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1. 发明授权

US07618710B2 Fluorescent articles having multiple film layers 有权
标题翻译：具有多个膜层的荧光制品
公开(公告)号：US07618710B2
公开(公告)日：2009-11-17
申请号：US11731888
申请日：2007-04-02
申请人： Guang-Xue Wei , Drew J. Buoni , Kimberly A. Dockus
发明人： Guang-Xue Wei , Drew J. Buoni , Kimberly A. Dockus
IPC分类号： B32B9/04
CPC分类号： B32B27/20 , B32B27/08 , B32B27/308 , B32B27/365 , B32B2307/422 , B32B2590/00 , G02B5/124 , G02B5/128 , Y10T428/31504 , Y10T428/31507 , Y10T428/31551 , Y10T428/31786 , Y10T428/31855
摘要： Articles are provided which have fluorescent properties and which are suitable for use in making retroreflective articles such as safety and informational signage. The articles have at least two film layers, each film layer including a colorant dye. The multiple film layer sheeting exhibits excellent resistance to weathering and overall color durability while also providing chromaticity properties dictated by industry standards for a particular coloration. A method of preparing the articles is provided. In a particular application, the articles embody retroreflective properties and are informational for safety signage articles such as pedestrian crossing and school safety fluorescent yellow green signs.
摘要翻译：提供具有荧光性质并且适用于制造诸如安全和信息标志的回射制品的制品。制品具有至少两个膜层，每个膜层包括着色剂染料。多层膜层具有优异的耐候性和整体色彩耐久性，同时还提供了特定着色行业标准所规定的色度特性。提供了制备物品的方法。在具体应用中，这些物品体现了逆向反射性质，并且对于诸如行人过路和学校安全荧光黄绿色标志的安全标志物品是信息性的。

2. 发明申请

US20090246465A1 RETROREFLECTIVE FILM CONTAINING A POLYMERIC FACE FILM AND METHOD OF MANUFACTURE THEREFORE 有权
标题翻译：包含聚合物薄膜的回流膜及其制造方法
公开(公告)号：US20090246465A1
公开(公告)日：2009-10-01
申请号：US12356614
申请日：2009-01-21
申请人： Drew J. Buoni
发明人： Drew J. Buoni
IPC分类号： B32B3/10 , B32B37/00
CPC分类号： G02B5/124 , B41M5/0041 , B41M5/382 , B41M5/502 , B41M5/504 , B41M5/506 , B41M5/508 , B41M5/5254 , B41M2205/02 , B41M2205/36 , B41M2205/38 , G02B5/128 , Y10T156/10 , Y10T428/24355 , Y10T428/24364 , Y10T428/24405 , Y10T428/24479 , Y10T428/24488 , Y10T428/24521 , Y10T428/24529
摘要： In one aspect, there is provided a retroreflective film, comprising a retroreflective sub-structure, and a transparent polymeric film, having a surface roughness profile where the Arithmetic Mean Deviation of the Roughness Profile (Ra) ranges from about 0.18 microns to about 1.30 microns and where the Mean Spacing of Local Peaks (R—S) in the printing direction ranges from about 10 microns to about 85 microns, located over and coupled to the retroreflective sub-structure.
摘要翻译：在一个方面，提供一种包括回射子结构的回射膜和透明聚合物膜，其具有表面粗糙度轮廓，其中粗糙度轮廓（Ra）的算术平均偏差范围为约0.18微米至约1.30微米并且其中打印方向上的局部峰值（RS）的平均间距范围为约10微米至约85微米，其位于并耦合到回射子结构。

3. 发明授权

US08360586B2 Retroreflective film containing a polymeric face film and method of manufacture therefore 有权
标题翻译：因此，含有聚合物面膜的回射膜及其制造方法
公开(公告)号：US08360586B2
公开(公告)日：2013-01-29
申请号：US12889231
申请日：2010-09-23
申请人： Drew J. Buoni
发明人： Drew J. Buoni
IPC分类号： G02B5/124 , G02B5/128 , B41M5/382 , B32B3/00
CPC分类号： G02B5/124 , B41M5/41 , B41M5/506 , B41M5/508 , B41M2205/02 , B41M2205/36 , B41M2205/38 , G02B5/128 , Y10T156/10 , Y10T428/24355 , Y10T428/24364 , Y10T428/24405 , Y10T428/24479 , Y10T428/24488 , Y10T428/24521 , Y10T428/24529
摘要： In one aspect, there is provided a retroreflective film, comprising a retroreflective sub-structure, and a transparent polymeric film, having a surface roughness profile where the Arithmetic Mean Deviation of the Roughness Profile (Ra) ranges from about 0.18 microns to about 1.30 microns and where the Mean Spacing of Local Peaks (R-S) in the printing direction ranges from about 10 microns to about 85 microns, located over and coupled to the retroreflective sub-structure and wherein the polymeric film as a Vicat softening point of about 90° or greater.
摘要翻译：在一个方面，提供一种包括回射子结构的回射膜和透明聚合物膜，其具有表面粗糙度轮廓，其中粗糙度轮廓（Ra）的算术平均偏差范围为约0.18微米至约1.30微米并且其中打印方向上的局部峰值（RS）的平均间距范围为约10微米至约85微米，位于并且耦合到回射子结构，并且其中聚合物膜为维卡软化点约90°或更大

