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    • 1. 发明授权
    • Refractive index detector
    • 折射率检测器
    • US3999857A
    • 1976-12-28
    • US582064
    • 1975-05-29
    • Donald J. DavidDavid A. ShawHuel C. Tucker
    • Donald J. DavidDavid A. ShawHuel C. Tucker
    • G01N21/43G01N21/46
    • G01N21/431
    • A refractive index detector is described comprising a waveguide, means for contacting said waveguide with a fluid, a light source and means to transmit light into said waveguide, means for detecting light exiting from said waveguide as an indication of the refractive index of said fluid and means to automatically change the angle of incidence of the light entering said waveguide in response to changes of refractive index of said fluid. A preferred embodiment of the detector for use as a detector for gradient elution chromatography has means to indicate the rate of change of refractive index. A preferred means to automatically change the angle of incidence of the light entering the waveguide is a movable prism. It is preferred to use a monochromatic light source in the detector. It is preferred to provide reference means for the detector to compensate for changes in intensity of the light output from said light source. A process for determining the refractive index of effluent from a gradient elution liquid chromatograph is described comprising continuously measuring the differential of the refractive index of said effluent to compensate for the change in refractive index resulting from the continuously changing composition of the elution solution.
    • 描述了一种折射率检测器,其包括波导,用于使所述波导与流体接触的装置,光源和将光透射到所述波导中的装置,用于检测从所述波导出射的光作为所述流体的折射率的指示; 用于响应于所述流体的折射率的变化而自动改变进入所述波导的光的入射角的装置。 用作梯度洗脱色谱检测器的检测器的优选实施方案具有指示折射率变化率的装置。 自动改变进入波导管的光的入射角的优选方法是可动棱镜。 优选在检测器中使用单色光源。 优选提供用于检测器的参考装置以补偿从所述光源输出的光的强度变化。 描述了用于确定来自梯度洗脱液相色谱仪的流出物的折射率的方法,其包括连续测量所述流出物的折射率的差异,以补偿由洗脱溶液的连续变化的组成引起的折射率的变化。
    • 2. 发明授权
    • Electronic system for providing specificity in an electrochemical
analytical device
    • 用于在电化学分析装置中提供特异性的电子系统
    • US4048041A
    • 1977-09-13
    • US689287
    • 1976-05-24
    • Donald J. DavidHuel C. Tucker
    • Donald J. DavidHuel C. Tucker
    • G01N27/416G01N27/48
    • G01N27/48
    • An electronic circuit is used to continuously determine the nitroglycerin ncentration in a sample solution of an electrochemical monitoring cell by controlling the applied potential to a cathode electrode of a three element cell. The cathode of the electrochemical cell is maintained at a desired potential by supplying a square wave modulated negative potential signal thereto and then measuring the difference in cell current between the cathode and anode elements at the start and finish of the pulse signal with a demodulator. Current from any additional reactions that are constant or that occur above a desired reduction potential within the electrochemical cell are automatically cancelled by a gating circuit which is electrically coupled to the demodulator.
    • 电子电路用于通过控制施加到三元电池的阴极的电位来连续地确定电化学监测电池的样品溶液中的硝酸甘油浓度。 通过向其提供方波调制的负电位信号,然后用解调器测量在脉冲信号的开始和结束时阴极和阳极元件之间的电池电流的差异,将电化学电池的阴极保持在期望的电位。 通过电耦合到解调器的选通电路自动地消除来自电化学电池内的所需还原电位以上或恒定的任何附加反应的电流。
    • 8. 发明授权
    • Optical analytical device, waveguide and method
    • 光分析装置,波导和方法
    • US4050895A
    • 1977-09-27
    • US724035
    • 1976-09-17
    • Edgar E. HardyDonald J. David
    • Edgar E. HardyDonald J. David
    • G01N21/55G01N21/77G01N21/22G01N33/16
    • G01N21/7703G01N2021/7709G01N2021/7783Y10S359/90Y10S436/805Y10S436/807Y10T428/2964
    • A device for detecting a first material comprising (a) a waveguide having on a peripheral surface of the waveguide a second material which on contacting the first material selectively combines with the first material to measurably change the light transmitting capabilities of the waveguide, (b) a light source positioned to transmit light into the waveguide, and (c) means for measuring the light exiting from the waveguide. The waveguide described in the previous sentence is a new article of manufacture. The device is useful in a method for detecting a first material comprising the steps of (a) exposing a waveguide having on a peripheral surface of the waveguide a second material to an unknown material which may contain the first material, and second material upon being contacted by the first material selectively combines with the first material to measurably change the light transmitting capabilities of the waveguide; (b) transmitting light through the waveguide after exposure in step (a); and, (c) detecting the light transmitted in step (b) as a measure of the first material. The device and method can be used in either qualitative or quantitative analysis.
    • 一种用于检测第一材料的装置,包括:(a)在波导的外周表面上具有与第一材料接触的第二材料的波导选择性地与第一材料组合以可测量地改变波导的透光能力,(b) 定位成将光传输到波导中的光源,以及(c)用于测量从波导出射的光的装置。 上一句中描述的波导是新的制造品。 该装置可用于检测第一材料的方法,包括以下步骤:(a)将具有第二材料的波导的外周表面上的波导暴露于可能包含第一材料的未知材料,以及在接触时的第二材料 通过第一材料选择性地与第一材料组合以可测量地改变波导的光传输能力; (b)在步骤(a)中曝光后透过光波导; 和(c)检测在步骤(b)中传输的光作为第一材料的量度。 该设备和方法可用于定性或定量分析。
    • 9. 发明授权
    • Process for producing mixed poly(vinyl acetal)s
    • 制备混合聚(乙烯醇缩醛)的方法
    • US5594069A
    • 1997-01-14
    • US387821
    • 1995-02-17
    • Donald J. DavidNestor A. Rotstein
    • Donald J. DavidNestor A. Rotstein
    • C08F8/28
    • C08F8/28
    • A process for producing mixed poly(vinyl acetals) containing butyral acetal groups and long chain acetal groups derived from one or more aldehydes containing at least six C atoms, by conducting an acetalization reaction forming long chain acetal groups in the substantial of absence butyraldehyde until gel break occurs, adding butyraldehyde after gel break and continuing acetalization until the desired reaction endpoint is reached. Reaction temperature is from about 40.degree. C. up to the boiling point of water at the pressure of the acetalization reaction and preferably between about 75.degree. C. and about 98.degree..
    • PCT No.PCT / US92 / 10510 Sec。 371日期:1995年2月17日 102(e)1995年2月17日PCT PCT 1992年12月4日PCT公布。 第WO94 / 13710号公报 日期1994年12月23日制造含有缩丁醛缩醛基的混合聚(乙烯醇缩醛)和由一种或多种含有至少6个C原子的醛衍生的长链缩醛基的方法,通过在实质上进行缩醛化反应形成长链缩醛基 不存在丁醛直至发生凝胶破裂,凝胶断裂后加入丁醛并继续缩醛化直到达到所需的反应终点。 在缩醛化反应的压力下,反应温度为约40℃至水的沸点,优选约75℃至约98℃。