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    • 3. 发明授权
    • Amphiphilic polyesters, preparation thereof, and use thereof in laundry
detergents
    • 两亲性聚酯,其制备方法及其在衣物洗涤剂中的用途
    • US5777046A
    • 1998-07-07
    • US687322
    • 1996-08-05
    • Dieter BoeckhHans-Ulrich JagerGunnar Schornick
    • Dieter BoeckhHans-Ulrich JagerGunnar Schornick
    • C08G63/66C08G63/672C11D3/37C08F20/00
    • C11D3/3715C08G63/66C08G63/672
    • Amphiphilic polyesters containing (a) ester units derived from polyalkylene glycols having a molecular weight of from 500 to 7500 and aliphatic dicarboxylic acids and/or monohydroxymonocarboxylic acids and (b) ester units derived from aromatic dicarboxylic acids and polyhydric alcohols and having molecular weights of from 1500 to 25,000, processes for preparing the amphiphilic polyesters by polycondensation, preparing first (a) aliphatic polyesters of polyalkylene glycols having a molecular weight of from 500 to 7500 with aliphatic dicarboxylic acids and/or monohydroxymonocarboxylic acids and then, within the aliphatic polyester thus obtained, (b) aromatic polyesters from aromatic dicarboxylic acids and polyhydric alcohols, reversing the order of the polycondensation, or condensing oligomeric aromatic polyesters (b) with oligomeric aliphatic polyesters (a), and use of the amphiphilic polyesters as additive in laundry detergents, other laundry detergent additives and laundry aftertreatments.
    • PCT No.PCT / EP95 / 00300 Sec。 371日期:1996年8月5日 102(e)日期1996年8月5日PCT提交1995年1月28日PCT公布。 公开号WO95 / 21880 日期1995年8月17日含有(a)衍生自分子量为500〜7500的聚亚烷基二醇的酯单元和脂族二羧酸和/或单羟基单羧酸的酯双酯和(b)衍生自芳族二羧酸和多元醇的酯单元和 具有1500至25,000的分子量,通过缩聚制备两亲性聚酯的方法,首先使用脂族二羧酸和/或单羟基单羧酸制备分子量为500至7500的聚亚烷基二醇的脂肪族聚酯,然后在 由此获得的脂肪族聚酯,(b)来自芳族二羧酸和多元醇的芳族聚酯,反转缩聚的顺序,或将低聚芳族聚酯(b)与低聚脂族聚酯(a)缩合,并使用两亲性聚酯作为添加剂 在洗衣洗涤剂,其他洗衣洗涤剂添加剂和l 杂项后期。
    • 4. 发明授权
    • Water-soluble copolymers and their preparation
    • 水溶性共聚物及其制备方法
    • US4914172A
    • 1990-04-03
    • US179477
    • 1988-04-08
    • Hans-Peter Seelmann-EggebertDieter BoeckhHeinrich HartmannWolfgang Trieselt
    • Hans-Peter Seelmann-EggebertDieter BoeckhHeinrich HartmannWolfgang Trieselt
    • A01N25/26C08F20/02C08F220/04C08F220/26C08F220/28C08F222/02C08L101/16
    • A01N25/26C08F220/04
    • Water-soluble copolymers having a K value of from 8 to 100 (determined according to H. Fikentscher on sodium salt in aqueous solution at 25.degree. C., a pH of 7 and a polymer concentration of the Na salt of 1% by weight) contain, in polymerized form,(a) not less than 15 mol % of one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids,(b) from 0.5 to 84.5 mol % of one or more ethylenically unsaturated C.sub.4 -C.sub.6 -dicarboxylic acids,(c) from 0 to 20 mol % of one or more hydroxyalkyl esters, where hydroxyalkyl is of 2 to 6 carbon atoms, of monoethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids,(d) from 0 to 30 mol % of other water-soluble, monoethylenically unsaturated monomers copolymerizable with (a), (b) and (c),(e) from 0.5 to 15 mol % of a comonomer which possesses two or more ethylenically unsaturated, nonconjugated double bonds and one or more --CO--OH groups and/or their salt with an alkali metal, ammonium or alkaline earth metal base and, if required,(f) up to 10 mol % of one or more comonomers which differ from (e) and possess two or more ethylenically unsaturated, nonconjugated double bonds,are prepared by copolymerization of the monomers (a) to (f) and are used for coating seed.