4. 发明授权

US06375776B1 Method for forming multi-layer laminates with microstructures 有权
标题翻译：用微结构形成多层层压板的方法
公开(公告)号：US06375776B1
公开(公告)日：2002-04-23
申请号：US09489789
申请日：2000-01-24
申请人： Drew J. Buoni , Alan R. Kaufman
发明人： Drew J. Buoni , Alan R. Kaufman
IPC分类号： B32B3120
CPC分类号： B32B38/06 , B29D11/00605 , B32B37/26 , B32B2037/268 , B32B2307/418 , Y10T156/1023 , Y10T156/1712 , Y10T156/1741
摘要： A method of continuously forming a multi-layer laminate of thermoplastic polymeric films wherein one surface thereof has a precision pattern of embossed elements thereon and wherein the thermoplastic polymeric films can be dissimilar. A generally cylindrical seamless metal embossing tool with an outer surface having the reverse of the pattern to be formed on the surface of the sheeting is used. The laminate is formed by continuously feeding onto a heated embossing tool a superimposed first resinous film and a first carrier film wherein the first resinous film is pressed against the embossing tool and is heated above its glass transition temperature thereby becoming embossed with the pattern, while the first carrier film remains at a temperature below its glass transition temperature. The first carrier film is then removed, and a second resinous film and second carrier film are superimposed on the unembossed surface of the first resinous film and are heated such that the two resinous films become bonded together. The resulting laminate is then cooled and is stripped from the embossing tool. If the laminate is to be used for retroreflective sheeting, then, because the second resinous film is applied after the embossing step is complete, a smooth interface can be formed between the two resinous films. This results in a sheeting of exceptional retroreflective capability, even if the first and second resinous films are dissimilar thermoplastic materials.
摘要翻译：一种连续形成多层热塑性聚合物薄膜的方法，其中一个表面上具有压花元件的精密图案，其中热塑性聚合物薄膜可以是不相似的。使用通常为圆柱形的无缝金属压花工具，其外表面具有形成在片材表面上的图案的相反面。层压体是通过将加热的压花工具连续地送入叠加的第一树脂膜和第一载体膜而形成的，其中第一树脂膜被压靠在压花工具上并被加热到其玻璃化转变温度以上，从而变得被压印，同时第一载体膜保持在低于其玻璃化转变温度的温度。然后除去第一载体膜，并且将第二树脂膜和第二载体膜叠加在第一树脂膜的未卷曲的表面上并被加热，使得两个树脂膜结合在一起。然后将所得层压体冷却并从压花工具剥离。如果层压板用于逆反射片材，则由于在压花步骤完成之后施加第二树脂膜，所以可以在两个树脂膜之间形成平滑的界面。即使第一和第二树脂膜是不同的热塑性材料，这导致了特殊的反射能力的片材。

5. 发明授权

US07618709B2 Fluorescent articles having multiple film layers 有权
标题翻译：具有多个膜层的荧光制品
公开(公告)号：US07618709B2
公开(公告)日：2009-11-17
申请号：US10354515
申请日：2003-01-30
申请人： Guang-Xue Wei , Drew J. Buoni
发明人： Guang-Xue Wei , Drew J. Buoni
IPC分类号： B32B9/04
CPC分类号： B32B27/20 , B32B27/08 , B32B27/308 , B32B27/365 , B32B2307/422 , B32B2590/00 , G02B5/124 , G02B5/128 , Y10T428/31504 , Y10T428/31507 , Y10T428/31551 , Y10T428/31786 , Y10T428/31855
摘要： Articles are provided which have fluorescent properties and which are suitable for use in making retroreflective articles such as safety and informational signage. The articles have at least two film layers, each film layer including a colorant dye. The multiple film layer sheeting exhibits excellent resistance to weathering and overall color durability while also providing chromaticity properties dictated by industry standards for a particular coloration. A method of preparing the articles is provided. In a particular application, the articles embody retroreflective properties and are fluorescent yellow signs.
摘要翻译：提供具有荧光性质并且适用于制造诸如安全和信息标志的回射制品的制品。制品具有至少两个膜层，每个膜层包括着色剂染料。多层膜层具有优异的耐候性和整体色彩耐久性，同时还提供了特定着色行业标准所规定的色度特性。提供了制备物品的方法。在特定应用中，这些物品体现了逆反射性质并且是荧光黄色的迹象。

