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    • 3. 发明授权
    • Process scheme for SO.sub.x  removal from flue gases
    • 从烟道气中去除SOx的工艺方案
    • US5741469A
    • 1998-04-21
    • US727843
    • 1996-10-04
    • Nazeer A. BhoreDavid L. JohnsonKhushrav E. NarimanDavid L. Stern
    • Nazeer A. BhoreDavid L. JohnsonKhushrav E. NarimanDavid L. Stern
    • B01D53/50B01D53/73C01B17/04B01J8/00C01B7/00
    • C01B17/0473B01D53/508B01D53/73C01B17/04
    • A dry, regenerable solid oxide process directed to convert SO.sub.x from the flue gas stream from a power plant, a coal or oil-fired plant or process heat furnace, or an FCC regenerator to elemental sulfur without using a Claus unit, a hydrogen plant, a regeneration gas separation system, or a hydrogenation section. This dry, regenerable solid oxide process is also effective on Claus plant tail-gas. This process uses solid oxides, such as, for example, magnesium aluminates or spinels to remove sulfur oxides from flue gas streams. The solid oxide is then regenerated by a reducing gas to release the sulfur compounds contained on the solid oxide to produce a gas stream comprising hydrogen sulfide, sulfur oxides and elemental sulfur. The elemental sulfur is then condensed and recovered as a product and the resulting gas stream may be recycled to be reprocessed over the solid oxide.
    • 一种干式可再生固体氧化物工艺,其特征是将SO x从来自发电厂,煤或燃油电厂或工艺加热炉或FCC再生器的烟道气转化为元素硫,而不使用克劳斯单元,氢厂, 再生气体分离系统或氢化部。 这种干式可再生固体氧化物工艺对克劳斯植物尾气也是有效的。 该方法使用固体氧化物,例如铝酸镁或尖晶石从烟道气流中除去硫氧化物。 然后通过还原气体再生固体氧化物以释放固体氧化物上所含的硫化合物,以产生包含硫化氢,硫氧化物和元素硫的气流。 然后将元素硫冷凝并回收,作为产物,所得气流可以再循环以在固体氧化物上再处理。