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    • 1. 发明申请
    • HIGHLY BRANCHED PRIMARY ALCOHOL COMPOSITIONS, AND BIODEGRADABLE DETERGENTS MADE THEREFROM
    • 高分子量的主要酒精组合物和可生物降解的洗涤剂
    • US20070219112A1
    • 2007-09-20
    • US11748976
    • 2007-05-15
    • David SingletonLouis KravetzBrendan Murray
    • David SingletonLouis KravetzBrendan Murray
    • C11D3/20
    • C11D1/72C11D1/146
    • There is provided a new branched primary alcohol composition and the sulfates thereof exhibiting good cold water detergency and biodegradability. The branched primary alcohol composition has an average number of branches per chain of at least 0.7, having at least 8 carbon atoms and contianing both methyl and ethyl branches. The primary alcohol composition may also contain less than 0.5 atom % of quaternary carbon atoms, and a significant number ethyl branches, terminal isopropyl branches, and branching at the C3 position relative to the hydroxyl carbon. The process for its manufacture is by skeletally isomerizing an olefin feed having at least 7 carbon atoms followed by conversion to an alcohol, as by way of hydroformylation, and ultimately, sulfation to obtain a detergent surfactant. Useful catalysts include the zeolites having at least one channel with a crystallographic free diameter along the x and/or y planes of the [001] view ranging from greater than 4.2 Å and less than 7 Å but allows one to skeletally isomerize the olefin to produce a variety of branches, while retaining ready biodegradability and good cold water detergency.
    • 提供了一种新的支链伯醇组合物,其硫酸盐具有良好的冷水去污力和生物降解性。 支链伯醇组合物具有至少0.7个链的平均支链数,至少为0.7,具有至少8个碳原子并连接甲基和乙基支链。 伯醇组合物还可以含有小于0.5原子%的季碳原子,相对于羟基碳,在C 3位上有大量的乙基支链,末端异丙基支链和支链。 其制造方法是通过骨架异构化具有至少7个碳原子的烯烃原料,然后转化为醇,通过加氢甲酰化,最终硫酸化得到洗涤剂表面活性剂。 有用的催化剂包括沿[001]视图的x和/或y平面具有至少一个具有至少一个具有结晶自由直径的通道的沸石,范围从大于4.2和小于7,但允许一个骨架异构化烯烃以产生 各种分支,同时保持即时的生物降解性和良好的冷水去污力。
    • 2. 发明申请
    • Method, System, and Software Tool for Emulating a Portal Application
    • 用于模拟门户应用程序的方法,系统和软件工具
    • US20070016696A1
    • 2007-01-18
    • US11306424
    • 2005-12-28
    • Stanley Jerrard-DunneMark LevinsBrendan MurrayBrian O'Gorman
    • Stanley Jerrard-DunneMark LevinsBrendan MurrayBrian O'Gorman
    • G06F15/16
    • G06F17/3089
    • A method, system and software tool for emulating a portal application in a rich client application are provided. The rich client application is executable on a client platform capable of displaying views contributed by plug-in components registered with the client platform. The method comprises providing a user interface for eliciting user inputs for creating a new portal application on the client platform, detecting user selection of a portal page layout, and one or more views for each cell of the page layout, and generating a description of a client page representing the portal application. When the rich client application is run on the client platform it is directed to build a client page representing the portal application using the generated description.
    • 提供了一种用于在富客户端应用程序中模拟门户应用程序的方法,系统和软件工具。 富客户端应用程序可在能够显示由客户端平台注册的插件组件贡献的视图的客户端平台上执行。 该方法包括提供用于引导用户输入的用户界面,用于在客户端平台上创建新的门户应用,检测门户页面布局的用户选择以及页面布局的每个单元的一个或多个视图,以及生成 客户端页面代表门户应用程序。 当富客户端应用程序在客户端平台上运行时,它被引导使用生成的描述构建表示门户应用程序的客户端页面。
    • 3. 发明申请
    • Process for the isomerization of an olefin
    • 烯烃异构化的方法
    • US20060183954A1
    • 2006-08-17
    • US11398300
    • 2006-04-05
    • Michael DollBrendan Murray
    • Michael DollBrendan Murray
    • C07C5/25
    • C07C5/2518C07C2529/08
    • A process for the double bond isomerization of an olefin, which process comprises contacting a feed comprising the olefin with an isomerization catalyst, wherein prior to contacting the feed with the isomerization catalyst one or more components of the feed are pretreated by contacting with a pretreating material which comprises a zeolite which has a pore size of at least 0.35 nm; a plant which is suitable for carrying out the isomerization process; and a process for treating an olefin mixture which comprises a linear α-olefin and a vinylidene olefin which is isomeric to the linear α-olefin and which is of the general formula CH2═C(R1)R2, wherein R1 represents an ethyl group and R2 represents a linear 1-alkyl group, which process comprises isomerising the vinylidene olefin to form a double bond isomer of the vinylidene olefin by contacting a feed comprising the olefin mixture with an isomerization catalyst, and separating the linear α-olefin from the double bond isomer of the vinylidene olefin, wherein prior to contacting the feed with the isomerization catalyst one or more components of the feed are pretreated by contacting with a pretreating material which comprises a zeolite which has a pore size of at least 0.35 nm.
    • 一种烯烃双键异构化的方法,该方法包括将包含烯烃的进料与异构化催化剂接触,其中在将进料与异构化催化剂接触之前,将进料的一种或多种组分与预处理材料 其包含孔径至少为0.35nm的沸石; 适用于进行异构化处理的植物; 以及一种用于处理烯烃混合物的方法,所述烯烃混合物包含直链α-烯烃和与线性α-烯烃异构的亚乙烯基烯烃,其通式为CH 2 -C(R 0 其中R 1表示乙基,R 2表示直链的1-烷基,其中R 1表示直链的1-烷基,其中R 1表示乙基,R 2表示直链的1-烷基, 将亚乙烯基烯烃异构化以形成亚乙烯基烯烃的双键异构体,其通过使包含烯烃混合物的进料与异构化催化剂接触,并将线性α-烯烃与亚乙烯基烯烃的双键异构体分离,其中在接触之前 与异构化催化剂一起进料的进料通过与预处理材料接触来预处理,该预处理材料包含孔径至少为0.35nm的沸石。
    • 5. 发明申请
    • Process to convert linear alkanes into alpha olefins
    • 将线性烷烃转化为α-烯烃的方法
    • US20050245777A1
    • 2005-11-03
    • US11109551
    • 2005-04-19
    • Howard FongLizbeth TrevinoBrendan MurrayManuel Cano
    • Howard FongLizbeth TrevinoBrendan MurrayManuel Cano
    • C07C1/00C07C1/30C07C11/02C07C17/10C07C17/358C07C17/37C07C29/124
    • C07C29/124C07C1/30C07C11/02C07C17/10C07C17/358C07C17/37C07C2521/10C07C2521/14C07C2523/14C07C2523/44C07C2523/745C07C2523/78C07C19/075C07C19/01C07C31/125
    • This invention provides for a process to convert branched or linear alkanes to branched or linear alpha olefins (AO) of the same carbon number. The process comprises the steps of: a) halogenating linear alkanes, branched alkanes, or a mixture of linear and branched alkane to produce a mixture containing primary mono-haloalkanes and hydrogen halide; b) separating the hydrogen halide from the mixture and optionally neutralizing it with a metal oxide to produce a partially halogenated metal oxide and/or metal halide which may be regenerated; c) separating the primary mono-haloalkanes from the mixture; d) reacting the separated primary mono-haloalkanes with a metal oxide to produce a mixture of products that contains alpha olefins, unconverted primary mono-haloalkanes, possibly other reaction products, and a partially halogenated metal oxide and/or metal halide which may be regenerated; e) regenerating the partially halogenated metal oxide and/or metal halide to halogen and/or acid and a metal oxide (such as Cl2) for recycle by reaction with air or oxygen ; and f) removing the unreacted primary mono-haloalkane from the reaction mixture and then purifying the alpha olefin.
