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1. 发明授权

US5552546A Process for the preparation of 2-ethoxy-4,6-dihydroxypyrimidine 失效
标题翻译： 2-乙氧基-4,6-二羟基嘧啶的制备方法
公开(公告)号：US5552546A
公开(公告)日：1996-09-03
申请号：US282398
申请日：1994-07-28
申请人： Douglas L. Pearson , Jon A. Orvik , Gary A. Roth , Carmen A. Scott , Ron B. Leng , Dawn L. Shiang
发明人： Douglas L. Pearson , Jon A. Orvik , Gary A. Roth , Carmen A. Scott , Ron B. Leng , Dawn L. Shiang
IPC分类号： C07D239/60 , C07D239/02
CPC分类号： C07D239/60
摘要： A salt of 2-ethoxy-4,6-dihydroxypyrimidine (DHEP) is prepared by contacting a salt of O-ethylisourea with dimethyl malonate in the presence of a methoxide base to form the salt of DHEP. The salt of DHEP can optionally be protonated with an acid to form neutral DHEP. The reaction is typically conducted in a methanol solvent at a temperature less than about 30.degree. C. Typically, the monosodium salt of DHEP is prepared by contacting O-ethylisourea hydrochloride with dimethyl malonate in the presence of sodium methoxide and methanol solvent.
摘要翻译：通过在甲醇盐碱存在下使O-乙基异脲的盐与丙二酸二甲酯接触以制备DHEP的盐来制备2-乙氧基-4,6-二羟基嘧啶（DHEP）的盐。 DHEP的盐可任选地用酸质子化形成中性DHEP。反应通常在甲醇溶剂中在低于约30℃的温度下进行。通常，在甲醇钠和甲醇溶剂存在下，通过使O-乙基异脲盐酸盐与丙二酸二甲酯接触来制备DHEP的单钠盐。

2. 发明授权

US5488109A 5-alkoxy[1,2,4]triazolo[1,5-c]pyrimidine-2(3H)--thione compounds and their use in the preparation of and 2-chlorosulfonyl-5-alkoxy[1,2,4]triazolo[1,5-c]-pyrimidine compounds 失效
标题翻译：（3H） - 硫酮化合物及其在制备2,2'-二硫代双（5-烷氧基-1,2,3,4-三唑并[1,5-c]嘧啶）和2-氯磺酰基 - 5-烷氧基-1,2,3,4-三唑并[1,5-c]嘧啶化合物
公开(公告)号：US5488109A
公开(公告)日：1996-01-30
申请号：US148790
申请日：1993-11-05
申请人： Thomas A. Olmstead , Michael A. Gonzalez , Jon A. Orvik , Douglas L. Pearson , James W. Ringer , Dawn Shiang , Jimmy J. Tai , Anne P. Wallin
发明人： Thomas A. Olmstead , Michael A. Gonzalez , Jon A. Orvik , Douglas L. Pearson , James W. Ringer , Dawn Shiang , Jimmy J. Tai , Anne P. Wallin
IPC分类号： A01N43/90 , C07D487/04 , C07D519/00
CPC分类号： C07D487/04
摘要： 2-Chlorosulfonyl-5-alkoxy[1,2,4]triazolo-[1,5-c]pyrimidine compounds, such as 2-chlorosulfonyl-5-ethoxy-7-fluoro[1,2,4]triazolo[1,5-c]pyrimidine, that are useful for the preparation of 5-alkoxy[1,2,4]triazolo [1,5-c]pyrimidine-2-sulfonamide herbicides, were prepared in an improved manner from 5-alkoxy[1,2,4]triazolo [1,5-c]pyrimidine-2(3H)-thione compounds, such as 5-ethoxy-7-fluoro[1,2,4]triazolo[1,5-c]pyrimidine-2(3H)-thione, by oxidation with hydrogen peroxide to obtain novel 2,2'-dithiobis(5-alkoxy[1,2,4]triazolo[1,5-c]pyrimidine) compounds, such as 2,2'-dithiobis (5-ethoxy-7-fluoro[1,2,4]triazolo[1,5-c]pyrimidine), and subsequent chloroxidation of these intermediate compounds.
摘要翻译： 2-氯磺酰基-5-烷氧基[1,2,4]三唑并 - [1,5-c]嘧啶化合物如2-氯磺酰基-5-乙氧基-7-氟[1,2,4]三唑并[ 5-c]嘧啶，其可用于制备5-烷氧基[1,2,4]三唑并[1,5-c]嘧啶-2-磺酰胺除草剂，以5-烷氧基[1 ，2,4]三唑并[1,5-c]嘧啶-2（3H） - 硫酮化合物如5-乙氧基-7-氟[1,2,4]三唑并[1,5-c]嘧啶-2 （3H） - 硫酮，通过用过氧化氢氧化得到新的2,2'-二硫代双（5-烷氧基[1,2,4]三唑并[1,5-c]嘧啶）化合物，二硫代双（5-乙氧基-7-氟[1,2,4]三唑并[1,5-c]嘧啶），然后这些中间体化合物的氯氧化。

