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1. 发明申请

US20080221363A1 Process for the Monosulfonation of Aromatic Phosphines, and Zwitterionic Product Derived Therefrom 有权
标题翻译：芳香膦单磺化方法及其衍生的两性离子产物
公开(公告)号：US20080221363A1
公开(公告)日：2008-09-11
申请号：US12064064
申请日：2006-09-14
申请人： Donald L. Morrison , Kurt D. Olson , Walter C. Reed , Anthony G. Abatjoglou
发明人： Donald L. Morrison , Kurt D. Olson , Walter C. Reed , Anthony G. Abatjoglou
IPC分类号： C07F9/54
CPC分类号： C07F9/5022 , C07F9/5442 , C07F9/5449
摘要： A method of preparing an aromatic phosphine monosulfonate in zwitterionic form, such as dicyclohexylphenylphosphine monosulfonate zwitterion, involving contacting an aromatic phosphine with a sulfonating agent to provide a reaction mixture containing aromatic phosphine monosulfonate in acid form and unconverted sulfonating agent; quenching or removing substantially all of the unconverted sulfonating agent; partially neutralizing the aromatic phosphine monosulfonate in acid form to phase separate aromatic phosphine monosulfonate in zwitterionic form as a solid or neat liquid layer; and collecting the zwitterion as a solid or neat liquid. The zwitterion may be neutralized to form the corresponding aromatic phosphine monosulfonate metal salt, which is useful in preparing catalysts for hydroformylation processes.
摘要翻译：一种以两性离子形式制备芳族膦单磺酸盐如二环己基苯基膦单磺酸盐两性离子的方法，包括使芳族膦与磺化剂接触以提供含有酸形式的芳族膦单磺酸盐和未转化的磺化剂的反应混合物; 淬火或去除基本上所有未转化的磺化剂; 部分中和酸形式的芳族膦单磺酸盐作为固体或纯液体层以两性离子形式相分离芳香族膦单磺酸盐; 并收集两性离子作为固体或纯净液体。两性离子可以被中和形成相应的芳族膦单磺酸盐金属盐，其可用于制备用于加氢甲酰化方法的催化剂。

2. 发明授权

US07754924B2 Process for the monosulfonation of aromatic phosphines, and zwitterionic product derived therefrom 有权
标题翻译：芳香膦单磺化的方法和由其衍生的两性离子产物
公开(公告)号：US07754924B2
公开(公告)日：2010-07-13
申请号：US12064064
申请日：2006-09-14
申请人： Donald L. Morrison , Kurt D. Olson , Walter C. Reed , Anthony G. Abatjoglou
发明人： Donald L. Morrison , Kurt D. Olson , Walter C. Reed , Anthony G. Abatjoglou
IPC分类号： C07F5/02
CPC分类号： C07F9/5022 , C07F9/5442 , C07F9/5449
摘要： A method of preparing an aromatic phosphine monosulfonate in zwitterionic form, such as dicyclohexylphenylphosphine monosulfonate zwitterion, involving contacting an aromatic phosphine with a sulfonating agent to provide a reaction mixture containing aromatic phosphine monosulfonate in acid form and unconverted sulfonating agent; quenching or removing substantially all of the unconverted sulfonating agent; partially neutralizing the aromatic phosphine monosulfonate in acid form to phase separate aromatic phosphine monosulfonate in zwitterionic form as a solid or neat liquid layer; and collecting the zwitterion as a solid or neat liquid. The zwitterion may be neutralized to form the corresponding aromatic phosphine monosulfonate metal salt, which is useful in preparing catalysts for hydroformylation processes.
摘要翻译：一种以两性离子形式制备芳族膦单磺酸盐如二环己基苯基膦单磺酸盐两性离子的方法，包括使芳族膦与磺化剂接触以提供含有酸形式的芳族膦单磺酸盐和未转化的磺化剂的反应混合物; 淬火或去除基本上所有未转化的磺化剂; 部分中和酸形式的芳族膦单磺酸盐作为固体或纯液体层以两性离子形式相分离芳香族膦单磺酸盐; 并收集两性离子作为固体或纯净液体。两性离子可以被中和形成相应的芳族膦单磺酸盐金属盐，其可用于制备用于加氢甲酰化方法的催化剂。

3. 发明授权

US07485759B2 Minimization of ligand degradation products, or reversion of same to useful phosphine ligands 有权
标题翻译：配体降解产物的最小化，或者将其还原成有用的膦配体
公开(公告)号：US07485759B2
公开(公告)日：2009-02-03
申请号：US12018841
申请日：2008-01-24
申请人： John R. Briggs , Wei-Jun Peng , Brian M. Roesch , Anthony G. Abatjoglou , Donald L. Morrison
发明人： John R. Briggs , Wei-Jun Peng , Brian M. Roesch , Anthony G. Abatjoglou , Donald L. Morrison
IPC分类号： C07C45/50
CPC分类号： C07F9/5022 , C07C29/16 , C07C45/50 , C07C45/62 , C07C67/38 , C07C33/03 , C07C69/738 , C07C47/21 , C07C47/02
摘要： A process for the minimization of phosphonium ion ligand degradation products formed during reaction of a polyunsaturated olefin or an unconjugated functionalized olefin in the presence of a transition metal-triorganophosphine ligand complex catalyst to form as a product, by-product, or intermediate product a conjugated functionalized olefin having a carbon-carbon double bond conjugated to an α-electron-withdrawing group, such as, an α,β-unsaturated aldehyde, ketone, ester, acid, or nitrile. The minimization process involves conducting the reaction under selected conditions of conversion, temperature, pressure, or a combination thereof; and/or by selecting a triorganophosphine ligand with a specified steric and/or electronic property. Further, a process for reversion of phosphonium ion ligand degradation product(s) back to useful triorganophosphine ligand(s), the reversion involving treating a reaction product fluid containing the degradation product(s) with an inert gas, hydrogen, synthesis gas, or a mixture thereof under conditions sufficient to regenerate the triorganophosphine ligand(s).
摘要翻译：一种在过渡金属 - 三有机膦配体催化剂存在下，在多不饱和烯烃或非共轭官能化烯烃反应期间形成的鏻离子配体降解产物最小化的方法，以形成产物，副产物或中间产物，共轭具有与α-吸电子基团例如α，β-不饱和醛，酮，酯，酸或腈共轭的碳 - 碳双键的官能化烯烃。最小化方法包括在选择的转化条件，温度，压力或其组合下进行反应; 和/或通过选择具有特定空间和/或电子性质的三有机膦配体。此外，将鏻离子配位体降解产物还原回有用的三有机膦配体的方法，涉及用惰性气体，氢气，合成气体或其混合物处理含有降解产物的反应产物流体的逆转其混合物在足以再生三有机膦配体的条件下进行。

4. 发明授权

US07351868B2 Minimization of ligand degradation products, of reversion of same to useful phosphine ligands 有权
标题翻译：最小化配体降解产物，将其转化为有用的膦配体
公开(公告)号：US07351868B2
公开(公告)日：2008-04-01
申请号：US10562602
申请日：2004-06-28
申请人： John R. Briggs , Wei-Jun Peng , Brian M. Roesch , Anthony G. Abatjoglou , Donald L. Morrison
发明人： John R. Briggs , Wei-Jun Peng , Brian M. Roesch , Anthony G. Abatjoglou , Donald L. Morrison
IPC分类号： C07C45/49 , C07F9/02
CPC分类号： C07F9/5022 , C07C29/16 , C07C45/50 , C07C45/62 , C07C67/38 , C07C33/03 , C07C69/738 , C07C47/21 , C07C47/02
摘要： A process for the minimization of phosphonium ion ligand degradation products formed during reaction of a polyunsaturated olefin or an unconjugated functionalized olefin in the presence of a transition metal-triorganophosphine ligand complex catalyst to form as a product, by-product, or intermediate product a conjugated functionalized olefin having a carbon-carbon double bond conjugated to an a-electronwithdrawing group, such as, an a,β-unsaturated aldehyde, ketone, ester, acid, or nitrile. The minimization process involves conducting the reaction under selected conditions of conversion, temperature, pressure, or a combination thereof; and/or by selecting a triorganophosphine ligand with a specified steric and/or electronic property. Further, a process for reversion of phosphonium ion ligand degradation product(s) back to useful triorganophosphine ligand(s), the reversion involving treating a reaction product fluid containing the degradation product(s) with an inert gas, hydrogen, synthesis gas, or a mixture thereof under conditions sufficient to regenerate the triorganophosphine ligand(s).
摘要翻译：一种在过渡金属 - 三有机膦配体催化剂存在下，在多不饱和烯烃或非共轭官能化烯烃反应期间形成的鏻离子配体降解产物最小化的方法，以形成产物，副产物或中间产物，共轭具有与α-电子取向基团例如a不饱和醛，酮，酯，酸或腈共轭的碳 - 碳双键的官能化烯烃。最小化方法包括在选择的转化条件，温度，压力或其组合下进行反应; 和/或通过选择具有特定空间和/或电子性质的三有机膦配体。此外，将鏻离子配位体降解产物还原回有用的三有机膦配体的方法，涉及用惰性气体，氢气，合成气体或其混合物处理含有降解产物的反应产物流体的逆转其混合物在足以再生三有机膦配体的条件下进行。

