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1. 发明授权

US4229554A Flame retardant antistatic additives and antistatic fibers 失效
标题翻译：阻燃抗静电添加剂和抗静电纤维
公开(公告)号：US4229554A
公开(公告)日：1980-10-21
申请号：US746723
申请日：1976-12-02
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： C08G63/682 , D06M11/47 , D06M11/70 , D06M15/507 , D06M15/53 , C08F283/02 , C08G63/76 , C08G69/44
CPC分类号： C08G63/6824 , D06M11/47 , D06M11/70 , D06M15/507 , D06M15/53
摘要： Flame-retardant antistatic polymer additives are provided which inhibit the buildup of electrostatic charges upon the addition of such compositions to synthetic polymeric fibers, i.e., polyamide fibers, and at the same time do not contribute to the flammability characteristics of such polymeric fibers. The flame-retardant antistatic polymer compositions are useful in combinations with fibers such as polyamide, polyester, polyurea, polyurethane, polysulfonamide, polyolefin and polyacrylic fibers. The antistatic effect is obtained by the process of coating the fibers or dispersing in or on the fibers up to about 12 percent by weight of a polymer composition which is the reaction product of:(a) a polyoxyalkylene compound or polyester thereof and(b) at least one reactant selected from the group consisting of (1) a diol, (2) a polyester and (3) an aliphatic or aromatic diacid or derivative of (3), wherein at least one said reactant is halogenated.Improved flame-retardant properties can be obtained by including with the flame-retardant, antistatic polymer composition an effective flame retardant proportion of a compound containing a metal from group Vb of the periodic table. Generally about 1:4 to about 4:1 parts halogen to antimony compound is used. Such compounds are oxides of metals such as phosphorus, arsenic, antimony, or bismuth with the preferred compound being antimony trioxide.
摘要翻译：提供了阻燃抗静电聚合物添加剂，其在将合成聚合物纤维即聚酰胺纤维加入这些组合物时抑制静电荷的累积，并且同时对这种聚合物纤维的可燃性没有贡献。阻燃抗静电聚合物组合物可与纤维如聚酰胺，聚酯，聚脲，聚氨酯，聚磺酰胺，聚烯烃和聚丙烯酸纤维组合使用。抗静电效果是通过将纤维涂布或分散在纤维中或在纤维上分散至约12重量％的聚合物组合物获得的，所述聚合物组合物是以下物质的反应产物：（a）聚氧化烯化合物或其聚酯和（b）至少一种选自（1）二醇，（2）聚酯和（3）脂族或芳族二酸或（3）的衍生物的反应物，其中至少一种所述反应物被卤化。通过使阻燃抗静电聚合物组合物包含含有周期表第Vb族中的金属的化合物的有效阻燃剂比例，可以获得改进的阻燃性能。通常使用约1:4至约4:1的卤素至锑化合物。这些化合物是金属的氧化物，例如磷，砷，锑或铋，优选的化合物是三氧化锑。

2. 发明授权

US4217394A Metal molds coated with oxidative stable polyoxyalkylene release agents 失效
标题翻译：金属模具涂有氧化稳定的聚氧化烯脱模剂
公开(公告)号：US4217394A
公开(公告)日：1980-08-12
申请号：US973100
申请日：1978-12-26
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： B29C33/62 , C10M107/34 , B32B15/04
CPC分类号： C10M107/34 , B29C33/62 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/106 , C10M2209/107 , C10M2209/109 , C10N2220/02 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , Y10T428/31678
摘要： There are disclosed mold-release compositions suitable for lubricating metal molds which are used in molding natural and synthetic rubber and other polymers. The mold release agents of the invention are oxidation-stable homopolymer and copolymer, i.e., block or heteric polyoxyalkylene lubricant compounds. The lubricants of the invention can be used alone or in mixtures with prior art polyoxyalkylene lubricant compounds. The polyoxyalkylene mold release lubricants of the invention have the formula: ##STR1## R is individually selected from alkyl groups of 1 to about 21 carbon atoms, preferably about 7 to about 21 carbon atoms, and most preferably about 12 to about 18 carbon atoms. In lubricants I and III, R.sub.1 and R.sub.2 are the residue of the same or different and in lubricant II different alkylene units, all individually selected from the group consisting of the residue of ethylene oxide, propylene oxide, butylene oxide and an aromatic glycidyl ether, R.sub.3 is the residue of a difunctional phenol, R.sub.4 is hydrogen, an acyl or alkyl group and where alkyl, derived from an aliphatic monofunctional alcohol having 1 to about 21 carbon atoms, preferably about 4 to about 18 carbon atoms and most preferably about 4 to about 12 carbon atoms or where acyl derived from an aliphatic monocarboxylic acid of 2 to about 21 carbon atoms, preferably about 4 to about 18 carbon atoms and most preferably about 6 to about 12 carbon atoms, R.sub.5 is the residue of an aromatic glycidyl ether, preferably a phenyl glycidyl ether and n or m+n have a value to produce a molecular weight of about 300 to about 6000, preferably about 600 to about 5000 and most preferably about 1000 to about 4000.
摘要翻译：公开了适用于润滑金属模具的脱模组合物，其用于模制天然和合成橡胶和其它聚合物。本发明的脱模剂是氧化稳定的均聚物和共聚物，即嵌段或杂多聚氧化烯润滑剂化合物。本发明的润滑剂可以单独使用或与现有技术的聚氧化烯润滑剂化合物混合使用。本发明的聚氧化烯脱模润滑剂具有下式： I. II。和 III。 R独立地选自1至约21个碳原子，优选约7至约21个碳原子的烷基，最优选约12至约18个碳原子。在润滑剂I和III中，R1和R2是相同或不同的残基，润滑剂II不同的亚烷基单元，全部分别选自环氧乙烷，环氧丙烷，环氧丁烷和芳族缩水甘油醚的残基， R3是二官能苯酚的残基，R4是氢，酰基或烷基，其中烷基衍生自具有1至约21个碳原子，优选约4至约18个碳原子，最优选约4至约18个碳原子的脂肪族单官能醇约12个碳原子，或其中衍生自2至约21个碳原子，优选约4至约18个碳原子，最优选约6至约12个碳原子的脂肪族单羧酸的酰基，R 5为芳族缩水甘油醚的残基，优选苯基缩水甘油醚，n或m + n具有产生约300至约6000，优选约600至约5000，最优选约1000至约4000的分子量的值。