3. 发明授权

US4739070A Preparation of substituted (dichloromethyl)pyridines 失效
标题翻译：取代（二氯甲基）吡啶的制备
公开(公告)号：US4739070A
公开(公告)日：1988-04-19
申请号：US855226
申请日：1986-04-23
申请人： Jon A. Orvik
发明人： Jon A. Orvik
IPC分类号： C07D213/84 , C07D213/06 , C07D213/26 , C07D213/61 , C07D213/71 , C07D213/32
CPC分类号： C07D213/61
摘要： 2- and 4-(Dichloromethyl)pyridines containing electron withdrawing substituents on the ring are prepared by the reaction of the corresponding 2- or 4-halopyridines with excess chloroform in the presence of a strong base in a medium containing a dipolar aprotic solvent or a phase transfer catalyst. 3-Chloro-5-(trifluoromethyl)-2-(dichloromethyl)pyridine, for example, is prepared by the reaction of 2,3-dichloro-5-(trifluoromethyl)pyridine with chloroform in the presence of sodium hydroxide and N-methylpyrrolidone. Substituted 2-(dichloromethyl)pyridines are useful as agricultural pesticides and as intermediates for the preparation of agricultural pesticides.
摘要翻译：通过相应的2-或4-卤代吡啶与过量的氯仿在强碱的存在下在含有偶极非质子溶剂的介质中反应制备含有吸电子取代基的2-和4-（二氯甲基）吡啶，相转移催化剂。例如通过2,3-二氯-5-（三氟甲基）吡啶与氯仿在氢氧化钠和N-甲基吡咯烷酮存在下反应制备3-氯-5-（三氟甲基）-2-（二氯甲基）吡啶。取代的2-（二氯甲基）吡啶可用作农药，作为制备农药的中间体。

4. 发明授权

US5084576A 2-hydrocarbyl-3,6-dichloropyridine compounds 失效
标题翻译： 2-烃基-3,6-二氯吡啶化合物
公开(公告)号：US5084576A
公开(公告)日：1992-01-28
申请号：US626644
申请日：1990-12-11
申请人： Marc E. Halpern , Jon A. Orvik , Thomas J. Dietsche , J. Brian Barron
发明人： Marc E. Halpern , Jon A. Orvik , Thomas J. Dietsche , J. Brian Barron
IPC分类号： C07D213/61
CPC分类号： C07D213/61
摘要： 2-Hydrocarbyl-3,6-dichloropyridines are prepared from dichloromethyl hydrocarbyl ketones and acrylonitrile in a two-step process involving an addition reaction under basic conditions to form intermediate 1,1-dichloro-3-cyanopropyl hydrocarbyl ketones and a subsequent cyclization reaction in the presence of hydrogen chloride. Thus, 3,6-dichloro-2-methylpyridine is prepared from 1,1-dichloro-2-propanone and acrylonitrile by the formation and further reaction of 4,4-dichloro-5-oxo-hexanenitrile. The intermediates and products are novel compounds useful in the preparation of herbicides and nitrification inhibitors.
摘要翻译： 2-二烃基-3,6-二氯吡啶由二氯甲基烃基酮和丙烯腈制备，包括在碱性条件下进行加成反应的两步法形成中间体1,1-二氯-3-氰基丙基烃基酮，随后进行环化反应存在氯化氢。因此，通过4,4-二氯-5-氧代 - 己腈的形成和进一步的反应，由1,1-二氯-2-丙酮和丙烯腈制备3,6-二氯-2-甲基吡啶。中间体和产物是可用于制备除草剂和硝化抑制剂的新化合物。

