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    • 2. 发明授权
    • Method of operating chlor-alkali electrolytic cells
    • 氯碱电解池操作方法
    • US06296745B1
    • 2001-10-02
    • US09560598
    • 2000-04-28
    • Donald W. DuBoisBernard A. Maloney
    • Donald W. DuBoisBernard A. Maloney
    • C25C706
    • C25B13/00C25B1/46
    • A method of operating a chlor-alkali electrolytic cell comprising a catholyte compartment containing a cathode, an anolyte compartment containing an anode, and a liquid-permeable diaphragm partitioning the catholyte and anolyte compartments, is described. The method comprises adding water-insoluble inorganic particulate material, e.g., clay mineral, and alkali metal polyphosphate, e.g., tetrasodium pyrophosphate, to the anolyte compartment of the electrolytic cell while the cell is operating. The water-insoluble inorganic particulate material and alkali metal polyphosphate may be added to the anolyte compartment in the form of an aqueous slurry.
    • 描述了一种操作氯碱电解池的方法,该电解池包括含有阴极的阴极电解室,含有阳极的阳极电解液室和分隔阴极电解液和阳极电解液室的液体可透过隔膜。 该方法包括在细胞运行时将诸如粘土矿物的水不溶性无机颗粒材料和焦磷酸四钠的碱金属多磷酸盐加入到电解池的阳极电解液室中。 水不溶性无机颗粒材料和碱金属多磷酸盐可以以含水浆料的形式加入到阳极电解液室中。
    • 3. 发明授权
    • Method of preparing a diaphragm for an electrolytic cell
    • 制备电解槽隔膜的方法
    • US06299939B1
    • 2001-10-09
    • US09560599
    • 2000-04-28
    • Donald W. DuBoisBernard A. Maloney
    • Donald W. DuBoisBernard A. Maloney
    • B05D500
    • C25B13/04
    • A method of forming a liquid-permeable asbestos-free diaphragm for use in an electrolytic cell (e.g., a chlor-alkali cell) is described. The method comprises, (a) forming a liquid-permeable diaphragm base mat of asbestos-free material on a foraminous structure (e.g., a foraminous cathode structure); (b) drawing through the base mat a topcoat slurry comprising an aqueous medium (e.g., deionized water), water-insoluble inorganic particulate material (e.g., attapulgite clay) and alkali metal polyphosphate (e.g., tetrasodium pyrophosphate decahydrate); and (c) drying the formed diaphragm. The inorganic material of the topcoat slurry is deposited on and within the diaphragm base mat.
    • 描述了形成用于电解槽(例如氯碱池)中的透液性无石棉隔膜的方法。 该方法包括:(a)在多孔结构(例如,多孔阴极结构)上形成无石棉材料的透液膜基垫; (b)通过基底垫将包含水性介质(例如去离子水),水不溶性无机颗粒材料(例如绿坡缕石粘土)和碱金属多磷酸盐(例如焦磷酸四钠十水合物)的面漆浆液拉伸; 和(c)干燥所形成的隔膜。 面漆浆料的无机材料沉积在隔膜基垫上和内。
    • 4. 发明授权
    • Diaphragm for electrolytic cell
    • 电解槽隔膜
    • US6059944A
    • 2000-05-09
    • US124441
    • 1998-07-29
    • Donald W. DuBoisBernard A. MaloneyJerry N. Kinney
    • Donald W. DuBoisBernard A. MaloneyJerry N. Kinney
    • C25B13/04C25B13/06
    • C25B13/04
    • A method of forming a liquid-permeable asbestos-free diaphragm on a cathode structure is described. The method comprises forming a liquid-permeable diaphragm base mat comprising fibrous synthetic polymeric material, e.g., polytetrafluoroethylene, on a cathode structure, e.g., a foraminous cathode; drawing a liquid slurry comprising an aqueous medium containing a wetting amount of surfactant and water-insoluble inorganic particulate material through the base mat, thereby to deposit said inorganic particulate material on and within the pre-formed base mat; and drying the resultant diaphragm at temperatures less than the temperature at which decomposition by-products of the surfactant are formed. The liquid slurry is substantially free of alkali metal halide and alkali metal hydroxide; and the inorganic particulate material comprises at least one oxide or silicate of a valve metal, e.g., zirconium oxide, having a median diameter of 0.1 to 5 micrometers, and optionally clay mineral and/or hydrous oxide of zirconium and/or magnesium. In a further embodiment of the present invention, the base mat is dried prior to deposition of the inorganic particulate material.
    • 描述了在阴极结构上形成液体渗透性无石棉隔膜的方法。 该方法包括在阴极结构(例如多孔阴极)上形成包含纤维状合成聚合物材料(例如聚四氟乙烯)的液体可渗透膜基底垫; 拉制包含含有润湿量的表面活性剂和水不溶性无机颗粒材料的水性介质的液体浆料通过基垫,从而将所述无机颗粒材料沉积在预成型的基垫上和内; 并且在低于形成表面活性剂分解副产物的温度的温度下干燥所得的隔膜。 液体浆料基本上不含碱金属卤化物和碱金属氢氧化物; 并且无机颗粒材料包含至少一种中等直径为0.1至5微米的阀金属例如氧化锆的氧化物或硅酸盐,以及任选的锆和/或镁的粘土矿物和/或含氧化合物。 在本发明的另一个实施方案中,在沉积无机颗粒材料之前将基底垫干燥。