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    • 2. 发明授权
    • Process for preparing attrition resistant zeolitic layered catalyst composition
    • 制备耐磨沸石层状催化剂组合物的方法
    • US06710003B2
    • 2004-03-23
    • US10022024
    • 2001-12-13
    • Deng-Yang JanJames F. Mc GeheeGuy B. WoodleMasao TakayamaRaelynn M. Miller
    • Deng-Yang JanJames F. Mc GeheeGuy B. WoodleMasao TakayamaRaelynn M. Miller
    • B01J2904
    • B01J23/626B01J23/40B01J29/06B01J29/7007B01J37/0219B01J37/0242B01J37/0246Y10T428/2991Y10T428/2993
    • A layered catalyst composition is disclosed where the composition is prepared by bonding an outer layer comprising a bound zeolite (e.g. zeolite beta) to an inner core material (e.g. cordierite). The use of an organic bonding agent in the catalyst preparation procedure provides a composition that is sufficiently resistant to mechanical attrition to be used commercially in aromatic alkylation processes (e.g. benzene alkylation to ethylbenzene). Advantages associated with the use of layered compositions include a significant reduction in the amount of zeolite used for a given reactor loading and improved selectivity to desired alkylated aromatic products. Further benefits are realized when the layered composition is formed into shapes having a sufficiently high void volume to reduce pressure drop across the alkylation catalyst bed. This is especially relevant for operation involving high recycle rates and consequently low alkylating agent concentrations in the reaction zone. Such conditions are known to promote reduced byproduct formation.
    • 公开了一种分层催化剂组合物,其中通过将包含结合的沸石(例如β沸石)的外层粘合到内芯材料(例如堇青石)来制备组合物。 在催化剂制备方法中使用有机粘合剂提供了足够耐机械磨损的组合物,其可以在芳族烷基化方法(例如苯烷基化至乙苯)中商业使用。 与使用分层组合物相关的优点包括用于给定反应器负载的沸石的量的显着减少和对所需烷基化芳族产物的改进的选择性。 当层状组合物形成为具有足够高的空隙体积的形状以减少跨越烷基化催化剂床的压降时,可实现进一步的益处。 这对于涉及高回收率和因此反应区中低烷基化剂浓度的操作特别有用。 已知这种条件促进副产物形成。