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1. 发明授权

US5425872A Electrochemical preparation of addition polymerization catalysts 失效
标题翻译：加成聚合催化剂的电化学制备
公开(公告)号：US5425872A
公开(公告)日：1995-06-20
申请号：US275579
申请日：1994-07-15
申请人： David D. Devore , Robert D. Mussell , James C. Stevens , Francis J. Timmers
发明人： David D. Devore , Robert D. Mussell , James C. Stevens , Francis J. Timmers
IPC分类号： C08F4/642 , B01J37/34 , C07F17/00 , C08F4/659 , C08F4/6592 , C08F10/00 , C25B3/12
CPC分类号： C07F17/00 , B01J37/348 , C08F10/00 , C08F2420/02 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y10S526/943
摘要： Group 4 metal complexes useful as addition polymerization catalysts are prepared by electrolysis of cyclopentadienyl metal complexes under inert electrolysis conditions.
摘要翻译：可用作加成聚合催化剂的第4族金属络合物通过在惰性电解条件下电解环戊二烯基金属络合物来制备。

2. 发明授权

US5624878A Titanium (II) or zirconium (II) complexes and addition polymerization catalysts therefrom 失效
标题翻译：钛（II）或锆（II）络合物及其加成聚合催化剂
公开(公告)号：US5624878A
公开(公告)日：1997-04-29
申请号：US469186
申请日：1995-06-06
申请人： David D. Devore , Francis J. Timmers , James C. Stevens , Robert D. Mussell , Lenore H. Crawford
发明人： David D. Devore , Francis J. Timmers , James C. Stevens , Robert D. Mussell , Lenore H. Crawford
IPC分类号： C07F20060101 , C07F17/00 , C08F20060101 , C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F36/00 , C08F36/04 , C08F210/02 , C08F210/16 , C08F210/18 , B01J31/00 , C07F7/28
CPC分类号： C07F17/00 , C08F10/00 , C08F210/02 , C08F210/16 , C08F210/18 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/901 , Y10S526/905 , Y10S526/943
摘要： Novel catalytic derivatives of titanium or zirconium complexes containing one and only one cyclic delocalized, anionic, .PI.-bonded group wherein the metal is in the +2 formal oxidation state and having a bridged ligand structure and an activating cocatalyst are useful as catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.
摘要翻译：含有一个且仅一个环状离域阴离子，+529键合基团的钛或锆络合物的新型催化衍生物，其中金属处于+2形式氧化态并具有桥连配体结构和活化助催化剂可用作聚合催化剂烯烃，二烯烃和/或炔属不饱和单体。

3. 发明授权

US5556928A Titanium (II) or Zirconium (II) complexes and addition polymerization catalysts therefrom 失效
标题翻译：钛（II）或锆（II）络合物及其加成聚合催化剂
公开(公告)号：US5556928A
公开(公告)日：1996-09-17
申请号：US470858
申请日：1995-08-15
申请人： David D. Devore , Francis J. Timmers , James C. Stevens , Robert D. Mussell , Lenore H. Crawford , David R. Wilson
发明人： David D. Devore , Francis J. Timmers , James C. Stevens , Robert D. Mussell , Lenore H. Crawford , David R. Wilson
IPC分类号： C07F20060101 , C07F17/00 , C08F20060101 , C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F36/00 , C08F36/04 , C08F210/02 , C08F210/16 , C08F210/18 , C08F4/643
CPC分类号： C07F17/00 , C08F10/00 , C08F210/02 , C08F210/16 , C08F210/18 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/901 , Y10S526/905 , Y10S526/943
摘要： A process for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers using novel catalyst compositions comprising titanium or zirconium complexes containing one and only one cyclic delocalized, anionic, .pi.-bonded group wherein the metal is in the +2 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes, and an activating cocatalyst.
摘要翻译：使用新型催化剂组合物聚合烯烃，二烯烃和/或炔属不饱和单体的方法，该催化剂组合物包含含有一个且仅一个环状离域阴离子的π键合基团的钛或锆络合物，其中金属处于+2形式氧化态并具有桥连配体结构，也称为约束几何复合物，和活化助催化剂。

4. 发明授权

US5372682A Electrochemical preparation of addition polymerization catalysts 失效
标题翻译：加成聚合催化剂的电化学制备
公开(公告)号：US5372682A
公开(公告)日：1994-12-13
申请号：US82201
申请日：1993-06-24
申请人： David D. Devore , Robert D. Mussell , James C. Stevens , Francis J. Timmers
发明人： David D. Devore , Robert D. Mussell , James C. Stevens , Francis J. Timmers
IPC分类号： C08F4/642 , B01J37/34 , C07F17/00 , C08F4/659 , C08F4/6592 , C08F10/00 , C25B3/12
CPC分类号： C07F17/00 , B01J37/348 , C08F10/00 , C08F2420/02 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y10S526/943
摘要： Group 4 metal complexes useful as addition polymerization catalysts are prepared by electrolysis of cyclopentadienyl metal complexes under inert electrolysis conditions.
摘要翻译：可用作加成聚合催化剂的第4族金属络合物通过在惰性电解条件下电解环戊二烯基金属络合物来制备。

5. 发明授权

US5347024A Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation 失效
标题翻译：通过路易斯酸制备加成聚合催化剂减轻金属中心氧化
公开(公告)号：US5347024A
公开(公告)日：1994-09-13
申请号：US34434
申请日：1993-03-19
申请人： Peter N. Nickias , David D. Devore , Francis J. Timmers , Robert K. Rosen , Robert D. Mussell
发明人： Peter N. Nickias , David D. Devore , Francis J. Timmers , Robert K. Rosen , Robert D. Mussell
IPC分类号： C08F4/64 , C07F5/02 , C07F7/10 , C07F9/50 , C07F17/00 , C08F4/60 , C08F4/659 , C08F4/6592 , C08F4/74 , C08F10/00 , C07C7/00
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/6592
摘要： Addition polymerization catalysts comprising a derivative of a titanium or zirconium in the +4 oxidation state prepared by metal center oxidation and cation complex formation of a reduced metal precursor complex via electron transfer in a single step by use of a neutral organic oxidant, optionally in the presence of a Lewis acid mitigator.
摘要翻译：包含通过金属中心氧化制备的+4氧化态的钛或锆的衍生物的加成聚合催化剂，并且通过使用中性有机氧化剂在一个步骤中通过电子转移阳离子络合物形成还原金属前体复合物，任选地在存在路易斯酸缓释剂。

6. 发明授权

US5625087A Silylium cationic polymerization activators for metallocene complexes 失效
标题翻译：茂金属络合物的硅烷阳离子聚合活化剂
公开(公告)号：US5625087A
公开(公告)日：1997-04-29
申请号：US304314
申请日：1994-09-12
申请人： David D. