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1. 发明申请

US20160115347A1 RESOLE PHENOLIC RESINS CURABLE WITH FUNCTIONAL POLYESTERS 审中-公开
标题翻译： RESOLE PHENOLIC RESINS可固化功能性聚酯
公开(公告)号：US20160115347A1
公开(公告)日：2016-04-28
申请号：US14922846
申请日：2015-10-26
申请人： Eastman Chemical Company
发明人： Thauming Kuo , Junjia Liu , Phillip Bryan Hall
IPC分类号： C09D167/02 , C08L67/02 , C08L61/06 , C08G8/08
CPC分类号： C08L61/06 , C08G8/08 , C08G8/36 , C09D161/06 , C09D161/14 , C09D167/00 , C08L61/04 , C08L67/00
摘要： This invention relates to a resole phenolic resin comprising the residues of (a) from about 50 to 100 mole % of a meta-substituted phenol [phenolic component (a)], (b) from 0 to about 50 mole % of at least one phenolic component [phenolic component (b)] other than said meta-substituted phenol, and (c) from about 150 to about 300 mole % of at least one aldehyde, wherein the mole percentages of said phenolic components (a) and (b) are based on the total moles of phenolic components (a) and (b); wherein the mole percentages of said aldehyde component is based on the total moles of said phenolic components (a) and (b), and wherein said resole phenolic resin is soluble in an organic solvent and curable with a functional polyester.
摘要翻译：本发明涉及一种甲阶酚醛树脂，其包含（a）约50-100摩尔％的间位取代的酚[酚组分（a）]，（b）0至约50摩尔％的至少一种酚类成分（酚类成分（b）），以及（c）约150〜约300摩尔％的至少一种醛，其中所述酚成分（a）和（b）的摩尔百分数基于酚类组分（a）和（b）的总摩尔数; 其中所述醛组分的摩尔百分比是基于所述酚类组分（a）和（b）的总摩尔数，并且其中所述甲阶酚醛树脂可溶于有机溶剂中并且可用官能聚酯固化。

2. 发明授权

US09487619B2 Carboxyl functional curable polyesters containing tetra-alkyl cyclobutanediol 有权
标题翻译：含有四烷基环丁二醇的羧基官能的可固化聚酯
公开(公告)号：US09487619B2
公开(公告)日：2016-11-08
申请号：US14524509
申请日：2014-10-27
申请人： Eastman Chemical Company
发明人： Thauming Kuo , Junjia Liu , Phillip Bryan Hall
IPC分类号： C08G64/00 , C08G63/199 , C08G63/78 , C09D167/02 , C08G63/02 , C08K5/17
CPC分类号： C08G63/199 , C08G63/78 , C08K5/17 , C09D167/02
摘要： A curable polyester resin composition containing residues of: a) polyhydroxyl compounds that include: (i) 2,2,4,4-tetraalkylcyclobutane-1,3-diol (TACD) compounds, and (ii) polyhydroxyl compounds other than TACD, and (b) polycarboxylic acid compounds that include: (i) polycarboxylic acid compounds, a derivative of polycarboxylic acid compound other than (bii), or a combination thereof, and (ii) a polycarboxylic anhydride compound; wherein the curable polyester resin has an acid number ranging from about 20 to about 120 mg KOH/g, a hydroxyl number ranging from greater than 0 to about 100 mg KOH/g, and an acid number:hydroxyl (AN:OH) number ratio of at least 0.5:1. The curable polyester resin can be dispersed in water or a solvent and is suitable for waterborne or solventborne coating compositions and powder coating applications. Phenolic based crosslinking coating compositions that contain these curable polyester resins are curable at elevated temperatures.