3. 发明授权

US4371476A Mold release agents containing oxidation stable polyoxyalkylenes 失效
标题翻译：含有氧化稳定的聚氧化烯的脱模剂
公开(公告)号：US4371476A
公开(公告)日：1983-02-01
申请号：US211952
申请日：1980-12-01
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： B29C33/62 , C08L21/00
CPC分类号： B29C33/62 , C10M3/00 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/106 , C10M2209/107 , C10M2209/109 , C10N2220/02 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： Compositions having internal mold-release properties comprise a molding polymer and an oxidation stable polyoxyalkylene lubricant compound used alone or in combination with other polyoxyalkylene compounds.
摘要翻译：具有内部脱模性的组合物包括单独使用或与其它聚氧化烯化合物组合使用的模塑聚合物和氧化稳定的聚氧化烯润滑剂。

4. 发明授权

US4127490A Fiber finish compositions 失效
标题翻译：纤维成品组合物
公开(公告)号：US4127490A
公开(公告)日：1978-11-28
申请号：US857425
申请日：1977-12-05
申请人： David D. Newkirk , Basil Thir , Robert B. Login
发明人： David D. Newkirk , Basil Thir , Robert B. Login
IPC分类号： D06M13/18
CPC分类号： D06M7/00 , D06M2200/40 , Y10T428/2969
摘要： A textile treating composition, consisting of a mixture of a major amount of lubricant and a minor amount of a stabilizer of said lubricant and a process for employment thereof.
摘要翻译：一种纺织品处理组合物，其由主要量的润滑剂和少量的所述润滑剂的稳定剂的混合物组成，以及其使用方法。

5. 发明授权

US4303767A Flame retardant antistatic additives and antistatic fibers 失效
标题翻译：阻燃抗静电添加剂和抗静电纤维
公开(公告)号：US4303767A
公开(公告)日：1981-12-01
申请号：US094033
申请日：1979-11-13
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： C08G63/682 , D06M11/47 , D06M11/68 , D06M15/507 , D06M15/53 , C08L67/00
CPC分类号： D06M11/47 , C08G63/6824 , D06M11/68 , D06M15/507 , D06M15/53
摘要： Flame-retardant antistatic polymer additives are provided which inhibit the buildup of electrostatic charges upon the addition of such compositions to synthetic polymeric fibers, i.e., polyamide fibers, and at the same time do not contribute to the flammability characteristics of such polymeric fibers. The flame-retardant antistatic polymer compositions are useful in combinations with fibers such as polyamide, polyester, polyurea, polyurethane, polysulfonamide, polyolefin and polyacrylic fibers. The antistatic effect is obtained by the process of coating the fibers or dispersing in or on the fibers up to about 12 percent by weight of a polymer composition which is the reaction product of:(a) a polyoxyalkylene compound or polyester thereof and(b) at least one reactant selected from the group consisting of (1) a diol, (2) a polyester and (3) an aliphatic or aromatic diacid or derivative of (3), wherein at least one said reactant is halogenated.Improved flame-retardant properties can be obtained by including with the flame-retardant, antistatic polymer composition an effective flame retardant proportion of a compound from group Vb of the periodic table. Generally about 1:4 to about 4:2 parts halogen to antimony compound is used. Such compounds are oxides of metals such as phosphorus, arsenic, antimony, or bismuth with the preferred compound being antimony trioxide.
摘要翻译：提供了阻燃抗静电聚合物添加剂，其在将合成聚合物纤维即聚酰胺纤维加入这些组合物时抑制静电荷的累积，并且同时不影响这种聚合物纤维的可燃性。阻燃抗静电聚合物组合物可与纤维如聚酰胺，聚酯，聚脲，聚氨酯，聚磺酰胺，聚烯烃和聚丙烯酸纤维组合使用。抗静电效果是通过将纤维涂布或分散在纤维中或在纤维上分散至约12重量％的聚合物组合物获得的，聚合物组合物是以下物质的反应产物：（a）聚氧化烯化合物或其聚酯和（b）至少一种选自（1）二醇，（2）聚酯和（3）脂族或芳族二酸或（3）的衍生物的反应物，其中至少一种所述反应物被卤化。通过使阻燃抗静电聚合物组合物包含有效的阻燃比例的元素周期表中的Vb族化合物，可以获得改进的阻燃性能。通常使用约1：4至约4：2份卤素至锑化合物。这些化合物是金属的氧化物，例如磷，砷，锑或铋，优选的化合物是三氧化锑。

