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1. 发明授权

US4427821A Hydrogenation of residual monomers in partially polymerized acrylamide copolymers in latex form 失效
标题翻译：部分聚合的丙烯酰胺共聚物中乳液形式的残余单体的氢化
公开(公告)号：US4427821A
公开(公告)日：1984-01-24
申请号：US443270
申请日：1982-11-22
申请人： Dodd W. Fong , Ronald J. Allain
发明人： Dodd W. Fong , Ronald J. Allain
IPC分类号： C08F6/16 , C08F6/14
CPC分类号： C08F6/16
摘要： A method of reducing the monomer content of water-in-oil emulsions of partially polymerized acrylamide polymers which comprises catalytically hydrogenating the monomer at a temperature not greater than 100.degree. C. and at a pressure below 500 psi.
摘要翻译：一种降低部分聚合的丙烯酰胺聚合物的油包水乳液的单体含量的方法，其包括在不高于100℃和低于500psi的压力下催化氢化单体。

2. 发明授权

US4375529A Hydrogenation of residual monomers in partially polymerized acrylamide copolymers in latex form 失效
标题翻译：部分聚合的丙烯酰胺共聚物中乳液形式残留单体的氢化
公开(公告)号：US4375529A
公开(公告)日：1983-03-01
申请号：US289637
申请日：1981-08-03
申请人： Dodd W. Fong , Ronald J. Allain
发明人： Dodd W. Fong , Ronald J. Allain
IPC分类号： C08F2/32 , C08F6/16
CPC分类号： C08F6/16
摘要： A method of reducing the monomer content of water-in-oil emulsions of partially polymerized acrylamide polymers which comprises catalytically hydrogenating the monomer at a temperature not greater than 100.degree. C. and at a pressure below 500 psi.
摘要翻译：一种降低部分聚合的丙烯酰胺聚合物的油包水乳液的单体含量的方法，其包括在不高于100℃和低于500psi的压力下催化氢化单体。

3. 发明授权

US4347147A Process for preparing overbased magnesium sulfonates 失效
标题翻译：制备高碱性磺酸镁的方法
公开(公告)号：US4347147A
公开(公告)日：1982-08-31
申请号：US213323
申请日：1980-12-05
申请人： Ronald J. Allain , Dodd W. Fong
发明人： Ronald J. Allain , Dodd W. Fong
IPC分类号： C10M159/24 , C10M169/00 , C10M1/40
CPC分类号： C07C309/00 , C10M159/24
摘要： A method of preparing superbased magnesium sulfonates by dispersing MgO in the preformed low viscosity overbased magnesium sulfonates. The low viscosity overbased magnesium sulfonates is prepared by sulfonating an alkyl benzene with a material containing SO.sub.3, preferably oleum, and reacting the alkyl benzene sulfonate with magnesium oxide in the presence of a low viscosity diluent, such as No. 2 oil or LOPS (low odor paraffin solvent), together with water, alcohol, and CO.sub.2. The newness of the method lies in the steps of preferably positively utilizing oleum which contains a minor amount of sulfuric acid as a promoter and utilizing also a surfactant couple of a C.sub.12 -C.sub.18 fatty acid such as oleic acid and an ethanol amide such as a lauryl diethanol amide, which may be Witcamide 5138; where a ready made sulfonate is used, such as SA697 (Conoco), H.sub.2 SO.sub.4 is utilized. In certain instances the amide may be omitted with satisfactory results occurring by using the acid alone.Of particular interest is the preparation of a concentrated magnesium sulfonate wherein the water and alcohol are removed by distillation and a diluent such as LOPS or No. 2 oil is added to produce a slurry.An important feature of this process lies in the reduction in size of the magnesium oxide particles. CO.sub.2 is preferentially bubbled through the mixture after introduction of the magnesium oxide and at a temperature range of 30.degree.-80.degree. C. with stirring. A typical zone of particle size is 40-50% of about 200 A and 50-60% of 0.1-1.0 microns. This is quite advantageous where an emulsion is formulated and the percentage of magnesium is in the area of 14-23% and preferably 20% or over.
摘要翻译：通过将MgO分散在预制的低粘度高碱性磺酸镁中制备高碱性磺酸镁的方法。低粘度高碱性磺酸镁通过用含有SO 3，优选发烟硫酸的材料磺化烷基苯，并在低粘度稀释剂如2号油或LOPS（低）下使烷基苯磺酸盐与氧化镁反应制备气味石蜡溶剂），以及水，酒精和二氧化碳。该方法的新颖性在于优选积极利用含有少量硫酸作为助催化剂的发烟硫酸的步骤，还利用C 12 -C 18脂肪酸如油酸和乙醇酰胺的表面活性剂对，例如月桂基二乙醇酰胺，其可以是Witcamide 5138; 其中使用现成的磺酸盐，例如SA697（Conoco），使用H 2 SO 4。在某些情况下，可以省略酰胺，并通过单独使用酸而发生令人满意的结果。特别令人感兴趣的是制备浓缩的磺酸镁，其中通过蒸馏除去水和醇，并加入稀释剂如LOPS或NO 2油以产生浆料。该方法的一个重要特征在于氧化镁颗粒的尺寸减小。在引入氧化镁后，在搅拌下，在30〜80℃的温度范围内，CO 2优先鼓泡通过混合物。典型的粒度区域是约200A的40-50％和0.1-1.0微米的50-60％。当配制乳液并且镁的百分比在14-23％，优选20％或更高的范围内时，这是非常有利的。