5. 发明授权

US4766219A Preparation of 2-cyano-6-chloropyridine compounds 失效
标题翻译：制备2-氰基-6-氯吡啶化合物
公开(公告)号：US4766219A
公开(公告)日：1988-08-23
申请号：US66597
申请日：1987-06-26
申请人： Jon A. Orvik , Alexander P. Fung , Jim Love , Thomas J. Dietsche
发明人： Jon A. Orvik , Alexander P. Fung , Jim Love , Thomas J. Dietsche
IPC分类号： C07D213/84 , C07D213/57 , C07D213/85
CPC分类号： C07D213/84
摘要： Novel methods for preparing 2-cyano-6-chloropyridines are disclosed. The compounds are useful as intermediates in preparing other intermediates or as intermediates directly used in making pesticides, especially herbicides.
摘要翻译：公开了制备2-氰基-6-氯吡啶的新方法。该化合物可用作制备其它中间体或直接用于制备农药的中间体，特别是除草剂。

6. 发明授权

US4257899A Method for removing chloropicrin from an aqueous medium 失效
标题翻译：从水性介质中除去氯化苦的方法
公开(公告)号：US4257899A
公开(公告)日：1981-03-24
申请号：US073778
申请日：1979-09-10
申请人： Jon A. Orvik
发明人： Jon A. Orvik
IPC分类号： C02F1/70 , C02F9/00 , C02F1/72
CPC分类号： C02F1/70 , C02F2101/36 , Y10S210/903
摘要： A method for destroying chloropicrin in an aqueous medium contaminated with chloropicrin which comprises contacting the aqueous medium with a sufficient amount of an alkali metal sulfite for a sufficient period of time to convert the chloropicrin to an alkali metal chloride and to nitromethane disulfonic acid or a salt thereof, whereby the aqueous medium is rendered substantially free of chloropicrin.
摘要翻译：一种在氯化苦毒素污染的水性介质中破坏氯化苦的方法，该方法包括使水性介质与足够量的碱金属亚硫酸盐接触足够的时间以将氯化苦霉素转化为碱金属氯化物和硝基甲烷二磺酸或盐由此使得水性介质基本上不含氯化苦。

7. 发明授权

US4140847A Polymers of oxetane-spiro-cyclic polyethers 失效
标题翻译：氧杂环丁烷 - 环 - 环聚醚的聚合物
公开(公告)号：US4140847A
公开(公告)日：1979-02-20
申请号：US510873
申请日：1974-10-01
申请人： Jon A. Orvik , Edwin C. Steiner
发明人： Jon A. Orvik , Edwin C. Steiner
IPC分类号： C08G65/18 , C08G65/02
CPC分类号： C08G65/18
摘要： Novel linear, branched and cyclic polymers of the repeating unit ##STR1## wherein R is ethylene or propylene bearing from zero to six methyl groups and m and n are lower integers and a process for utilizing said polymers to extract salts from solution are disclosed. For example, a monomer of the formula ##STR2## is contacted with traces of water in the presence of BF.sub.3.etherate to give a homopolymer consisting essentially of repeating units of the formula ##STR3## which extracts sodium salts from aqueous solution in a thermally reversible manner.
摘要翻译：公开了重复单元“IMAGE”的新型直链，支链和环状聚合物，其中R是含有0至6个甲基的乙烯或丙烯，m和n是较低的整数，并且公开了利用所述聚合物从溶液中提取盐的方法。例如，在BF 3醚的存在下，将式“IMAGE”的单体与微量的水接触，得到基本上由式“IMAGE”重复单元组成的均聚物，其从水溶液中以热可逆的方式提取钠盐方式。