6. 发明授权

US4179544A Fiber finish compositions 失效
标题翻译：纤维成品组合物
公开(公告)号：US4179544A
公开(公告)日：1979-12-18
申请号：US857382
申请日：1977-12-05
申请人： David D. Newkirk , Basil Thir , Robert B. Login
发明人： David D. Newkirk , Basil Thir , Robert B. Login
IPC分类号： C10M169/04 , D06M15/693 , D02G3/00
CPC分类号： D06M15/693 , C10M169/04 , C10M2207/023 , C10M2207/024 , C10M2209/101 , C10M2209/1033 , C10M2209/1045 , C10M2209/1055 , C10M2209/1065 , C10M2209/107 , C10M2209/1075 , C10M2209/1085 , C10M2209/1095 , C10M2221/043 , C10M2227/00 , C10N2220/02 , C10N2240/62 , Y10T428/2933 , Y10T428/2964 , Y10T428/2969
摘要： A fiber finish composition, consisting of a mixture of a major amount of lubricant and a minor amount of a stabilizer of said fiber finish and a process for employment thereof.
摘要翻译：一种纤维整理剂组合物，其由主要量的润滑剂和少量的所述纤维整理剂的稳定剂的混合物组成，以及其使用方法。

7. 发明授权

US4304801A Process for producing flame retardant antistatic fibers 失效
标题翻译：制造阻燃抗静电纤维的方法
公开(公告)号：US4304801A
公开(公告)日：1981-12-08
申请号：US93242
申请日：1979-11-13
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： C08G63/682 , D01F1/09 , D06M11/47 , D06M11/70 , D06M15/507 , D06M15/53 , B05D3/02 , C08G63/76 , C08G69/44
CPC分类号： D01F1/09 , C08G63/6824 , D06M11/47 , D06M11/70 , D06M15/507 , D06M15/53
摘要： A process for preparing a flame-retardant antistatic polymer additive useful for incorporation into the melt prior to extruding fibers or other polymers or for dispersing on fibers. Improved flame-retardant properties are obtained by including with said flame-retardant additive an effective flame-retardant proportion of a compound from group Vb of the periodic table.
摘要翻译：制备阻燃抗静电聚合物添加剂的方法，其用于在挤出纤维或其它聚合物之前掺入到熔体中或用于分散在纤维上。通过将所述阻燃添加剂与周期表第Vb族化合物的阻燃比例相比较，可以获得改进的阻燃性能。

