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    • 1. 发明授权
    • Carbon aerogels for supercapacitors and method of manufacturing the same
    • 超级电容器的碳气凝胶及其制造方法
    • US08480930B2
    • 2013-07-09
    • US12740606
    • 2008-10-09
    • Dong Jin SuhTae Jin ParkYoung-Woong SuhYoung Hyun YoonHyun-Joong Kim
    • Dong Jin SuhTae Jin ParkYoung-Woong SuhYoung Hyun YoonHyun-Joong Kim
    • H01B1/04
    • H01G11/32B01J13/0091C01B32/05C04B35/524C04B35/62655C04B38/00H01G11/34Y02E60/13Y02P20/124C04B35/52
    • A method for preparing carbon aerogels and carbon aerogels obtained therefrom are disclosed. The method for preparing carbon aerogels comprises: mixing organic starting materials including phloroglucinol and furfural with a solvent capable of dissolving the organic materials in a predetermined ratio to form a sol solution; adjusting pH of the sol solution adequately by using an acidic or basic catalyst, gelling the sol solution at room temperature under atmospheric pressure, and aging the resultant gels; substituting the solvent in thus obtained gels with liquid carbon dioxide, followed by drying in a supercritical state, to form organic aerogels; and pyrolyzing the organic aerogels in an electric furnace under inert atmosphere to obtain carbon aerogels. Particularly, the gels are formed at room temperature in a short period of time by adequately adjusting pH of the sol solution. Therefore, the method provides improved time efficiency and energy efficiency as compared to existing methods for preparing gels. Additionally, the method allows supercritical drying while avoiding a need for an additional solvent substitution, thereby simplifying the overall process. Further, the method enables preparation of carbon aerogels for supercapacitors having a high specific surface area and high capacitance even in the absence of additional activation step.
    • 公开了制备碳气凝胶和碳气凝胶的方法。 制备碳气凝胶的方法包括:将含有间苯三酚和糠醛的有机原料与能够以有规定比例溶解有机物质的溶剂混合形成溶胶溶液; 通过使用酸性或碱性催化剂充分调节溶胶溶液的pH,在室温下在大气压下胶凝溶胶溶液,并使所得凝胶老化; 用液态二氧化碳代替所得凝胶中的溶剂,然后以超临界状态干燥,形成有机气凝胶; 并在惰性气氛下在电炉中热解有机气凝胶,得到碳气凝胶。 特别地,通过充分调节溶胶溶液的pH,在室温下在短时间内形成凝胶。 因此,与用于制备凝胶的现有方法相比,该方法提供了改进的时间效率和能量效率。 此外,该方法允许超临界干燥,同时避免需要另外的溶剂置换,从而简化了整个过程。 此外,即使在没有额外的活化步骤的情况下,该方法也可以制备具有高比表面积和高电容的超级电容器的碳气凝胶。
    • 2. 发明申请
    • Carbon Aerogels for Supercapacitors and Method of Manufacturing the Same
    • 超级电容器的碳气凝胶及其制造方法
    • US20100310847A1
    • 2010-12-09
    • US12740606
    • 2008-10-09
    • Dong Jin SuhTae Jin ParkYoung-Woong SuhYoung Hyun YoonHyun-Joong Kim
    • Dong Jin SuhTae Jin ParkYoung-Woong SuhYoung Hyun YoonHyun-Joong Kim
    • H01B1/04B32B5/18
    • H01G11/32B01J13/0091C01B32/05C04B35/524C04B35/62655C04B38/00H01G11/34Y02E60/13Y02P20/124C04B35/52
    • A method for preparing carbon aerogels and carbon aerogels obtained therefrom are disclosed. The method for preparing carbon aerogels comprises: mixing organic starting materials including phloroglucinol and furfural with a solvent capable of dissolving the organic materials in a predetermined ratio to form a sol solution; adjusting pH of the sol solution adequately by using an acidic or basic catalyst, gelling the sol solution at room temperature under atmospheric pressure, and aging the resultant gels; substituting the solvent in thus obtained gels with liquid carbon dioxide, followed by drying in a supercritical state, to form organic aerogels; and pyrolyzing the organic aerogels in an electric furnace under inert atmosphere to obtain carbon aerogels. Particularly, the gels are formed at room temperature in a short period of time by adequately adjusting pH of the sol solution. Therefore, the method provides improved time efficiency and energy efficiency as compared to existing methods for preparing gels. Additionally, the method allows supercritical drying while avoiding a need for an additional solvent substitution, thereby simplifying the overall process. Further, the method enables preparation of carbon aerogels for supercapacitors having a high specific surface area and high capacitance even in the absence of additional activation step.
