日：1999-11-23
申请号：US936154
申请日：1997-09-24
申请人： Eberhard Esselborn , Jurgen Fock
发明人： Eberhard Esselborn , Jurgen Fock
IPC分类号： C08F2/42 , C08F8/14 , C08F20/18 , C08F20/22 , C08F220/10 , C08G18/62 , C08G59/14 , C08G63/00 , C08G63/49 , C08G63/66 , C08G63/91 , C08L63/00 , C08L67/08 , C08L71/02
CPC分类号： C08F8/14 , C08G18/6245 , C08G63/00 , C08L63/00 , C08L67/08 , C08L71/02 , C08F2810/40
摘要： .alpha., .omega.-polymethacrylate glycols of the general formula ##STR1## are prepared and a method for their synthesis and their use as only or partial glycol component for the preparation of polyesters and polyurethanes and for the modification of alkyd and epoxide resins are described.
摘要翻译：制备通式的α，ω-聚甲基丙烯酸酯二醇及其合成方法及其作为仅用于制备聚酯和聚氨酯的部分二醇组分和用于醇酸树脂和环氧树脂改性的方法。

9. 发明授权

US5571872A Polymethacrylate esters, the ester groups of which in the .alpha. and optionally also in the .omega. position differ from the ester groups in the chain 失效
标题翻译：聚甲基丙烯酸酯，其酯基在α和任选地也在ω位置不同于链中的酯基
公开(公告)号：US5571872A
公开(公告)日：1996-11-05
申请号：US589031
申请日：1996-01-19
申请人： Eberhard Esselborn , Jurgen Fock
发明人： Eberhard Esselborn , Jurgen Fock
IPC分类号： C08F2/42 , C08F8/14 , C08F8/30 , C08F20/10 , C08F20/12
CPC分类号： C08F8/14 , C08F8/30 , C08F2810/30 , C08F2810/40
摘要： Novel polymethacrylate esters are prepared; the ester groups of which in the .alpha. and optionally also in .omega. the position differ from the ester groups in the chain. The invention furthermore relates to a method for the synthesis of these compounds by transesterification under selected method conditions.
摘要翻译：制备新型聚甲基丙烯酸酯; 其中α基团的酯基和任选的ω位置与链中的酯基不同。本发明还涉及通过在选择的方法条件下酯交换合成这些化合物的方法。

10. 发明授权

US5296573A Polyacrylate ester with long-chain alkoxylated hydrocarbonoxy groups and their use in cosmetics and personal grooming 失效
标题翻译：具有长链烷氧基化烃氧基的聚丙烯酸酯酯及其在化妆品和个人修饰中的应用
公开(公告)号：US5296573A
公开(公告)日：1994-03-22
申请号：US648725
申请日：1991-01-31
申请人： Eberhard Esselborn , Jurgen Fock , Gotz Koerner , Dietmar Schaefer
发明人： Eberhard Esselborn , Jurgen Fock , Gotz Koerner , Dietmar Schaefer
IPC分类号： B01F17/52 , C08F8/14 , C08F20/26 , C08G81/02 , C08F220/26 , C08F220/28
CPC分类号： A61Q5/02 , A61K8/86 , C08F8/14 , C08G81/025 , C08F2810/30
摘要： Polyacrylate esters with long-chain alkoxylated hydrocarbonoxy groups are disclosed which can be obtained by the transesterification of polyacrylate esters with polyoxyalkylene monools, wherein the polyacrylate esters, up to 50% of which can be replaced by the corresponding methacrylate esters, have been obtained by free radical polymerization and wherein the polyoxyalkylene monools have the average formulaR.sup.1 O(C.sub.n H.sub.2n O--).sub.x HwhereinR.sup.1 is an alkyl, alkenyl or alkylphenyl group,n has an absolute value of 2, 3 or 4 and an average value of 2.0 to 2.5 andx is 10 to 200.The compounds, which can be used as emulsifiers, solubilizers and for thickening aqueous solutions which contain anionic surfactants, particularly in cosmetics and for personal grooming, are distinguished by a content of low molecular weight components, which is smaller compared to that of products obtained by copolymerization.
摘要翻译：公开了具有长链烷氧基化烃氧基的聚丙烯酸酯，其可通过聚丙烯酸酯与聚氧化烯一醇的酯交换获得，其中至多50％可被相应的甲基丙烯酸酯代替的聚丙烯酸酯已经通过游离自由基聚合，其中聚氧化烯一元醇具有平均式R1O（CnH2nO-）xH，其中R1是烷基，烯基或烷基苯基，n的绝对值为2,3或4，平均值为2.0至2.5，x为可用作乳化剂，增溶剂和含有阴离子表面活性剂，特别是化妆品中和用于个人修饰的阴离子表面活性剂的水溶液的化合物的特征在于低分子量组分的含量比其低的共聚产物。

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