    • K值为8〜100(根据H.Fikentscher在25℃的水溶液中的钠盐,pH为7,Na盐的聚合物浓度为1重量%)测定的水溶性共聚物, 含有(a)不小于15摩尔%的一种或多种单烯属不饱和C3-C6-一元羧酸,(b)0.5-84.5摩尔%的一种或多种烯属不饱和C4-C6-二羧酸, (c)0至20摩尔%的一种或多种羟烷基酯(其中羟基烷基为2至6个碳原子)为单烯属不饱和C 3 -C 6羧酸,(d)0至30摩尔%的其它水溶性 可与(a),(b)和(c)共聚的单烯属不饱和单体,(e)0.5〜15摩尔%的共聚单体,其具有两个或多个烯属不饱和的非共轭双键和一个或多个-CO-OH基团 和/或其与碱金属,铵或碱土金属碱的盐,如果需要,(f)至多10mol%的o 通过单体(a)至(f)的共聚制备不同于(e)并具有两个或更多个烯属不饱和非共轭双键的共聚单体,并用于涂覆种子。
    • 5. 发明授权
    • Water-soluble copolymers and their preparation
    • 水溶性共聚物及其制备方法
    • US4897458A
    • 1990-01-30
    • US179049
    • 1988-04-08
    • Hans-Peter Seelmann-EggebertDieter BoeckhHeinrich HartmannWolfgang Trieselt
    • Hans-Peter Seelmann-EggebertDieter BoeckhHeinrich HartmannWolfgang Trieselt
    • C07C69/533A01N25/26C08F2/10C08F220/04C08F290/00C08F299/00C08L101/16
    • C08F220/04A01N25/26
    • Water-soluble copolymers having a K value of from 15 to 120 (determined according to H. Fikentscher in an aqueous solution of their sodium salt at 25.degree. C., a pH of 7 and a polymer concentration of the Na salt of 1% by weight) contain, in polymerized form,(a) not less than 80 mol % of one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids,(b) from 0.5 to 20 mol % of a comonomer which possesses two or more ethylenically unsaturated, non-conjugated double bonds and one or more --CO--OX groups and/or their salt with an alkali metal, ammonium or alkaline earth metal base, and, if required,(c) not more than 10 mol % of one or more comonomers which differ from (b) and possess two or more ethylenically unsaturated, non-conjugated double bonds, and the said copolymers are prepared by copolymerization of the monomers (a), (b) and, if required (c) in aqueous solution and are used for coating seed.
    • K值为15〜120的水溶性共聚物(根据H.Fikentscher在25℃的钠盐水溶液中测定,pH为7,Na盐的聚合物浓度为1%的聚合物浓度由 重量)含有(a)不小于80摩尔%的一种或多种单烯属不饱和C3-C6-一元羧酸,(b)0.5-20摩尔%的具有两个或更多个烯属不饱和的共聚单体, 非共轭双键和一个或多个-CO-OX基团和/或其与碱金属,铵或碱土金属的碱的盐,如果需要,(c)不大于10摩尔%的一种或多种共聚单体 其不同于(b)并且具有两个或更多个烯键式不饱和的非共轭双键,并且所述共聚物通过单体(a),(b)和(如果需要(c))在水溶液中共聚而制备,并且 用于涂覆种子。
    • 6. 发明授权
    • Copolymers with monomers containing polyalkylene oxide blocks,
preparation thereof and use thereof
    • 与含有聚环氧烷嵌段的单体的共聚物,其制备及其用途
    • US5273676A
    • 1993-12-28
    • US768203
    • 1991-10-24
    • Dieter BoeckhHans-Peter Seelmann-EggebertHeinrich HartmannAlexander KudWolfgang Trieselt
    • Dieter BoeckhHans-Peter Seelmann-EggebertHeinrich HartmannAlexander KudWolfgang Trieselt
    • C08F216/12C08F2/06C08F2/38C08F16/14C08F16/32C08F20/10C08F216/14C08F218/02C08F218/04C08F220/10C08F220/18C08F220/28C08F290/00C08F290/06C08F299/02C11D3/37C11D1/83C08F218/08C08F220/14C11D1/835
    • C08F290/062C11D3/3757
    • Copolymers useful in amounts of from 0.1 to 15% by weight as grayness inhibiting and primary detergency boosting additives in pulverulent liquid detergents have K values of from 10 to 80 (determined by Fikentscher in dimethylformamide at 25.degree. C. with a polymer concentration of 2% by weight) and are obtainable by copolymerizing monomer mixtures of(a) from 10 to 60% by weight of water-soluble monomers obtainable from (A) water-soluble polyalkylene glycols or (B) water-soluble alkoxylated C.sub.1 -C.sub.25 -alcohols, for example by esterification with C.sub.3 -C.sub.6 -carboxylic acids, by vinylation with acetylene or by allylation with alkenyl ethers, or by reaction with ammonia to give the corresponding end group aminated compounds (A) or (B) and by reaction with monoethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids to form the amides, and(b) from 40 to 90% by weight of vinyl esters of saturated monocarboxylic acids and/or alkyl esters of monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acidsat up to 160.degree. C. in inert solvents in the presence of from 0.1 to 5% by weight, based on the monomers, of polymerization initiators, and, if the amount of initiator is less than 2% by weight, additionally in the presence of polymerization regulators.
    • PCT No.PCT / EP90 / 00720 Sec。 371日期1991年10月24日 102(e)日期1991年10月24日PCT提交1990年5月4日PCT公布。 第WO90 / 13581号公报 日期为1990年11月15日。在粉末状液体洗涤剂中,灰分抑制和初级去污增强添加剂的量为0.1至15重量%的聚合物的K值为10至80(由Fikentscher在25℃的二甲基甲酰胺中测定) 聚合物浓度为2重量%),并且可以通过(a)10至60重量%的可从(A)水溶性聚亚烷基二醇得到的水溶性单体或(B)水溶性的单体混合物 烷氧基化的C 1 -C 25醇,例如通过与C 3 -C 6 - 羧酸酯化,通过与乙炔反应或与烯基醚进行烯丙基化,或通过与氨反应得到相应的端基胺化化合物(A)或(B) 并通过与单烯键式不饱和C 3 -C 6羧酸反应形成酰胺,和(b)40-90%重量的饱和一元羧酸和/或单烯属不饱和C 3 -C 6 - 单羧酸烷基酯 在惰性溶剂中,在0.1至5重量%存在下,基于单体的聚合引发剂,并且如果引发剂的量小于2重量%,则另外在 存在聚合调节剂。