    • 本发明提供将支链或直链烷烃转化为相同碳数的支链或直链α-烯烃(AO)的方法。 该方法包括以下步骤:a)将直链烷烃,支链烷烃或直链和支链烷烃的混合物卤化以产生含有主要单卤代烷烃和卤化氢的混合物; b)从混合物中分离卤化氢并任选地用金属氧化物中和它以产生可再生的部分卤化的金属氧化物和/或金属卤化物; c)从混合物中分离初级单卤代烷烃; d)使分离的初级单卤代烷烃与金属氧化物反应以产生含有α-烯烃,未转化的初级单卤代烷烃,可能的其它反应产物和可再生的部分卤化的金属氧化物和/或金属卤化物的产物的混合物 ; e)将部分卤化的金属氧化物和/或金属卤化物再生成卤素和/或酸和金属氧化物(例如Cl 2 N 2),以通过与空气或氧气反应再循环; 和f)从反应混合物中除去未反应的主要单卤代烷烃,然后纯化α-烯烃。
    • 6. 发明授权
    • Dynamic interface component control support
    • 动态界面组件控件支持
    • US08943424B2
    • 2015-01-27
    • US13569577
    • 2012-08-08
    • Gili MendelBrendan MurrayJeffrey D. MyersJoseph R. Winchester
    • Gili MendelBrendan MurrayJeffrey D. MyersJoseph R. Winchester
    • G06F3/00G06F9/44
    • G06F8/38G06F8/31
    • A system, computer program and method for developing a graphical user interface (GUI) in a computer program. The invention allows developers to control the properties of interface components according to the state of a program during execution. According to the invention, a GUI development environment may be configured to provide a GUI builder for creating the GUI, display an interface component with at least one interface component property to be instantiated in the GUI, display a property interface to input at least one value for the interface component property in response to an event detectable by the computer program during GUI program execution, and automatically generate GUI program code effectuating the value for the interface component property in response to the event detectable by the computer program during GUI program execution.
    • 一种用于在计算机程序中开发图形用户界面(GUI)的系统,计算机程序和方法。 本发明允许开发人员在执行期间根据程序的状态来控制接口组件的属性。 根据本发明,GUI开发环境可以被配置为提供用于创建GUI的GUI构建器,在GUI中显示具有要被实例化的至少一个界面组件属性的接口组件,显示属性界面以输入至少一个值 响应于在GUI程序执行期间可由计算机程序检测到的事件的接口组件属性,并且响应于在GUI程序执行期间由计算机程序检测到的事件,自动生成GUI程序代码来实现界面组件属性的值。
    • 7. 发明申请
    • Derivatives of alcohols and olefins
    • US20050245772A1
    • 2005-11-03
    • US11116892
    • 2005-04-28
    • Howard FongLizbeth TrevinoBrendan MurrayManuel CanoTerry Thomason
    • Howard FongLizbeth TrevinoBrendan MurrayManuel CanoTerry Thomason
    • C07C1/30C07C17/10C07C27/00C07C29/124C07C41/01C07C43/11C07C45/27C07C305/06C11D1/04C11D3/37
    • C07C1/30C07C29/124C07C31/20C07C11/02
    • Derivatives of branched or linear olefins and alcohols made by halogenation of branched or n-alkanes of the same carbon number, preferably to make primary mono-haloalkanes, which may then be oxidized with metal oxides. The derivatives of primary alcohols of this invention include alcohol ethoxylates, alcohol sulfates, alcohol sulfated ethoxylates, surfactants, including those made with these ethoxylates and/or sulfated ethoxylates, detergents made with these surfactants, oxyalkylated alcohols, oxyalkylated alcohol sulfates, polymethacrylate esters, alkyl amines and their derivatives, linear phthalates, linear adipates, alcohol ether amines, alkyl glycerol ether sulfonates, thioproprionate esters, alkyl polyglucosides, alcohol phosphates, alcohol ether phosphates, esters of fatty acids, alcohol phosphites, and benzophenones. Secondary alcohol derivatives include secondary alcohol ethoxylates, secondary alcohol sulfates, secondary alcohol sulfated ethoxylates, surfactants, including those made with these ethoxylates and/or sulfated ethoxylates, and detergents made with these surfactants. Internal olefins derivatives included within the scope of this invention include alkylbenzene, alkylxylene, detergent alcohols, plasticizer alcohols, alkenyl succinates, ether secondary alcohols, and diols and polyols produced by catalytic dihydroxylation of internal olefins with the use of hydrogen peroxide. Alpha olefin derivatives included within the scope of this invention include internal olefins, alkylbenzene, alkylxylene, alkylphenol, alkylnaphthalene, detergent alcohols, plasticizer alcohols, alkylates of phenylbenzo compounds, alkyl ammonium salts of unsaturated fatty acids, alkyl amines and their derivatives, alpha olefin sulfonates, alkenyl succinates, polyalphaolefins, linear mercaptans, synthetic acids such as based on 1-butene, 1-hexene, or 1-octene, chlorinated alpha olefins, aluminum alkyls, alkyl diphenylether disulfonates, fatty acids, lubricant additives, and ether primary alcohols.