    • 公开了制备碳气凝胶和碳气凝胶的方法。 制备碳气凝胶的方法包括:将含有间苯三酚和糠醛的有机原料与能够以有规定比例溶解有机物质的溶剂混合形成溶胶溶液; 通过使用酸性或碱性催化剂充分调节溶胶溶液的pH,在室温下在大气压下胶凝溶胶溶液,并使所得凝胶老化; 用液态二氧化碳代替所得凝胶中的溶剂,然后以超临界状态干燥,形成有机气凝胶; 并在惰性气氛下在电炉中热解有机气凝胶,得到碳气凝胶。 特别地,通过充分调节溶胶溶液的pH,在室温下在短时间内形成凝胶。 因此,与用于制备凝胶的现有方法相比,该方法提供了改进的时间效率和能量效率。 此外,该方法允许超临界干燥,同时避免需要另外的溶剂置换,从而简化了整个过程。 此外,即使在没有额外的活化步骤的情况下,该方法也可以制备具有高比表面积和高电容的超级电容器的碳气凝胶。
    • 3. 发明申请
    • Vanadia-Titania Aerogel Catalysts, Preparing Method of The Same, and Oxidative Destruction of Chlorinated Aromatic Compounds Using The Same
    • 钒酸二氧化钛气凝胶催化剂,其制备方法及使用其的氯化芳族化合物的氧化破坏
    • US20090202420A1
    • 2009-08-13
    • US12428329
    • 2009-04-22
    • Dong Jin SuhTae Jin ParkYoung Hyun YoonJin Soon Choi
    • Dong Jin SuhTae Jin ParkYoung Hyun YoonJin Soon Choi
    • C01B31/18
    • B01J23/22B01D53/8662B01J21/063B01J23/34B01J37/036
    • Disclosed are a vanadia-titania aerogel catalyst having high specific surface area and porosity, a method of preparing the same and a method of completely oxidatively-decomposing a chlorinated aromatic compound using the catalyst under air condition. The vanadia-titania aerogel catalyst of the invention is an aerogel form having many porosities and a high specific surface area obtained by performing a supercritical drying of vanadia-titania wet gel, which is prepared by a sol-gel method, with carbon dioxide and then firing the dried vanadia-titania, with a micro porosity structure being maintained, consists of vanadia and titania wherein a content of the vanadia is 1˜15 wt % of an overall catalyst weight. In addition, according to the invention, the vanadia-titania aerogel catalyst may further comprise a manganese oxide of 1˜5 wt % or a sulfur component of 0.0001˜1 wt %. Since the vanadia-titania aerogle catalyst of the invention has the very high conversion rate and selectivity for the complete oxidation reaction of the chlorinated aromatic compound and is very thermally stable, it can be usefully used in the oxidation reaction having a high heating value capable of generating local heat spots.
    • 公开了具有高比表面积和孔隙率的氧化钒 - 二氧化钛气凝胶催化剂,其制备方法和使用该催化剂在空气条件下完全氧化分解氯化芳族化合物的方法。 本发明的氧化钒 - 二氧化钛气凝胶催化剂是具有许多孔隙率和高比表面积的气凝胶形式,其通过使用溶胶 - 凝胶法制备的氧化钒 - 二氧化钛湿凝胶用二氧化碳进行超临界干燥,然后 焙烧干燥的氧化钒 - 二氧化钛,保持微孔结构,由氧钒和二氧化钛组成,其中氧钒的含量为总催化剂重量的1〜15重量%。 此外,根据本发明,氧化钒 - 二氧化钛气凝胶催化剂还可以包含1〜5重量%的氧化锰或0.0001〜1重量%的硫成分。 由于本发明的氧化钒 - 二氧化钛气溶胶催化剂对氯化芳族化合物的完全氧化反应具有非常高的转化率和选择性,并且非常热稳定,因此可以有用地用于具有高热值的氧化反应 产生局部热点。
    • 5. 发明申请
    • Vanadia-Titania Aerogel Catalysts, Preparing Method of the Same, and Oxidative Destruction of Chlorinated Aromatic Compounds Using the Same
    • Vanadia-Titania气凝胶催化剂,其制备方法及使用其的氯化芳族化合物的氧化破坏
    • US20090081111A1
    • 2009-03-26
    • US11720724
    • 2005-11-29
    • Dong Jin SuhTae Jin ParkYoung Hyun YoonJin Soon Choi
    • Dong Jin SuhTae Jin ParkYoung Hyun YoonJin Soon Choi
    • C01B31/18B01J23/22B01J23/34B01J27/02B01J27/053C01B31/20
    • B01J23/22B01D53/8662B01J21/063B01J23/34B01J37/036
