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    • 4. 发明申请
    • METHOD FOR PREPARING 5-CHLOROMETHYL-2-FURFURAL USING GALACTAN DERIVED FROM SEAWEED IN TWO COMPONENT PHASE
    • 使用衍生自两个组分相中的海藻糖衍生的5-氯代二甲基丙二酸的方法
    • US20140066641A1
    • 2014-03-06
    • US13985019
    • 2012-02-16
    • Jin-Ku ChoSang-Yong KimDo-Hoon LeeBo Ra KimJae-Won Jung
    • Jin-Ku ChoSang-Yong KimDo-Hoon LeeBo Ra KimJae-Won Jung
    • C07D307/46B01J31/02
    • C07D307/46B01J31/0231
    • The present disclosure relates to an acid catalyst composition for producing 5-chloromethyl-2-furfural from galactan derived from seaweed and a method for producing 5-chloromethyl-2-furfural from galactan derived from seaweed on a two component phase using the acid catalyst, the acid catalyst composition for producing 5-chloromethyl-2-furfural from galactan derived from seaweed including organic solvent and dilute hydrochloric acid, a concentration of the dilute hydrochloric acid being 4N to 8N (normal).According to the present disclosure, there is an advantage of converting 5-chloromethyl-2-furfural from galactan derived from seaweed by means of a single process by mixing dilute hydrochloric acid and organic solvent by an optimal ratio, unlike conventional methods for producing 5-chloromethyl-2-furfural that had to go through a multi-phase process of preconditioning and saccharification.
    • 本公开内容涉及用于从海藻衍生的半乳聚糖制备5-氯甲基-2-糠醛的酸催化剂组合物,以及使用酸催化剂在双组分相上从海藻衍生的半乳聚糖制备5-氯甲基-2-糠醛的方法, 由衍生自海藻的半乳聚糖(包括有机溶剂和稀盐酸)生产5-氯甲基-2-糠醛的酸催化剂组合物,稀盐酸的浓度为4N至8N(正常)。 根据本公开内容,与常规的制备5-氯甲基-2-糠醛的方法相比,通过以单一方法通过混合稀盐酸和有机溶剂以最佳比例将来自海藻的半乳聚糖转化为5-氯甲基-2-糠醛的优点, 氯甲基-2-糠醛,必须经过预处理和糖化的多相过程。
    • 7. 发明授权
    • Metallocene compounds and their use for olefin polymerization
    • 茂金属化合物及其在烯烃聚合中的应用
    • US06506919B1
    • 2003-01-14
    • US09914717
    • 2001-08-31
    • Jae-Seung OhBun-Yeoul LeeJoo-Eun LeeDo-Hoon Lee
    • Jae-Seung OhBun-Yeoul LeeJoo-Eun LeeDo-Hoon Lee
    • C07F1700
    • C08F10/00C07F17/00C08F4/65912C08F4/65916C08F4/65922C08F110/02Y10S526/943C08F4/65925C08F4/6592
    • The present invention relates to a metallocene compound and the olefin polymerization using the same, particularly to a metallocene compound and the olefin polymerization using this compound on which supported catalysts are easily prepared by the reaction of the ligand containing —(CR12)a—O—SiRbYc ligand (wherein each Y, which can be the same as or different from other Y, is a hydrogen, halogen, alkoxy, aryloxy, amide, or silyloxy radical, each R1, which can be the same as or different from other R1, is a hydrogen radical, or an alkyl, cycloalkyl, aryl, alkenyl, alkylaryl, arylalkyl, or arylalkenyl radical having from 1 to 40 carbon atoms, each R, which can be the same as or different from other R, is an alkyl, cycloalkyl, aryl, alkenyl, alkylaryl, arylalkyl, or arylalkenyl radical having from 1 to 40 carbon atoms, a is an integral number from 1 to 40, c is 1, 2, or 3, and the sum of b and c is 3) with a support. Furthermore, the present invention relates to a supported metallocene catalyst using this metallocene compound and the olefin polymerization using the same. The metallocene compounds in this invention have superior characteristics in the preparation of supported catalyst due to the high reactivity with the support and minimal side reactions during the anchoring process. In addition, the olefin polymerization process employing the supported catalyst in this invention proceeds without fouling in the reactor, and the morphology and bulk density of the polymer produced are better than that produced by the conventional method.