5. 发明授权

US4789753A Phosphite ligands 失效
标题翻译：亚磷酸酯配体
公开(公告)号：US4789753A
公开(公告)日：1988-12-06
申请号：US107455
申请日：1987-10-13
申请人： Ernst Billig , Anthony G. Abatjoglou , David R. Bryant , Rex E. Murray , John M. Maher
发明人： Ernst Billig , Anthony G. Abatjoglou , David R. Bryant , Rex E. Murray , John M. Maher
IPC分类号： B01J31/18 , C07C45/49 , C07C45/50 , C07C45/82 , C07F9/6574 , C07F9/6578 , C07F15/00 , C07F9/15
CPC分类号： C07F15/008 , B01J31/185 , C07C45/49 , C07C45/50 , C07C45/82 , C07F9/65744 , C07F9/6578 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , Y02P20/582
摘要： Transition metal-diorganophosphite complex catalyzed carbonylation processes, especially hydroformylation, as well as transition metal-diorganophosphite ligand complex compositions, diorganophosphite ligands and transition metal-diorganophosphite catalysts.
摘要翻译：过渡金属 - 二有机亚磷酸酯复合催化羰基化过程，特别是加氢甲酰化反应，以及过渡金属 - 二有机亚磷酸酯配位体配合物组合物，二有机亚磷酸酯配体和过渡金属 - 二有机亚磷酸酯催化剂。

6. 发明授权

US4731486A Hydroformylation using low volatile phosphine ligands 失效
标题翻译：使用低挥发性膦配体加氢甲酰化
公开(公告)号：US4731486A
公开(公告)日：1988-03-15
申请号：US932002
申请日：1986-11-18
申请人： Anthony G. Abatjoglou , David R. Bryant
发明人： Anthony G. Abatjoglou , David R. Bryant
IPC分类号： B01J31/24 , B01J31/00 , C07B61/00 , C07C45/00 , C07C45/50 , C07C47/02 , C07C67/00
CPC分类号： C07C45/50 , Y02P20/582
摘要： A nonaqueous hydroformylation process for producing aldehydes using low volatile, organic solubilized monosulfonated tertiary phosphine metal salt ligands.
摘要翻译：使用低挥发性有机溶解的单磺化叔膦金属盐配体生产醛的非水加氢甲酰化方法。

7. 发明授权

US08394978B2 Sulfonated organophosphine compounds and use thereof in hydroformylation processes 有权
标题翻译：磺化有机膦化合物及其在加氢甲酰化方法中的应用
公开(公告)号：US08394978B2
公开(公告)日：2013-03-12
申请号：US12812985
申请日：2009-01-09
申请人： Michael L. Tulchinsky , Anthony G. Abatjoglou
发明人： Michael L. Tulchinsky , Anthony G. Abatjoglou
IPC分类号： C07F15/00
CPC分类号： C07F9/5004 , C07F9/5018
摘要： A compound comprising a sulfonated triorganophosphine of formula R1R2PR3[SO3M)]n, wherein R1 and R2 are selected individually from alkyl, aralkyl, and alicyclic groups; wherein R3 represents a branched divalent or polyvalent, alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents, and further wherein R3 does not contain any aryl moieties; M represents a monovalent cation; and n is an integer representing a total number of sulfonated substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improving ligand and transition metal, e.g., rhodium, recovery and recycling, as compared with prior art ligands.
摘要翻译：包含式R 1 R 2 PR 3 [SO 3 M]] n的磺化三有机膦的化合物，其中R 1和R 2分别选自烷基，芳烷基和脂环基; 其中R3表示与磷原子和一个或多个磺酸酯取代基结合的支链二价或多价亚烷基或脂环族基团，其中R3不含任何芳基部分; M表示一价阳离子; n为代表磺化取代基总数的整数。该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的羰基化形成一种或多种相应的醛产物。与现有技术的配体相比，配体不能进行烷基 - 芳基交换，从而导致配体使用减少并改善配体和过渡金属，例如铑，回收和再循环。