6. 发明授权

US06514594B1 Fluorescent polymeric articles having screening layer formed from U.V. light absorbing polymer 有权
标题翻译：具有由紫外线形成的屏蔽层的荧光聚合物制品光吸收聚合物
公开(公告)号：US06514594B1
公开(公告)日：2003-02-04
申请号：US09710560
申请日：2000-11-09
申请人： Guang-Xue Wei , Drew J. Buoni , Kimberly A. Dockus
发明人： Guang-Xue Wei , Drew J. Buoni , Kimberly A. Dockus
IPC分类号： C08F26302
CPC分类号： C08J5/18 , B32B27/08 , B32B27/18 , B32B27/36 , C08J2367/02 , C08K5/0041 , C08L51/08 , C08L53/00 , C08L67/02 , C08L67/03 , C08L69/00 , G02B5/124 , Y10S428/917 , Y10T428/1429 , Y10T428/24355 , C08L2666/02 , C08L2666/14 , C08L2666/04 , C08L2666/18
摘要： A fluorescent article is disclosed in which a U.V. light screening layer comprising a polymer having in its backbone repeating units of a U.V. light absorbing moiety, or a moiety capable of being transformed by Photo-Fries rearrangement into a U.V. light absorbing moiety, is disposed in operative screening relation to a layer containing a fluorescent colorant. The U.V. light screening layer affords surprisingly improved fluorescence protection as compared to prior U.V. light screening layers having only U.V. light absorbing additives.
摘要翻译：公开了一种荧光制品，其中光屏蔽层包含聚合物，其主链具有一个U.V.的主链重复单元。光吸收部分或能够通过Photo-Fries重排转化成U.V.的部分。光吸收部分以与包含荧光着色剂的层的操作性筛选关系设置。紫外线与以前的紫外线相比，光屏蔽层提供惊人的改善的荧光保护。仅具有紫外线的光屏蔽层光吸收添加剂。

7. 发明授权

US08267533B2 Retroreflective film containing a polymeric face film and method of manufacture therefore 有权
标题翻译：因此，含有聚合物面膜的回射膜及其制造方法
公开(公告)号：US08267533B2
公开(公告)日：2012-09-18
申请号：US12356614
申请日：2009-01-21
申请人： Drew J. Buoni
发明人： Drew J. Buoni
IPC分类号： G02B5/124 , G02B5/128 , B41M5/382 , B32B3/00
CPC分类号： G02B5/124 , B41M5/0041 , B41M5/382 , B41M5/502 , B41M5/504 , B41M5/506 , B41M5/508 , B41M5/5254 , B41M2205/02 , B41M2205/36 , B41M2205/38 , G02B5/128 , Y10T156/10 , Y10T428/24355 , Y10T428/24364 , Y10T428/24405 , Y10T428/24479 , Y10T428/24488 , Y10T428/24521 , Y10T428/24529
摘要： In one aspect, there is provided a retroreflective film, comprising a retroreflective sub-structure, and a transparent polymeric film, having a surface roughness profile where the Arithmetic Mean Deviation of the Roughness Profile (Ra) ranges from about 0.18 microns to about 1.30 microns and where the Mean Spacing of Local Peaks (R-S) in the printing direction ranges from about 10 microns to about 85 microns, located over and coupled to the retroreflective sub-structure.
摘要翻译：在一个方面，提供一种包括回射子结构的回射膜和透明聚合物膜，其具有表面粗糙度轮廓，其中粗糙度轮廓（Ra）的算术平均偏差范围为约0.18微米至约1.30微米并且其中打印方向上的局部峰值（RS）的平均间距范围为约10微米至约85微米，其位于并耦合到回射子结构。