8. 发明授权

US4118373A Preparation of urethane elastomers from epoxy resin, polyols and polyisocyanates using a catalyst composition of an organometal salt with either nitrogen or phosphorus compounds 失效
标题翻译：使用有机金属盐与氮或磷化合物的催化剂组合物从环氧树脂，多元醇和多异氰酸酯制备聚氨酯弹性体
公开(公告)号：US4118373A
公开(公告)日：1978-10-03
申请号：US793569
申请日：1977-05-04
申请人： Jon A. Orvik
发明人： Jon A. Orvik
IPC分类号： C08G18/16 , C08G18/66 , C08L75/08 , C08G18/18
CPC分类号： C08G18/6674 , C08G18/161 , C08G18/168 , C08L75/08
摘要： Elastomers are prepared from a mixture comprising a 1600 equivalent weight polyether polyol such as a glycerine initiated polyoxypropylene glycol end-capped with ethylene oxide, a diol such as diethylene glycol, a liquid polyepoxide such as the diglycidyl ether of bisphenol A and a catalyst mixture containing a quaternary ammonium or phosphonium salt and an organometal salt of the metal tin or lead such as tetrabutyl ammonium bromide and lead octoate.
摘要翻译：弹性体由包含1600当量聚醚多元醇如乙二醇封端的甘油引发的聚氧丙烯二醇，二甘醇二醇，液体聚环氧化物如双酚A的二缩水甘油醚和含有季铵盐或鏻盐和金属锡或铅的有机金属盐，例如四丁基溴化铵和辛酸铅。

9. 发明授权

US5189210A Process for the preparation of 3- and/or 5-substituted anthranilic acids 失效
标题翻译：制备3-和/或5-取代邻氨基苯甲酸的方法
公开(公告)号：US5189210A
公开(公告)日：1993-02-23
申请号：US876651
申请日：1992-04-30
申请人： Terry L. Wright , Jon A. Orvik
发明人： Terry L. Wright , Jon A. Orvik
IPC分类号： C07C227/22 , C07C229/56
CPC分类号： C07C227/22 , C07C229/56
摘要： Anthranilic acids substituted in the 3- and/or 5-position are valuable intermediates for the production of agricultural chemicals. These substituted anthranilic acids can be obtained in good yield without undesirable isomeric byproducts by the oxidative ring-opening of dihydroquinolin-4-ones or quinolin-2,4-diones with t-butyl hydroperoxide in the presence of a base.
摘要翻译：在3-和/或5-位取代的邻氨基苯甲酸是生产农药的有价值的中间体。这些取代的邻氨基苯甲酸可以以良好的产率获得，而在碱的存在下，通过二氢喹啉-4-酮或喹啉-2,4-二酮与叔丁基过氧化氢的氧化开环无异构副产物。

10. 发明授权

US4988812A Aqueous process for the preparation of 5-methyl-n-(aryl)-1,2,4-triazolo(1,5-A)pyrimidine-2-sulfonamides 失效
标题翻译：用于制备5-甲基 - 正 - （芳基）-1,2,4-三唑并（1,5-A）嘧啶-2-磺酰胺的水性方法
公开(公告)号：US4988812A
公开(公告)日：1991-01-29
申请号：US432241
申请日：1989-11-06
申请人： Kay K. Kim , Richard C. Krauss , Jon A. Orvik
发明人： Kay K. Kim , Richard C. Krauss , Jon A. Orvik
IPC分类号： A01N43/90 , C07D249/14 , C07D487/04
CPC分类号： C07D487/04
摘要： 5-Methyl-N-(aryl)-1,2,4-triazolo[1,5-a]-pyrimidine-2-sulfonamides are prepared by the cyclization of N -(3-(((aryl)amino)sulfonyl)-1H-1,2,4-triazol-5-yl)amines with 4-methoxy-3-butene-2-one or its synthetic equivalents in the presence of an aqueous base. By controlling the pH of the condensation between 8.5 and 10.5, by-product formation can be substantially reduced.

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