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    • 7. 发明授权
    • Process for direct production of low acetaldehyde packaging material
    • 直接生产低乙醛包装材料的方法
    • US5656221A
    • 1997-08-12
    • US518203
    • 1995-08-23
    • Heinz-Dieter SchumannUlrich Thiele
    • Heinz-Dieter SchumannUlrich Thiele
    • C08G63/88B29C47/36B29C47/76
    • C08G63/88
    • Process for direct production of shaped packaging material made of thermoplastic polyesters with no effect on the taste of foods packaged in them, where the diol component of the polyester consists of at least 70 wt % ethylene glycol, and the polyester is produced in the presence of the usual catalysts plus additional cobalt or cobalt and manganese compounds and phosphorus compounds. An inert gas is introduced into the polyester melt and distributed uniformly in the melt immediately after its discharge from the polycondensation reactor, 0.05 to 1.0 wt % of an amide compound with a low volatility is added to the polyester melt directly next to the gas inlet. Finally, the polyester melt is subjected to a vacuum degassing immediately before the shaping apparatus and the melt is sent directly to the shaping apparatus within a maximum of 30 minutes after its discharge from the reactor at a maximum temperature of 35.degree. C. above the crystallite melting point of the polyester.
    • 用于直接生产由热塑性聚酯制成的成形包装材料的方法,其对包装的食品的味道没有影响,其中聚酯的二醇组分由至少70重量%的乙二醇组成,聚酯在 通常的催化剂加上额外的钴或钴和锰化合物和磷化合物。 将惰性气体引入聚酯熔体中,并在从缩聚反应器排出后立即均匀分布在熔体中,将0.05-1.0重量%的具有低挥发性的酰胺化合物加入直接靠近进气口的聚酯熔体中。 最后,聚酯熔体在成型设备之前进行真空脱气,熔体直接从形成设备送出至最大30分钟后,从反应器中排出的最高温度高于微晶35℃ 聚酯的熔点。