8. 发明申请

US20110013282A1 RETROREFLECTIVE FILM CONTAINING A POLYMERIC FACE FILM AND METHOD OF MANUFACTURE THEREFORE 有权
标题翻译：包含聚合物薄膜的回流膜及其制造方法
公开(公告)号：US20110013282A1
公开(公告)日：2011-01-20
申请号：US12889231
申请日：2010-09-23
申请人： Drew J. Buoni
发明人： Drew J. Buoni
IPC分类号： G02B5/13 , G02B5/136
CPC分类号： G02B5/124 , B41M5/41 , B41M5/506 , B41M5/508 , B41M2205/02 , B41M2205/36 , B41M2205/38 , G02B5/128 , Y10T156/10 , Y10T428/24355 , Y10T428/24364 , Y10T428/24405 , Y10T428/24479 , Y10T428/24488 , Y10T428/24521 , Y10T428/24529
摘要： In one aspect, there is provided a retroreflective film, comprising a retroreflective sub-structure, and a transparent polymeric film, having a surface roughness profile where the Arithmetic Mean Deviation of the Roughness Profile (Ra) ranges from about 0.18 microns to about 1.30 microns and where the Mean Spacing of Local Peaks (R-S) in the printing direction ranges from about 10 microns to about 85 microns, located over and coupled to the retroreflective sub-structure and wherein the polymeric film as a Vicat softening point of about 90° or greater.
摘要翻译：在一个方面，提供一种包括回射子结构的回射膜和透明聚合物膜，其具有表面粗糙度轮廓，其中粗糙度轮廓（Ra）的算术平均偏差范围为约0.18微米至约1.30微米并且其中打印方向上的局部峰值（RS）的平均间距范围为约10微米至约85微米，位于并且耦合到回射子结构，并且其中聚合物膜为维卡软化点约90°或更大

9. 发明授权

US06972147B1 Fluorescent polymeric articles fabricated from U.V. light absorbing polymer 有权
标题翻译：由U.V.制造的荧光聚合物制品光吸收聚合物
公开(公告)号：US06972147B1
公开(公告)日：2005-12-06
申请号：US09710510
申请日：2000-11-09
申请人： Guang-Xue Wei , Drew J. Buoni , Kimberly A. Dockus
发明人： Guang-Xue Wei , Drew J. Buoni , Kimberly A. Dockus
IPC分类号： B32B25/08 , B32B25/14 , B32B27/16 , B32B27/18 , B32B27/28 , C08F263/02 , C08G63/06 , C08K5/132 , C08L67/02 , C08L67/03 , C08L67/04 , C08L69/00 , G02B5/124 , G02B5/128
CPC分类号： C08K5/132 , B32B27/18 , C08G63/065 , C08L67/02 , C08L67/03 , C08L67/04 , C08L69/00 , C08L69/005 , G02B5/124 , G02B5/128 , Y10S428/917 , Y10T428/1429 , Y10T428/24355 , C08L2666/18
摘要： A fluorescent article is disclosed comprising a polymer matrix comprising a polymer having in its backbone repeating units of a U.V. light absorbing moiety, or a moiety capable of being transformed by photo-Fries rearrangement into a U.V. light absorbing moiety, the matrix further comprising a fluorescent dye. The matrix affords surprisingly improved fluorescence protection as compared to prior fluorescent articles having only U.V. light absorbing additives.
摘要翻译：公开了一种荧光制品，其包含聚合物基质，所述聚合物基质包含其主链具有紫外线的重复单元的聚合物。光吸收部分或能够通过光 - 薯条重排转化成紫外线的部分。光吸收部分，所述基质还包含荧光染料。与仅具有紫外线的现有荧光体制品相比，该基质提供惊人的改善的荧光保护。光吸收添加剂。

10. 发明授权

US07264880B2 Fluorescent articles having multiple film layers 有权
公开(公告)号：US07264880B2
公开(公告)日：2007-09-04
申请号：US10135537
申请日：2002-04-30
申请人： Guang-Xue Wei , Drew J. Buoni , Kimberly A. Dockus
发明人： Guang-Xue Wei , Drew J. Buoni , Kimberly A. Dockus
IPC分类号： B32B27/00 , B32B27/36
CPC分类号： B32B27/20 , B32B27/08 , B32B27/308 , B32B27/365 , B32B2307/422 , B32B2590/00 , G02B5/124 , G02B5/128 , Y10T428/31504 , Y10T428/31507 , Y10T428/31551 , Y10T428/31786 , Y10T428/31855
摘要： Articles are provided which have fluorescent properties and which are suitable for use in making retroreflective articles such as safety and informational signage. The articles have at least two film layers, each film layer including a colorant dye. The multiple film layer sheeting exhibits excellent resistance to weathering and overall color durability while also providing chromaticity properties dictated by industry standards for a particular coloration. A method of preparing the articles is provided. In a particular application, the articles embody retroreflective properties and are informational for safety signage articles such as pedestrian crossing and school safety fluorescent yellow green signs.

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