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    • 4. 发明授权
    • Method for calibration of a spectroscopic sensor
    • 光谱传感器校准方法
    • US5835230A
    • 1998-11-10
    • US890926
    • 1997-07-10
    • James J. F. McAndrewRonald S. Inman
    • James J. F. McAndrewRonald S. Inman
    • G01J3/28G01J3/42G01N21/03G01N21/27G01N21/31G01N21/59
    • G01N21/276G01J3/42G01J2003/2866
    • A novel method for calibration of a spectroscopic sensor is provided. In the method, a spectroscopic system is provided. The system includes a measurement cell having one or more walls which at least partially enclose a sample region. The cell further includes a light entry port and a light exit port. The light entry port and the light exit port can be the same port or separate ports. Each of the ports contains a light transmissive window through which a light beam passes along an internal light path inside the measurement cell. The system further has an optical chamber which contains a light source for generating the light beam which passes through the light entry port into the cell, and a detector for measuring the light beam exiting the cell through the light exit port. The light beam passes along an external light path inside the optical chamber. In addition, a gas inlet is connected to the optical chamber. A calibration gas stream is introduced into the optical chamber. The calibration gas stream contains a calibrating gas species and a carrier gas. The calibrating gas species is present in the calibration gas stream in a known concentration. A spectroscopy measurement of the calibration gas stream is then performed. The method finds particular applicability in the calibration of an in-line spectroscopic sensor useful in the detection of molecules of interest in a semiconductor processing tool.
    • 提供了一种用于校准光谱传感器的新方法。 在该方法中,提供了光谱系统。 该系统包括具有至少部分地包围样品区域的一个或多个壁的测量单元。 电池还包括光入口和光出口。 光入口和光出口可以是相同的端口或单独的端口。 每个端口包含透光窗口,光束通过该透光窗口沿测量单元内部的内部光路传播。 该系统还具有光学室,该光学室包含用于产生通过光入口进入单元的光束的光源,以及用于测量通过光出口离开单元的光束的检测器。 光束通过光学室内的外部光路。 此外,气体入口连接到光学室。 校准气流被引入到光学室中。 校准气流包含校准气体种类和载气。 校正气体种类以已知浓度存在于校准气流中。 然后进行校准气流的光谱测量。 该方法在用于检测半导体加工工具中的分子的在线光谱传感器的校准中具有特别的适用性。
    • 10. 发明授权
    • Method and system for sensitive detection of molecular species in a
vacuum by harmonic detection spectroscopy
    • 通过谐波检测光谱法在真空中敏感检测分子物种的方法和系统
    • US5880850A
    • 1999-03-09
    • US951301
    • 1997-10-16
    • James McAndrewRonald S. Inman
    • James McAndrewRonald S. Inman
    • G01J3/433G01N21/39G01N21/00
    • G01N21/39G01J3/4338
    • Provided is a novel method and system for harmonic detection spectroscopy. The method comprises providing a cell having a sample region which is circumscribed by at least one wall. The cell has at least one light entry/exit port, with each entry/exit port containing a light transmissive window having a surface facing the sample region and disposed so as to seal the cell in the circumferential direction. A sample gas flows through the sample region in a direction parallel to a cell central axis, and the cell operates at less than atmospheric pressure. A frequency and/or amplitude modulated light source is provided for directing a light beam through one of the at least one light transmissive windows into the cell. The light source modulation amplitude is set to a value which approximately maximizes the value of a harmonic signal at the center of the absorption feature due to the detected gas phase molecular species inside the sample region, and the center frequency of the light source is adjusted so that it is either locked to the center of the absorption feature or repetitively scanned over the frequency range which includes the feature. A spectra is then generated which may be recorded individually or averaged. A detector is provided for measuring the light beam exiting the cell through one of the at least one light transmissive windows. The light source and detector are contained within a chamber which is external to the cell and isolated from the sample region, the chamber and the sample region being placed in optical communication with each other through at least one of the at least one light transmissive windows. The pressure inside the chamber is controlled to a value which is positive relative to atmospheric pressure. The method can be used to detect gas phase molecular species in a sample. Particular applicability is found in semiconductor processing.
    • 提供了一种用于谐波检测光谱的新颖方法和系统。 该方法包括提供具有被至少一个壁限定的样品区域的细胞。 电池具有至少一个光入口/出口,每个入口/出口包含透光窗口,该透光窗口具有面向样品区域的表面,并设置成在圆周方向上密封电池。 样品气体在平行于细胞中心轴线的方向上流过样品区域,并且细胞在小于大气压力下操作。 提供了频率和/或幅度调制光源,用于将光束引导通过至少一个透光窗中的一个进入单元。 由于检测到的样品区域内的气相分子种类,光源调制幅度被设定为大致使吸收特征中心处的谐波信号的值最大化的值,并且调整光源的中心频率 它被锁定到吸收特征的中心或在包括该特征的频率范围上重复扫描。 然后产生可以单独记录或平均记录的光谱。 提供了一种检测器,用于通过至少一个透光窗中的一个来测量离开单元的光束。 光源和检测器被包含在室内并且与样品区隔离的腔室中,腔室和样品区域通过至少一个透光窗口中的至少一个彼此光学连通。 室内的压力被控制为相对于大气压力为正的值。 该方法可用于检测样品中的气相分子种类。 在半导体处理中发现了特殊的适用性。