8. 发明申请

US20110054205A1 SULFONATED ORGANOPHOSPHINE COMPOUNDS AND USE THEREOF IN HYDROFORMYLATION PROCESSES 有权
标题翻译：硫化有机磷化合物及其在氢化方法中的应用
公开(公告)号：US20110054205A1
公开(公告)日：2011-03-03
申请号：US12812985
申请日：2009-01-09
申请人： Michael L. Tulchinsky , Anthony G. Abatjoglou
发明人： Michael L. Tulchinsky , Anthony G. Abatjoglou
IPC分类号： C07F9/50 , B01J31/24 , C07C45/49
CPC分类号： C07F9/5004 , C07F9/5018
摘要： A compound comprising a sulfonated triorganophosphine of formula R1R2PR3[SO3M)]n, wherein R1 and R2 are selected individually from alkyl, aralkyl, and alicyclic groups; wherein R3 represents a branched divalent or polyvalent, alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents, and further wherein R3 does not contain any aryl moieties; M represents a monovalent cation; and n is an integer representing a total number of sulfonated substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improving ligand and transition metal, e.g., rhodium, recovery and recycling, as compared with prior art ligands.
摘要翻译：包含式R 1 R 2 PR 3 [SO 3 M]] n的磺化三有机膦的化合物，其中R 1和R 2分别选自烷基，芳烷基和脂环基; 其中R3表示与磷原子和一个或多个磺酸酯取代基结合的支链二价或多价亚烷基或脂环族基团，其中R3不含任何芳基部分; M表示一价阳离子; n为代表磺化取代基总数的整数。该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的羰基化形成一种或多种相应的醛产物。与现有技术的配体相比，配体不能进行烷基 - 芳基交换，从而导致配体使用减少并改善配体和过渡金属，例如铑，回收和再循环。

9. 发明授权

US4670570A Production of carboxylic acids from alcohols using rhodium complex catalysts 失效
标题翻译：使用铑配合物催化剂从醇制备羧酸
公开(公告)号：US4670570A
公开(公告)日：1987-06-02
申请号：US891065
申请日：1986-07-31
申请人： Richard W. Wegman , Anthony G. Abatjoglou
发明人： Richard W. Wegman , Anthony G. Abatjoglou
IPC分类号： C07C67/36 , B01J31/24 , C07B61/00 , C07C51/12 , C07C53/08 , C07C53/122 , C07C69/14 , C01F15/00
CPC分类号： C07C51/12
摘要： A process for the production of organic carboxylic acids by the catalytic reaction of an alcohol and, carbon monoxide in contact with a homogeneous catalyst system of rhodium metal atom, a phosphorus containing ligand in which there is present at least one oxo oxygen atom attached to a phosphorus atom or a carbon atom to form a Z group and the ##STR1## in said Z group is located at least one carbon atom removed from the phosphorus atom of the molecules represented by the formulas ##STR2## and a halogen promoter, under mild reaction conditions, wherein R' is aryl, alkaryl, aralkyl or alkyl, and wherein 1 or more of said R' groups can be substituted with a Z group but not more than 3 of said R' groups in the molecule are so substituted; a is an integer from 0-4; b is an integer from 0-3; and Z is P(O)R'R'; --C(O)OR" or C(O)R", wherein R" is R' or --H.
摘要翻译：通过醇和与铑金属原子的均相催化剂体系接触的一氧化碳，含磷配位体生产有机羧酸的方法，其中存在至少一个氧代氧原子连接到磷原子或碳原子形成Z基团，并且所述Z基团中的“IMAGE”位于从由下式表示的分子的磷原子上除去的至少一个碳原子（V）或（ VI）和卤素促进剂，其中R'是芳基，烷芳基，芳烷基或烷基，并且其中1个或更多个所述R'基团可以被Z基团取代，但不超过3个所述R' 分子中的基团如此取代; a是0-4的整数; b是0-3的整数; Z为P（O）R'R'; -C（O）OR“或C（O）R”，其中R“为R'或-H。

10. 发明授权

US4599206A Transition metal complex catalyzed reactions 失效
公开(公告)号：US4599206A
公开(公告)日：1986-07-08
申请号：US685025
申请日：1984-12-28
申请人： Ernst Billig , Anthony G. Abatjoglou , David R. Bryant , Rex E. Murray , John M. Mather
发明人： Ernst Billig , Anthony G. Abatjoglou , David R. Bryant , Rex E. Murray , John M. Mather
IPC分类号： C07C47/02 , B01J27/18 , B01J31/18 , B01J31/20 , C07B61/00 , C07C45/00 , C07C45/50 , C07C67/00 , C07F9/06 , C07F9/547 , C07F9/6564 , C07F9/6574 , C07F9/6578 , C07F15/00 , C07F9/02
CPC分类号： C07F15/008 , B01J31/185 , C07C45/50 , C07F9/65744 , C07F9/6578 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , Y02P20/582
摘要： Transition metal-diorganophosphite complex catalyzed carbonylation processes, especially hydroformylation, as well as transition metal-diorganophosphite ligand complex compositions, diorganophosphite ligands and transition metal-diorganophosphite catalysts.

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