    • 8. 发明申请
    • Process for producing alkylbenzene
    • 生产烷基苯的方法
    • US20060189836A9
    • 2006-08-24
    • US10880072
    • 2004-06-29
    • Brendan MurrayGaro Vaporciyan
    • Brendan MurrayGaro Vaporciyan
    • C07C1/20C07C2/68
    • C07C15/085C07C1/22C07C2523/40C07C2523/44C07C2523/72C07C2523/74C07C2529/22Y02P20/127Y10S203/06
    • A process for producing an alkylbenzene from an alkylphenyl alcohol involving the steps of: (a) feeding a feed stream containing alkylphenyl a reactor having a catalytic distillation zone; and, (b) concurrently in the reactor (i) contacting the feed stream containing alkylphenyl alcohol with hydrogen in the catalytic distillation zone to convert alkylphenyl alcohol to alkylbenzene over a catalyst containing Group VIII or a Group IB metal; and, (ii) separating alkylbenzene from the reaction mixture by fractional distillation to produce an overhead stream containing alkylbenzene having a reduced concentration of alkylphenyl alcohol than the feed stream from the distillation column reactor. Examples of the alkylphenyl alcohol include cumyl alcohol, phenyl ethyl alcohol, or di(2-hydroxyl 2-propyl)benzene, and that for the alkylbenzene include cumene and di-ethyl benzene, or di(2-hydroxyl-2-propyl)benzene.
    • 包括以下步骤生产烷基苯的方法:(a)将含有烷基苯基的进料流输送到具有催化蒸馏区的反应器; 和(b)在反应器中同时(i)在催化蒸馏区中使含有烷基苯基醇的进料流与氢气接触,以使烷基苯醇在含有VIII族或IB族金属的催化剂上转化为烷基苯; 和(ii)通过分馏从反应混合物中分离出烷基苯,以产生含有烷基苯醇浓度低于来自蒸馏塔反应器的进料流的烷基苯的塔顶液流。 烷基苯醇的实例包括枯基醇,苯基乙醇或二(2-羟基-2-丙基)苯,对于烷基苯包括枯烯和二乙基苯,或二(2-羟基-2-丙基)苯 。
    • 9. 发明申请
    • Methods of preparing branched aliphatic alcohols
    • 制备支链脂肪醇的方法
    • US20050101808A1
    • 2005-05-12
    • US10965256
    • 2004-10-14
    • Paul AyoubHendrik DirkzwagerBrendan MurraySteve Sumrow
    • Paul AyoubHendrik DirkzwagerBrendan MurraySteve Sumrow
    • C07C29/16C07C27/22
    • C07C29/16C07C31/125
    • Systems and methods to produced branched aliphatic alcohols are described. Systems may include a dehydrogenation-isomerization unit, an olefin dimerization unit, an olefin isomerization unit, a hydroformylation unit, a dehydrogenation unit, a hydrogenation unit and/or combinations thereof. Methods for producing branched aliphatic alcohols may include isomerization of olefins in a process stream. The isomerized olefins may be hydroformylated to produce aliphatic alcohols. After hydroformylation of the aliphatic alcohols, unreacted components from the hydroformylation process may be separated from the aliphatic alcohols products. The unreacted components from the hydroformylation process may be recycled back into the main process stream or sent to other processing units. Addition of multiple streams to the units may be performed to control reaction conditions in the units.