3. 发明申请

US20160115345A1 CURABLE POLYESTERS AND THERMOSETTING COMPOSTIONS CONTAINING RESOLE PHENOLIC RESINS 审中-公开
标题翻译：可固化聚酯和含有酚醛树脂的热固化组合物
公开(公告)号：US20160115345A1
公开(公告)日：2016-04-28
申请号：US14683278
申请日：2015-04-10
申请人： Eastman Chemical Company
发明人： Thauming Kuo , Junjia Liu , Phillip Bryan Hall
IPC分类号： C09D167/02 , B05D1/02 , B05D1/28 , C09D171/00
CPC分类号： B05D1/28 , C09D167/06 , C08L61/04
摘要： There is now provided a variety of curable polyester resins that cure well with phenolic crosslinking agents. The curable polyester resins include polyester resins that have both carboxyl and hydroxyl functionalities and a high ratio of carboxyl functionalities to hydroxyl functionalities; unsaturated curable polyester having residues of an α,β-unsaturated polycarboxylic acid compound with at least one unsaturation in a position that is α,β relative to a carbonyl group and not located on an aromatic ring; and a curable polyester resin containing beta-ketoacetate moieties without vinyl unsaturation. The curable polyester resin can be dispersed in water or dissolved in a solvent and is suitable for waterborne or solventborne coating compositions. Phenolic based crosslinking coating compositions that contain these curable polyester resins cure well with phenolic resin crosslinking compounds with a wide variety of reactive curable polyester resins or other kinds of polyester resins.
摘要翻译：现在提供了多种可固化的聚酯树脂，其与酚交联剂良好地固化。可固化聚酯树脂包括具有羧基和羟基官能团以及羧基官能团与羟基官能团的高比例的聚酯树脂; 不饱和固化性聚酯，其具有在α，bgr的位置具有至少一个不饱和键的α，β-不饱和多元羧酸化合物的残基; 相对于羰基而不位于芳环上; 和含有不具有乙烯基不饱和键的β-酮乙酸酯部分的可固化聚酯树脂。可固化聚酯树脂可以分散在水中或溶于溶剂中，适用于水性或溶剂型涂料组合物。含有这些可固化聚酯树脂的酚醛交联涂料组合物与各种反应性固化聚酯树脂或其它类型的聚酯树脂的酚醛树脂交联化合物很好地固化。

4. 发明申请

US20180298224A1 PROCESS FOR PRODUCING CELLULOSE ESTER/ACRYLIC COMPOSITE LATEX PARTICLES 审中-公开
公开(公告)号：US20180298224A1
公开(公告)日：2018-10-18
申请号：US15486426
申请日：2017-04-13
申请人： Eastman Chemical Company
发明人： Bradley James Helmer , Junjia Liu , Jennifer Lynn Cogar , Casey Lynn Elkins
IPC分类号： C09D101/14 , C08J3/03 , C09D133/08 , C08L1/14 , C08L33/08
摘要： The invention is a method for producing cellulose ester and acrylic composite latex particles and to latex compositions prepared from the method. The cellulose ester and acrylic composite materials are prepared by dispersing at least one cellulose ester in water and incrementally adding at least one acrylic monomer to said dispersion in the presence of a polymerization initiator. Surfactants and solvents are optionally added to aid in the dispersion of the cellulose ester in water.

5. 发明申请

US20160115274A1 CARBOXYL FUNCTIONAL CURABLE POLYESTERS CONTAINING TETRA-ALKYL CYCLOBUTANEDIOL 有权
标题翻译：含羧基烷基胆甾醇的羧酸官能可固化聚酯
公开(公告)号：US20160115274A1
公开(公告)日：2016-04-28
申请号：US14524509
申请日：2014-10-27
申请人： Eastman Chemical Company
发明人： Thauming Kuo , Junjia Liu , Phillip Bryan Hall
IPC分类号： C08G63/199 , C09D167/02 , C08G63/78
CPC分类号： C08G63/199 , C08G63/78 , C08K5/17 , C09D167/02
摘要： A curable polyester resin composition containing residues of: a) polyhydroxyl compounds that include: (i) 2,2,4,4-tetraalkylcyclobutane-1,3-diol (TACD) compounds, and (ii) polyhydroxyl compounds other than TACD, and (b) polycarboxylic acid compounds that include: (i) polycarboxylic acid compounds, a derivative of polycarboxylic acid compound other than (bii), or a combination thereof, and (ii) a polycarboxylic anhydride compound; wherein the curable polyester resin has an acid number ranging from about 20 to about 120 mg KOH/g, a hydroxyl number ranging from greater than 0 to about 100 mg KOH/g, and an acid number:hydroxyl (AN:OH) number ratio of at least 0.5:1. The curable polyester resin can be dispersed in water or a solvent and is suitable for waterborne or solventborne coating compositions and powder coating applications. Phenolic based crosslinking coating compositions that contain these curable polyester resins are curable at elevated temperatures.
摘要翻译：一种可固化聚酯树脂组合物，其含有：a）多羟基化合物，其包括：（i）2,2,4,4-四烷基环丁烷-1,3-二醇（TACD）化合物和（ii）除TACD以外的多羟基化合物，和（b）多元羧酸化合物，其包括：（i）多元羧酸化合物，除（bii）以外的多元羧酸化合物的衍生物或其组合，和（ii）多元羧酸酐化合物; 其中所述可固化聚酯树脂的酸值为约20至约120mg KOH / g，羟基数范围为大于0至约100mg KOH / g，酸值为：羟基（AN：OH）数比至少0.5：1。可固化聚酯树脂可以分散在水或溶剂中，适用于水性或溶剂型涂料组合物和粉末涂料应用。含有这些可固化聚酯树脂的酚基交联涂料组合物在升高的温度下是可固化的。

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