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    • 4. 发明授权
    • Ultra-high strength ausaged steels with excellent cryogenic temperature toughness and method of making thereof
    • 具有优异的低温韧性的超高强度耐久钢及其制造方法
    • US06254698B1
    • 2001-07-03
    • US09215773
    • 1998-12-19
    • Jayoung KooNarasimha-Rao V. BangaruGlen A. VaughnRaghavan Ayer
    • Jayoung KooNarasimha-Rao V. BangaruGlen A. VaughnRaghavan Ayer
    • C21D802
    • C21D6/001C21D1/19C21D1/20C21D7/13C21D8/02C21D8/0226C21D9/0068C21D9/08C21D2211/001C21D2211/002C21D2211/008C22C38/001C22C38/04C22C38/08C22C38/12C22C38/14C22C38/16
    • An ultra-high strength, weldable, low alloy steel with excellent cryogenic temperature toughness in the base plate and in the heat affected zone (HAZ) when welded, having a tensile strength greater than about 830 MPa (120 ksi) and a microstructure comprising (i) predominantly fine-grained lower bainite, fine-grained lath martensite, fine granular bainite (FGB), or mixtures thereof, and (ii) up to about 10 vol % retained austenite, is prepared by heating a steel slab comprising iron and specified weight percentages of some or all of the additives carbon, manganese, nickel, nitrogen, copper, chromium, molybdenum, silicon, niobium, vanadium, titanium, aluminum, and boron; reducing the slab to form plate in one or more passes in a temperature range in which austenite recrystallizes; finish rolling the plate in one or more passes in a temperature range below the austenite recrystallization temperature and above the Ar3 transformation temperature; quenching the finish rolled plate to a suitable Quench Stop Temperature (QST); stopping the quenching; and either, for a period of time, holding the plate substantially isothermally at the QST or slow-cooling the plate before air cooling, or simply air cooling the plate to ambient temperature.
    • 在焊接时,在底板和热影响区(HAZ)中具有优异的低温韧性的超高强度,可焊接的低合金钢,具有大于约830MPa(120ksi)的拉伸强度和包含( i)主要是细粒度的下贝氏体,细粒状板条马氏体,细粒状贝氏体(FGB)或其混合物,和(ii)高达约10体积%的残余奥氏体,通过加热包括铁和指定的钢板 碳,锰,镍,氮,铜,铬,钼,硅,铌,钒,钛,铝和硼中的一些或所有添加剂的重量百分数。 在奥氏体重结晶的温度范围内,在一次或多次通过时,将板坯还原成板; 在低于奥氏体再结晶温度且高于Ar3转变温度的温度范围内,在一个或多个道次中对板进行精轧; 将精轧板淬火至合适的淬火停止温度(QST); 停止淬火 并且在一段时间内,在空气冷却之前将板保持基本上等温,或者在空气冷却之前缓慢冷却板,或者简单地将板空气冷却至环境温度。
    • 6. 发明授权
    • Bimodal and multimodal dense boride cermets with superior erosion performance
    • 具有优良侵蚀性能的双峰和多峰密集硼化物金属陶瓷
    • US07731776B2
    • 2010-06-08
    • US11293728
    • 2005-12-02
    • ChangMin ChunNarasimha-Rao V. BangaruNeeraj S. ThirumalaiHyun-Woo JinJayoung KooJohn R. PetersonRobert L. AntramChristopher J. FowlerEmery B. Lendvai-Lintner
    • ChangMin ChunNarasimha-Rao V. BangaruNeeraj S. ThirumalaiHyun-Woo JinJayoung KooJohn R. PetersonRobert L. AntramChristopher J. FowlerEmery B. Lendvai-Lintner
    • C22C29/14B22F3/16
    • C22C29/14B22F1/0014B22F2009/043B22F2998/10B22F2999/00Y10T428/12007B22F1/0003B22F3/02B22F3/1021B22F3/1035B22F9/04
    • Multimodal cermet compositions comprising a multimodal grit distribution of the ceramic phase and method of making are provided by the present invention. The multimodal cermet compositions include a) a ceramic phase and b) a metal binder phase, wherein the ceramic phase is a metal boride with a multimodal distribution of particles, wherein at least one metal is selected from the group consisting of Group IV, Group V, Group VI elements of the Long Form of The Periodic Table of Elements and mixtures thereof, and wherein the metal binder phase comprises at least one first element selected from the group consisting of Fe, Ni, Co, Mn and mixtures thereof, and at least second element selected from the group consisting of Cr, Al, Si and Y, and Ti. The method of making multimodal boride cermets includes the steps of mixing multimodal ceramic phase particles and metal phase particles, milling the ceramic and metal phase particles, uniaxially and optionally isostatically pressing the particles, liquid phase sintering of the compressed mixture at elevated temperatures, and finally cooling the multimodal cermet composition. Advantages disclosed by the multimodal cermets are high packing density of the ceramic phase, high fracture toughness and improved erosion resistance at high temperatures up to 1000° C. The disclosed multimodal cermets are suitable in high temperature erosion/corrosion applications in various chemical and petroleum environments.