    • Disclosed are a vanadia-titania aerogel catalyst having high specific surface area and porosity, a method of preparing the same and a method of completely oxidatively-decomposing a chlorinated aromatic compound using the catalyst under air condition. The vanadia-titania aerogel catalyst of the invention is an aerogel form having many porosities and a high specific surface area obtained by performing a supercritical drying of vanadia-titania wet gel, which is prepared by a sol-gel method, with carbon dioxide and then firing the dried vanadia-titania, with a micro porosity structure being maintained, consists of vanadia and titania wherein a content of the vanadia is 1˜15 wt % of an overall catalyst weight. In addition, according to the invention, the vanadia-titania aerogel catalyst may further comprise a manganese oxide of 1-5 wt % or a sulfur component of 0.0001-1 wt %. Since the vanadia-titania aerogle catalyst of the invention has the very high conversion rate and selectivity for the complete oxidation reaction of the chlorinated aromatic compound and is very thermally stable, it can be usefully used in the oxidation reaction having a high heating value capable of generating local heat spots.
    • 公开了具有高比表面积和孔隙率的氧化钒 - 二氧化钛气凝胶催化剂,其制备方法和使用该催化剂在空气条件下完全氧化分解氯化芳族化合物的方法。 本发明的氧化钒 - 二氧化钛气凝胶催化剂是具有许多孔隙率和高比表面积的气凝胶形式,其通过使用溶胶 - 凝胶法制备的氧化钒 - 二氧化钛湿凝胶用二氧化碳进行超临界干燥,然后 焙烧干燥的氧化钒 - 二氧化钛,保持微孔结构,由氧钒和二氧化钛组成,其中氧钒的含量为总催化剂重量的1〜15重量%。 此外,根据本发明,氧化钒 - 二氧化钛气凝胶催化剂还可以包含1-5重量%的氧化锰或0.0001-1重量%的硫成分。 由于本发明的氧化钒 - 二氧化钛气溶胶催化剂对氯化芳族化合物的完全氧化反应具有非常高的转化率和选择性,并且非常热稳定,因此可以有用地用于具有高热值的氧化反应 产生局部热点。
    • 7. 发明授权
    • QoS-based routing method
    • 基于QoS的路由方法
    • US06813272B1
    • 2004-11-02
    • US09595862
    • 2000-06-16
    • Sun Shin AnYoung Hyun YoonEun Ho ChoiHong Beom JeonDoo Seok Kim
    • Sun Shin AnYoung Hyun YoonEun Ho ChoiHong Beom JeonDoo Seok Kim
    • H04L1228
    • H04L45/12H04L45/02H04L45/302H04L45/52
    • A routing method with routing algorithms applicable to a one-level hierarchical network, including a first algorithm in which a shortest one among all paths established in association with one destination is selected, a second algorithm in which the first method is conducted in a distributed fashion to achieve a fast routing, and a third algorithm in which any one of paths established in association with one destination may be selected as a shortest path when the QoS value calculated in association therewith is more optimum than a required reference QoS value, for preventing problems caused by errors at the single path. The method also provides algorithms that are modified versions of the second and third algorithm for the multi-level hierarchical network. Accordingly, the method is advantageous in that users can select an algorithm, most suitable for the system environment, from the above algorithms.
    • 一种具有适用于一级分层网络的路由算法的路由方法,包括选择与一个目的地相关联的所有路径中的最短路径的第一算法,其中第一种方法以分布式方式进行的第二算法 以实现快速路由,以及第三算法,其中当与一个目的地相关联地建立的任何一个路径可以被选择为当与其相关联地计算的QoS值比所需参考QoS值更优化时作为最短路径,以防止问题 由单路径错误引起。 该方法还提供了用于多级分层网络的第二和第三算法的修改版本的算法。 因此,该方法的优点在于,用户可以从上述算法中选择最适合于系统环境的算法。