8. 发明授权

US4294944A Flame retardant antistatic additives and antistatic fibers 失效
标题翻译：阻燃抗静电添加剂和抗静电纤维
公开(公告)号：US4294944A
公开(公告)日：1981-10-13
申请号：US94032
申请日：1979-11-13
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： C08G63/682 , D06M11/47 , D06M11/68 , D06M15/507 , D06M15/53 , C08L63/00
CPC分类号： C08G63/6824 , D06M11/47 , D06M11/68 , D06M15/507 , D06M15/53 , Y10S524/911 , Y10S525/927 , Y10T428/2969
摘要： Flame-retardant antistatic polymer additives are provided which inhibit the buildup of electrostatic charges upon the addition of such compositions to synthetic polymeric fibers, i.e., polyamide fibers, and at the same time do not contribute to the flammability characteristics of such polymeric fibers. The flame-retardant antistatic polymer compositions are useful in combinations with fibers such as polyamide, polyester, polyurea, polyurethane, polysulfonamide, polyolefin and polyacrylic fibers. The antistatic effect is obtained by the process of coating the fibers or dispersing in or on the fibers up to about 12 percent by weight of a polymer composition which is the reaction product of:(a) a polyoxyalkylene compound or polyester thereof and(b) at least one reactant selected from the group consisting of (1) a diol, (2) a polyester and (3) an aliphatic or aromatic diacid or derivative of (3), wherein at least one said reactant is halogenated.Improved flame-retardant properties can be obtained by including with the flame-retardant, antistatic polymer composition an effective flame retardant proportion of a compound from group Vb of the periodic table. Generally about 1:4 to about 4:1 parts halogen to antimony compound is used. Such compounds are oxides of metals such as phosphorus, arsenic, antimony, or bismuth with the preferred compound being antimony trioxide.
摘要翻译：提供了阻燃抗静电聚合物添加剂，其在将合成聚合物纤维即聚酰胺纤维加入这些组合物时抑制静电荷的累积，并且同时对这种聚合物纤维的可燃性没有贡献。阻燃抗静电聚合物组合物可与纤维如聚酰胺，聚酯，聚脲，聚氨酯，聚磺酰胺，聚烯烃和聚丙烯酸纤维组合使用。抗静电效果是通过将纤维涂布或分散在纤维中或在纤维上分散至约12重量％的聚合物组合物获得的，所述聚合物组合物是以下物质的反应产物：（a）聚氧化烯化合物或其聚酯和（b）至少一种选自（1）二醇，（2）聚酯和（3）脂族或芳族二酸或（3）的衍生物的反应物，其中至少一种所述反应物被卤化。通过使阻燃抗静电聚合物组合物包含有效的阻燃比例的元素周期表中的Vb族化合物，可以获得改进的阻燃性能。通常使用约1:4至约4:1的卤素至锑化合物。这些化合物是金属的氧化物，例如磷，砷，锑或铋，优选的化合物是三氧化锑。

9. 发明授权

US4361623A Flame retardant antistatic additives and antistatic fibers 失效
标题翻译：阻燃抗静电添加剂和抗静电纤维
公开(公告)号：US4361623A
公开(公告)日：1982-11-30
申请号：US161730
申请日：1980-06-20
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： C08G63/682 , D06M11/47 , D06M11/70 , D06M15/507 , D06M15/53 , B32B27/00 , D02G3/00
CPC分类号： D06M15/53 , C08G63/6824 , D06M11/47 , D06M11/70 , D06M15/507 , Y10S428/922 , Y10T428/2931 , Y10T428/2967 , Y10T428/2969
摘要： A flame-retardant, antistatic synthetic polymeric fiber which is the product of the process of coating on said fiber about 1 percent to about 12 percent by weight of a polymer composition which is the reaction product of a cross-linking agent and a polyoxyalkylene compound having as a nucleus a nitrogen containing reactive hydrogen containing compound with a diol which is halogenated.
摘要翻译：阻燃抗静电合成聚合物纤维，其是在所述纤维上涂覆约1％至约12％重量的聚合物组合物的产物的产物，所述聚合物组合物是交联剂和聚氧化烯化合物的反应产物，其具有作为核，含有含有反应性氢的化合物与被卤化的二醇形成。

10. 发明授权

US4312966A Flame retardant antistatic additives and antistatic fibers 失效
标题翻译：阻燃抗静电添加剂和抗静电纤维
公开(公告)号：US4312966A
公开(公告)日：1982-01-26
申请号：US161729
申请日：1980-06-20
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： C08G63/682 , D06M11/47 , D06M11/68 , D06M15/507 , D06M15/53 , C08L67/00 , C08L77/00
CPC分类号： C08G63/6824 , D06M11/47 , D06M11/68 , D06M15/507 , D06M15/53 , Y10S260/17 , Y10S260/19
摘要： A flame-retardant, antistatic synthetic polymeric fiber which is the product of the process of dispersing in said fiber about 1 percent to about 12 percent by weight of a polymer composition which is the reaction product of a polyester of a polyoxyalkylene compound having as a nucleus a nitrogen-containing reactive hydrogen containing compound with a reactant selected from the group consisting of at least one of an aliphatic or aromatic diacid, anhydride or acid halide thereof and a diol wherein at least one of said reactant is halogenated.
摘要翻译：一种阻燃的抗静电合成聚合物纤维，其是在所述纤维中分散约1％至约12％重量的聚合物组合物的产物的产物，聚合物组合物是具有作为核的聚氧化烯化合物的聚酯的反应产物含氮反应性氢化合物与选自脂族或芳族二酸，酸酐或其酰基卤和至少一种所述反应物卤化的二醇中的至少一种的反应物。

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