    • 包含陶瓷相的多峰砂粒分布的多模金属陶瓷组合物及其制造方法由本发明提供。 多峰金属陶瓷组合物包括a)陶瓷相和b)金属粘结相,其中所述陶瓷相是具有多峰颗粒分布的金属硼化物,其中至少一种金属选自第IV族,第V族 元素周期表的Long形式的VI族元素及其混合物,其中金属粘合剂相包含至少一种选自Fe,Ni,Co,Mn及其混合物的第一元素,至少 选自Cr,Al,Si和Y的第二元素和Ti。 制备多峰硼化物金属陶瓷的方法包括以下步骤:将多峰陶瓷相颗粒和金属相颗粒混合,研磨陶瓷和金属相颗粒,单轴和任选地等压挤压颗粒,在高温下液相烧结压缩混合物,最后 冷却多峰金属陶瓷组合物。 多峰金属陶瓷的优点是陶瓷相的高填充密度,高断裂韧性和在高达1000℃的高温下的耐腐蚀性得到改善。所公开的多峰金属陶瓷适用于各种化学和石油环境中的高温侵蚀/腐蚀应用 。
    • 10. 发明授权
    • Method for producing ultra-high strength, weldable steels with superior toughness
    • 具有优异韧性的超高强度,可焊接钢的生产方法
    • US06248191B1
    • 2001-06-19
    • US09123858
    • 1998-07-28
    • Michael J. LutonJayoung KooNarasimha-Rao V. BangaruClifford W. PetersenHiroshi TamehiroHitoshi AsahiTakuya HaraMasaaki Sugiyama
    • Michael J. LutonJayoung KooNarasimha-Rao V. BangaruClifford W. PetersenHiroshi TamehiroHitoshi AsahiTakuya HaraMasaaki Sugiyama
    • C21D800
    • C21D6/005C21D1/19C21D8/0226C21D2211/002C21D2211/008
    • A method is provided for producing an ultra-high strength steel having a tensile strength of at least about 900 MPa (130 ksi), a toughness as measured by Charpy V-notch impact test at −40° C. (−40° F.) of at least about 120 joules (90 ft-lbs), and a microstructure comprising predominantly fine-grained lower bainite, fine-grained lath martensite, or mixtures thereof, transformed from substantially unrecrystallized austenite grains and comprising iron and specified weight percentages of the additives: carbon, silicon, manganese, copper, nickel, niobium, vanadium, molybdenum, chromium, titanium, aluminum, calcium, Rare Earth Metals, and magnesium. A steel slab is heated to a suitable temperature; the slab is reduced to form plate in one or more hot rolling passes in a first temperature range in which austenite recrystallizes; said plate is further reduced in one or more hot rolling passes in a second temperature range below said first temperature range and above the temperature at which austenite begins to transform to ferrite during cooling; said plate is quenched to a suitable Quench Stop Temperature; and said quenching is stopped and said plate is allowed to air cool to ambient temperature.
    • 提供一种制造抗拉强度为至少约900MPa(130ksi)的超高强度钢,-40℃下通过夏比V-缺口冲击试验测得的韧性的方法(-40°F) )至少约120焦耳(90ft-lbs),以及由基本上未再结晶的奥氏体晶粒转化并且包含铁和特定重量百分比的主要由细晶粒的下贝氏体,细粒状板条马氏体或其混合物组成的微结构, 添加剂:碳,硅,锰,铜,镍,铌,钒,钼,铬,钛,​​铝,钙,稀土金属和镁。 将钢坯加热到合适的温度; 在奥氏体再结晶的第一温度范围内,在一个或多个热轧道中,将板坯还原成板; 所述板在一个或多个热轧道中在低于所述第一温度范围和高于在冷却期间奥氏体开始转变为铁素体的温度的温度范围内进一步减小; 所述板淬火至合适的淬火停止温度; 并且停止淬火,并使所述板空气冷却至环境温度。