    • 描述了制备支链脂族醇的体系和方法。 系统可以包括脱氢异构化单元,烯烃二聚单元,烯烃异构化单元,加氢甲酰化单元,脱氢单元,氢化单元和/或其组合。 制备支链脂族醇的方法可以包括在工艺流中烯烃的异构化。 异构化的烯烃可以加氢甲酰化以产生脂族醇。 在脂肪醇的加氢甲酰化之后,来自加氢甲酰化过程的未反应组分可以与脂族醇产物分离。 来自加氢甲酰化方法的未反应组分可以循环回到主工艺流中或送到其它处理单元。 可以向单元添加多个流以控制单元中的反应条件。
    • 10. 发明申请
    • Process for producing alkylene oxide
    • 环氧烷生产方法
    • US20050020840A1
    • 2005-01-27
    • US10872849
    • 2004-06-21
    • Brendan MurrayGaro Vaporciyan
    • Brendan MurrayGaro Vaporciyan
    • C07C409/00C07D301/19
    • C07D301/19Y02P20/127
    • A process for preparing an alkylene oxide, which process comprises: (i) oxidizing an alkylbenzene to obtain a stream comprising alkylbenzene hydroperoxide, (ii) contacting at least part of the alkylbenzene hydroperoxide obtained in step (i) with an olefin to obtain a product stream comprising an alkylene oxide (iii) separating alkylene oxide compound from the product stream of step (ii) to obtain (a) a residual product stream comprising alkylphenyl alcohol, and (b) alkylene oxide, (iv) feeding at least a part of the residual product stream comprising alkylphenyl alcohol to a reactor having a catalytic distillation zone, and concurrently in the reactor, (a) contacting the residual product stream comprising alkylphenyl alcohol with hydrogen in the catalytic distillation zone to convert the alkylphenyl alcohol in the residual product stream to alkylbenzene and form a reaction mixture, and (b) separating alkylbenzene from the reaction mixture by fractional distillation, (v) withdrawing a stream comprising alkylbenzene and having a reduced concentration of alkylphenyl alcohol than the feed stream from the reactor at a position upper from the catalytic reaction zone; (vi) withdrawing from the reactor at a position lower than the catalytic distillation zone a bottom stream comprising dimer(s) of alkylbenzene; (vii) converting the dimer(s) of alkylbenzene in the bottom stream from (vi) to alkylbenzene; and (viii) recycle at least a part of the alkylbenzene produced from (iv)(b) and/or (vi) to step (i).
    • 一种制备环氧烷的方法,该方法包括:(ⅰ)氧化烷基苯以获得包含烷基苯氢过氧化物的物流,(ⅱ)将步骤(ⅰ)中获得的烷基苯氢过氧化物的至少一部分与烯烃接触,得到产物 包含环氧烷的物流(iii)将烯化氧化合物与步骤(ii)的产物流分离,得到(a)包含烷基苯基醇的残余产物流,和(b)烯化氧,(iv)将至少一部分 残余产物流包含烷基苯醇至具有催化蒸馏区的反应器,并且同时在反应器中,(a)在催化蒸馏区中使包含烷基苯基醇的残余产物流与氢接触以将残余产物流中的烷基苯醇 形成反应混合物,和(b)通过分馏从反应混合物中分离出烷基苯,(v)作为 包含烷基苯并且具有降低的烷基苯醇浓度比来自反应器的进料流在催化反应区上方的位置; (vi)在低于催化蒸馏区的位置从反应器中排出包含烷基苯二聚体的底部流; (vii)将底部物流中烷基苯的二聚体从(vi)转化为烷基苯; 和(viii)将从(iv)(b)和/或(vi)至(ⅰ)产生的至少一部分烷基苯再循环。