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    • 7. 发明授权
    • Synthesis of lower alkylene oxides and lower alkylene glycols from lower alkanes and/or lower alkenes
    • 从低级烷烃和/或低级烯烃合成低级烯化氧和低级亚烷基二醇
    • US06765101B1
    • 2004-07-20
    • US09846642
    • 2001-05-01
    • Madan Mohan BhasinStephen Wayne King
    • Madan Mohan BhasinStephen Wayne King
    • C07D30103
    • C07D301/14C07C29/50C07D301/04C07D301/22C07C31/202
    • A method and apparatus for synthesizing at least one of alkylene oxides and alkylene glycols from lower alkanes and/or lower alkenes. In the preferred embodiment, the apparatus includes a lower alkane/alkene supply; an oxygen supply for providing a source of oxygen; and a metal oxide catalytic reactor. The metal oxide catalytic reactor includes a reactor chamber; and a catalyst in the chamber for reacting the lower alkane/alkene supply with the source of oxygen to convert the lower alkane/alkene by selective partial oxidation to at least one of the alkylene oxides and alkylene glycols. Also, in the preferred embodiment, a separator, downstream from the reactor, separates the alkylene oxides and alkylene glycols from the total product stream and the unconverted reactants.
    • 用于从低级烷烃和/或低级烯烃合成环氧烷烃和亚烷基二醇中的至少一种的方法和装置。 在优选实施方案中,该装置包括低级烷烃/烯烃供应; 用于提供氧源的氧供应; 和金属氧化物催化反应器。 金属氧化物催化反应器包括反应室; 以及室中的催化剂,用于使低级烷烃/烯烃供应源与氧源反应,以通过选择性部分氧化将低级烷烃/烯烃转化成至少一种烯化氧和亚烷基二醇。 而且,在优选的实施方案中,在反应器下游的隔板从总产物流和未转化的反应物中分离出烯化氧和亚烷基二醇。