4. 发明授权

US4306983A Process for preparing overbased magnesium sulfonates 失效
标题翻译：制备高碱性磺酸镁的方法
公开(公告)号：US4306983A
公开(公告)日：1981-12-22
申请号：US184156
申请日：1980-09-04
申请人： Ronald J. Allain , Dodd W. Fong
发明人： Ronald J. Allain , Dodd W. Fong
IPC分类号： C10M159/24 , C10M169/00 , C10M1/40
CPC分类号： C07C309/00 , C10M159/24
摘要： A method of preparing overbased or superbased magnesium sulfonates by sulfonating an alkyl benzene with a material containing SO.sub.3, preferably oleum, and reacting the alkyl benzene sulfonate with magnesium oxide in the presence of a low viscosity diluent, such as No. 2 oil or LOPS (low odor paraffin solvent), together with water, alcohol, and CO.sub.2. The newness of the method lies in the steps of preferably positively utilizing oleum which contains a minor amount of sulfuric acid as a promoter and utilizing also a surfactant couple of a C.sub.12 -C.sub.18 fatty acid such as oleic acid and an ethanol amide such as a lauryl diethanol amide, which may be Witcamide 5138; where a ready made sulfonate is used, such as SA697 (Conoco), H.sub.2 SO.sub.4 is utilized. In certain instances the amide may be omitted with satisfactory results occurring by using the acid alone.Of particular interest is the preparation of a concentrated magnesium sulfonate wherein the water and alcohol are removed by distillation and a diluent such as LOPS or No. 2 oil is added to produce a slurry.An important feature of this process lies in the reduction in size of the magnesium oxide particles. CO.sub.2 is preferentially bubbled through the mixture after introduction of the magnesium oxide and at a temperature range of 30.degree.-80.degree. C. with stirring.
摘要翻译：通过用含有SO 3的材料（优选发烟硫酸）磺化烷基苯，并在低粘度稀释剂（如2号油或LOPS）存在下使烷基苯磺酸盐与氧化镁反应来制备高碱性或高碱性磺酸镁的方法低气味石蜡溶剂），以及水，酒精和二氧化碳。该方法的新颖性在于优选积极利用含有少量硫酸作为助催化剂的发烟硫酸的步骤，还利用C 12 -C 18脂肪酸如油酸和乙醇酰胺的表面活性剂对，例如月桂基二乙醇酰胺，其可以是Witcamide 5138; 其中使用现成的磺酸盐，例如SA697（Conoco），使用H 2 SO 4。在某些情况下，可以省略酰胺，并通过单独使用酸而发生令人满意的结果。特别令人感兴趣的是制备浓缩的磺酸镁，其中通过蒸馏除去水和醇，并加入稀释剂如LOPS或NO 2油以产生浆料。该方法的一个重要特征在于氧化镁颗粒的尺寸减小。在引入氧化镁后，在搅拌下，在30〜80℃的温度范围内，CO 2优先鼓泡通过混合物。

5. 发明授权

US4238330A Flotation aids for oil-in-water emulsions 失效
标题翻译：浮选助剂用于水包油乳液
公开(公告)号：US4238330A
公开(公告)日：1980-12-09
申请号：US57663
申请日：1979-07-18
申请人： Dodd W. Fong , Ronald J. Allain
发明人： Dodd W. Fong , Ronald J. Allain
IPC分类号： B01D17/02 , B01D17/05 , B03D1/016 , C10G33/04 , B01D17/04
CPC分类号： C10G33/04 , B01D17/0205 , B03D1/016 , B03D1/01
摘要： An oil-in-water emulsion is separated to float the oil by adding to the emulsion a cationic polyacrylamide.
摘要翻译：通过向乳液中加入阳离子聚丙烯酰胺，将水包油乳液分离以漂浮油。

6. 发明授权

US4216066A Preparation of tetramethyltin from a magnesium-tin alloy 失效
标题翻译：从镁 - 锡合金制备四甲基锡
公开(公告)号：US4216066A
公开(公告)日：1980-08-05
申请号：US15032
申请日：1979-02-26
申请人： Ronald J. Allain , Joseph P. Maniscalco
发明人： Ronald J. Allain , Joseph P. Maniscalco
IPC分类号： C07F7/22 , C25C3/12 , C25B3/12
CPC分类号： C07F7/2212 , C25C3/12
摘要： A method of producing tetramethyltin which comprises the steps of:(a) reacting methyl chloride in an ether solvent with a tin-magnesium alloy containing from 1:1 to 1:2 mole ratio of tin to magnesium whereby a substantial quantity of the methyl chloride is converted to tetramethyltin and methyl magnesium chloride, and then(b) electrolyzing the methyl magnesium chloride in an electrolytic cell containing tin anodes whereby additional quantities of tetramethyltin are produced.
摘要翻译：一种生产四甲基锡的方法，其包括以下步骤：（a）使甲基氯在醚溶剂中与锡与镁的摩尔比为1:1至1:2的锡 - 镁合金反应，由此大量氯甲烷转化为四甲基锡和甲基氯化镁，然后（b）在含有锡阳极的电解池中电解甲基氯化镁，从而产生额外量的四甲基锡。

7. 发明授权

US4208392A Two-step process for removing boron compounds from aqueous solutions of magnesium chloride 失效
标题翻译：从氯化镁水溶液中除去硼化合物的两步法
公开(公告)号：US4208392A
公开(公告)日：1980-06-17
申请号：US23066
申请日：1979-03-23
申请人： Ronald J. Allain , David G. Braithwaite , Ansell L. Reid
发明人： Ronald J. Allain , David G. Braithwaite , Ansell L. Reid
IPC分类号： C01F5/30
CPC分类号： C01F5/30
摘要： A two-step process for removing boron impurities from aqueous solutions of magnesium chloride which comprises treating these solutions with more than 3 moles of methanol in the presence of an acid catalyst to form trimethyl borate and then removing the trimethyl borate and excess methanol from such solutions by means of distillation and then extracting from the thus-treated solutions any remaining boron compounds by means of a hydrocarbon liquid.The hydrocarbon liquid extraction step may be used prior to the methanol treatment.
摘要翻译：一种用于从氯化镁水溶液中除去硼杂质的两步法，其包括在酸催化剂存在下用大于3摩尔甲醇处理这些溶液以形成三甲基硼酸盐，然后从该溶液中除去三甲基硼酸盐和过量的甲醇通过蒸馏，然后通过烃液体从这样处理的溶液中提取任何剩余的硼化合物。烃液体萃取步骤可以在甲醇处理之前使用。

8. 发明授权

US4375003A Method for the hydrogenation of nitriles to primary amines 失效
标题翻译：将腈水解成伯胺的方法
公开(公告)号：US4375003A
公开(公告)日：1983-02-22
申请号：US3138
申请日：1979-01-15
申请人： Ronald J. Allain , Gerald D. Smith
发明人： Ronald J. Allain , Gerald D. Smith
IPC分类号： B01J25/00 , C07C209/48 , C07C85/12
CPC分类号： B01J25/00 , C07C209/48
摘要： An improved process for preparing primary amines from an aliphatic nitrile and hydrogen utilizing a Raney cobalt catalyst which contains from about 2 to 35 weight percent of aluminum on a 100 weight percent total weight basis. Preferably, this catalyst is prepared under low temperature conditions from a cobalt-aluminum alloy. The process can be practiced continuously for extended periods of time at high reaction rates and high conversion yields even when employing concentrated nitrile starting feeds.
摘要翻译：一种利用阮内钴催化剂从脂肪族腈和氢制备伯胺的改进方法，该催化剂以100重量％的总重量计含有约2至35重量％的铝。优选地，该催化剂在钴 - 铝合金的低温条件下制备。即使使用浓缩腈起始原料，该方法可以在高反应速率下连续实施长时间，并且转化率高。

9. 发明授权

US4266068A Preparation of 1,2-tetramethyldichloro-disilane from hexamethyldisilane and methylchlorodisilane 失效
标题翻译：由六甲基二硅烷和甲基氯二硅烷制备1,2-四甲基二氯乙硅烷
公开(公告)号：US4266068A
公开(公告)日：1981-05-05
申请号：US172606
申请日：1980-07-28
申请人： Ronald J. Allain , Joseph P. Maniscalco
发明人： Ronald J. Allain , Joseph P. Maniscalco
IPC分类号： C07F7/12 , C07F7/08
CPC分类号： C07F7/125
摘要： An improved process for producing tetramethyldisilane by Lewis acid catalyzed redistribution of hexamethyldisilane with a crude mixture of methylchlorodisilane which comprises the distillation of the mixed redistributed product with collection of a middle distillate cut containing at least 95% pure tetramethyldichlorodisilane.
摘要翻译：通过路易斯酸催化六甲基硅烷与甲基氯二硅烷的混合物重新分配生产四甲基二硅烷的改进方法，其包括蒸馏混合的再分配产物，收集含有至少95％纯的四甲基二氯二硅烷的中间馏分。

10. 发明授权

US06617421B2 Method for producing substantially dry water-insoluble polymers for improved flocculation in the Bayer process 有权
标题翻译：用于生产基本上干燥的水不溶性聚合物的方法，用于改善拜耳法中的絮凝
公开(公告)号：US06617421B2
公开(公告)日：2003-09-09
申请号：US10059474
申请日：2002-01-29
申请人： Everett C. Phillips , Ronald J. Allain
发明人： Everett C. Phillips , Ronald J. Allain
IPC分类号： C08F614
CPC分类号： C08J3/122 , C01F7/0653 , C08J2333/06
摘要： The present invention is a method of producing substantially dry water insoluble polymers from poly alkyl esters of vinylic monomers for use in a method for the clarification of red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite ore. The polymers can be either homopolymers, copolymers or terpolymers. Preferably, the dried emulsion polymers are high molecular weight polymers of poly(methyl acrylate), poly(methyl acrylate/acrylic acid), poly(vinyl acetate/acrylic acid/methyl acrylate), poly(t-butyl methacrylate/acrylic acid/methyl acrylate) and poly(t-butyl acrylate/acrylic acid/methyl acrylate).
摘要翻译：本发明是一种从乙烯基单体的聚烷基酯生产基本上干燥的水不溶性聚合物的方法，用于澄清在拜耳法中产生的用于从铝土矿矿石回收氧化铝的含红泥的液体的方法。聚合物可以是均聚物，共聚物或三元共聚物。优选地，干燥的乳液聚合物是聚（丙烯酸甲酯），聚（丙烯酸甲酯/丙烯酸），聚（乙酸乙烯酯/丙烯酸/丙烯酸甲酯），聚（甲基丙烯酸叔丁酯/丙烯酸/甲基）丙烯酸酯）和聚（丙烯酸叔丁酯/丙烯酸/丙烯酸甲酯）。

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