    • 本发明涉及茂金属化合物和使用该茂金属化合物的烯烃聚合,特别涉及茂金属化合物和使用该化合物的烯烃聚合,其上通过含有 - (CR12)aO-SiRbYc配体的配体的反应容易地制备负载型催化剂 (其中每个可以与其它Y相同或不同的Y是氢,卤素,烷氧基,芳氧基,酰胺或甲硅烷氧基,每个可以与其它R 1相同或不同的R 1是 氢原子或具有1至40个碳原子的烷基,环烷基,芳基,烯基,烷基芳基,芳基烷基或芳基烯基,每个R可以与其它R相同或不同,是烷基,环烷基,芳基 ,具有1至40个碳原子的烯基,烷基芳基,芳基烷基或芳基烯基,a为1至40的整数,c为1,2或3,b和c之和为3) 。 此外,本发明涉及使用该金属茂化合物的负载金属茂催化剂和使用其的烯烃聚合。 本发明中的茂金属化合物由于与载体的高反应性和锚固过程中的极少副反应而在制备负载型催化剂方面具有优异的特性。 此外,在本发明中使用负载型催化剂的烯烃聚合方法在反应器中不污染地进行,并且所生产的聚合物的形态和体积密度比通过常规方法产生的更好。
    • 8. 发明授权
    • Method for preparing 5-chloromethyl-2-furfural using galactan derived from seaweed in two component phase
    • 使用来自海藻的半乳聚糖在两相组分相中制备5-氯甲基-2-糠醛的方法
    • US08871958B2
    • 2014-10-28
    • US13985019
    • 2012-02-16
    • Jin-Ku ChoSang-Yong KimDo-Hoon LeeBo Ra KimJae-Won Jung
    • Jin-Ku ChoSang-Yong KimDo-Hoon LeeBo Ra KimJae-Won Jung
    • C07D307/46B01J31/02
    • C07D307/46B01J31/0231
    • The present disclosure relates to an acid catalyst composition for producing 5-chloromethyl-2-furfural from galactan derived from seaweed and a method for producing 5-chloromethyl-2-furfural from galactan derived from seaweed on a two component phase using the acid catalyst, the acid catalyst composition for producing 5-chloromethyl-2-furfural from galactan derived from seaweed including organic solvent and dilute hydrochloric acid, a concentration of the dilute hydrochloric acid being 4N to 8N (normal).According to the present disclosure, there is an advantage of converting 5-chloromethyl-2-furfural from galactan derived from seaweed by means of a single process by mixing dilute hydrochloric acid and organic solvent by an optimal ratio, unlike conventional methods for producing 5-chloromethyl-2-furfural that had to go through a multi-phase process of preconditioning and saccharification.
    • 本公开内容涉及用于从海藻衍生的半乳聚糖制备5-氯甲基-2-糠醛的酸催化剂组合物,以及使用酸催化剂在双组分相上从海藻衍生的半乳聚糖制备5-氯甲基-2-糠醛的方法, 由衍生自海藻的半乳聚糖(包括有机溶剂和稀盐酸)生产5-氯甲基-2-糠醛的酸催化剂组合物,稀盐酸的浓度为4N至8N(正常)。 根据本公开内容,与常规的制备5-氯甲基-2-糠醛的方法相比,通过以单一方法通过混合稀盐酸和有机溶剂以最佳比例将来自海藻的半乳聚糖转化为5-氯甲基-2-糠醛的优点, 氯甲基-2-糠醛,必须经过预处理和糖化的多相过程。