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    • 7. 发明授权
    • Magnetic recording discs
    • 磁记录盘
    • US4046932A
    • 1977-09-06
    • US656182
    • 1976-02-09
    • Hans-Joerg HartmannRoland FalkPeter GawlikWerner BalzKarl UhlDieter SchaeferHerbert Motz
    • Hans-Joerg HartmannRoland FalkPeter GawlikWerner BalzKarl UhlDieter SchaeferHerbert Motz
    • G11B5/702H01F10/02
    • G11B5/7023Y10S428/90Y10T428/254Y10T428/257Y10T428/269Y10T428/31529
    • The invention relates to a process for the manufacture of improved magnetic discs by applying a thin layer of a liquid dispersion of magnetic pigments and optionally further, non-magnetic, pigments in a binder mixture to a non-magnetic rigid base, and curing the magnetic coating which has been applied. The binder used is a mixture of polycondensates comprising 60 to 70% by weight of a solid curable polycondensate of 2,2-bis(4-hydroxyphenyl)-propane and epichlorohydrin having an epoxy equivalent weight from about 400 to 2,500 and a melting point from about 50.degree. to 150.degree. C, 10 to 30% by weight of a curable allyloxybenzene-formaldehyde condensate of the resol type with free methylol groups or with methylol groups etherified with a lower alcohol, and having a molecular weight of less than 1,000, and 10 to 30% by weight of a curable melamine-formaldehyde condensate with more than two methylol groups etherified with n-butanol or iso-butanol, and having a molecular weight of less than 2,500. A magnetic dispersion using such a binder allows the application of a firmly adhering magnetic coating, even in thicknesses of less than 4 .mu., to aluminum discs or pre-coated aluminum discs, and the magnetic coating produced has high resistance to mechanical wear.
    • 本发明涉及通过将粘性混合物中的磁性颜料和任选的另外的非磁性颜料的液体分散体的薄层施加到非磁性刚性基底上来制造改进的磁盘的方法,以及固化磁性 已涂覆的涂层。 使用的粘合剂是包含60至70重量%的环氧当量为约400至2,500的2,2-双(4-羟基苯基) - 丙烷和表氯醇的固体可固化缩聚物的缩聚物混合物,熔点为 约50〜150℃,10〜30重量%的甲阶型固化性烯丙氧基苯 - 甲醛缩合物与游离羟甲基或与低级醇醚化的羟甲基,分子量小于1,000,以及 10至30重量%的可固化的三聚氰胺 - 甲醛缩合物,其具有用正丁醇或异丁醇醚化的两个以上羟甲基,分子量小于2500。 使用这种粘合剂的磁性分散体允许对铝盘或预涂铝盘施加甚至厚度小于4微米的牢固粘附的磁性涂层,并且所产生的磁性涂层具有高的耐机械磨损性。
    • 10. 发明授权
    • Magnetic recording media
    • 磁记录媒体
    • US4357378A
    • 1982-11-02
    • US234708
    • 1981-02-17
    • Guenter VaethRudolf BachmannWerner SenkpielHans-Joerg HartmannRoland FalkHerbert Motz
    • Guenter VaethRudolf BachmannWerner SenkpielHans-Joerg HartmannRoland FalkHerbert Motz
    • C09D5/23G11B5/702B32B3/02
    • G11B5/7022Y10S428/90Y10T428/31605Y10T428/31609Y10T428/31699Y10T428/31935
    • The invention relates to magnetic recording media comprising a non-magnetic base and, applied thereto, a firmly adhering magnetic coating based on a finely divided magnetic pigment and a special binder mixture. This binder mixture consists essentially of 20 to 90 percent by weight of an elastomeric polyurethane which is soluble in a volatile organic solvent, is practically free of isocyanate groups and has been obtained from a linear, aliphatic polyester or polyether and a diisocyanate of 6 to 24 carbon atoms, and of 10 to 80 percent by weight of a vinyl chloride copolymer which contains 50 to 90 percent by weight of vinyl chloride units and 10 to 50 percent by weight of units of one or more diesters of maleic acid with an alcohol of 1 to 3 carbon atoms, or of the reaction product of this binder mixture with a polyisocyanate of 6 to 50 carbon atoms. Magnetic coatings containing such a binder mixture are distinguished by improved surface hardness coupled with improved orientability of the magnetic particles, as a result of which such recording media are particularly suitable for modern video- and audio-recording instruments.
    • 本发明涉及包含非磁性基底的磁记录介质,并且在其上施加基于细分磁性颜料和特殊粘合剂混合物的牢固粘附的磁性涂层。 该粘合剂混合物基本上由20至90重量%的可溶于挥发性有机溶剂的弹性体聚氨酯组成,实际上不含异氰酸酯基团,并且由线性脂族聚酯或聚醚和6至24的二异氰酸酯获得 和10至80重量%的氯乙烯共聚物,其含有50至90重量%的氯乙烯单元和10至50重量%的一种或多种马来酸二醇与醇的共聚物1 或者该粘合剂混合物与6至50个碳原子的多异氰酸酯的反应产物。 含有这种粘合剂混合物的磁性涂层的特征在于改进的表面硬度以及磁性颗粒的改进的取向性,结果这种记录介质特别适用于现代的视频和音频记录仪器。