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    • 4. 发明授权
    • Method for producing singlet molecular oxygen
    • 单线态分子氧的制备方法
    • US4102950A
    • 1978-07-25
    • US823910
    • 1977-08-12
    • Donald PilipovichIra B. GoldbergRoss I. Wagner
    • Donald PilipovichIra B. GoldbergRoss I. Wagner
    • C01B13/02
    • C01B13/0214
    • A method and generator are provided for producing singlet molecular oxygen, O.sub.2 (.sup.1 .DELTA..sub.g). A hypohalite selected from the group consisting of BrSO.sub.3 F, BrNO.sub.3, BrOCF.sub.3, ClSO.sub.3 F, ClNO.sub.3, Cl0CF.sub.3, FSO.sub.3 F, FOCF.sub.3, and ISO.sub.3 F, is reacted with hydrogen peroxide to produce singlet molecular oxygen. A preferred embodiment of the reaction is illustrated by the following example:ClSO.sub.3 F + H.sub.2 O.sub.2 .fwdarw. O.sub.2 (.sup.1 .DELTA..sub.g) + HSO.sub.3 F + HCl.The generator for producing the singlet molecular oxygen is a reactor vessel having nozzles for introducing the chlorine fluorosulfate and hydrogen peroxide into the vessel. An outlet is provided for withdrawing the products, and the singlet molecular oxygen is separated by condensing out the other products in a condensor.
    • 提供了一种方法和发生器,用于产生单分子氧,O 2(1 DELTA g)。 选自BrSO 3 F,BrNO 3,BrOCF 3,ClSO 3 F,ClNO 3,ClOCF 3,FSO 3 F,FOCF 3和ISO 3 F的次卤酸盐与过氧化氢反应以产生单线态分子氧。 反应的优选实施方案由以下实施例说明: