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    • 1. 发明授权
    • Salt-based melting process
    • 盐基熔化工艺
    • US5057194A
    • 1991-10-15
    • US435502
    • 1989-10-13
    • Donald L. StewartJan H. L. Van LindenAlfred F. LaCameraThomas V. PierceJames O. ParkhillJohn M. UrbanicThomas R. Hornack
    • Donald L. StewartJan H. L. Van LindenAlfred F. LaCameraThomas V. PierceJames O. ParkhillJohn M. UrbanicThomas R. Hornack
    • C22B9/10C22B21/00C22B26/12C25C3/00C25C3/02C25C3/04C25C3/06C25C3/12C25C7/02
    • C22B26/12C22B21/0046C22B21/0069C22B21/0092C22B9/106C25C3/00C25C3/02C25C3/04C25C3/06C25C3/125C25C7/025Y02P10/214Y02P10/218Y02P10/226
    • A continuous salt-based process is provided for melting and reclaiming aluminum from aluminum scrap containing impurities including heating a molten salt in a heat bay, mixing the heated salt with aluminum scrap or skim in a charge bay to form a molten charge mixture, separating aluminum from impurities in the charge bay by coalescing aluminum to form a molten aluminum metal pad, chlorinating a portion of the charge mixture from the charge bay to form a chlorinated salt mixture and metal chlorides, removing metal chlorides from the salt mixture, and feeding the salt mixture back to the heat bay. In one aspect, the chlorinating step of the present invention includes introducing carbon monoxide or, preferably, solid carbon to control oxide concentration. The process further comprises adding fluorides and removing metal chlorides from the salt to maintain a preferred salt composition. The metal chlorides can be removed by withdrawing volatile metal chloride gases and electrolytically reducing metal chlorides in the molten salt. A further aspect of the invention permits direct reduction of oxide impurities in the salt by electrolysis. In another aspect of the invention, the scrap itself is used as a consumable heating electrode (i.e., disappearing as the scrap melts) for heating the molten salt. An additional aspect of the invention provides that the molten salt is pumped past heating electrodes, which reduces hot spots that otherwise would lead to fuming and cause instability in the molten bath composition. Yet another aspect of the invention permits removal of carbon impurities, which can be introduced to the molten salt when melting of the scrap causes pyrolysis of organic material associated with the scrap, for example, the lacquer coating on beverage cans.
    • PCT No.PCT / US88 / 02374 371日期:1989年10月13日 102(e)日期1989年10月13日PCT Filed 1988年7月19日PCT Pub。 第WO89 / 06291号公报 日期为1989年7月13日。提供了一种连续的盐基方法,用于从含有杂质的铝废料中熔化和回收铝,包括在加热室中加热熔融盐,将加热的盐与铝废料或脱脂在电荷室中混合形成 熔融充料混合物,通过聚集铝形成熔融铝金属垫将铝与电荷隔室中的杂质分离,从电荷室氯化一部分电荷混合物以形成氯化盐混合物和金属氯化物,从金属氯化物中除去金属氯化物 盐混合物,并将盐混合物送回加热室。 一方面,本发明的氯化步骤包括引入一氧化碳或优选固体碳以控制氧化物浓度。 该方法还包括加入氟化物并从盐中除去金属氯化物以保持优选的盐组成。 可以通过抽出挥发性金属氯化物气体和电解还原金属氯化物来除去金属氯化物。 本发明的另一方面允许通过电解直接还原盐中的氧化物杂质。 在本发明的另一方面,废料本身用作可消耗的加热电极(即当废料熔化时消失)用于加热熔融盐。 本发明的另一方面提供了熔融盐被泵送通过加热电极,这减少了热点,否则会导致发烟并导致熔融浴组合物不稳定。 本发明的另一方面允许去除碳杂质,其可以在熔融废料时引入熔融盐,导致与废料相关的有机材料的热解,例如饮料罐上的漆层。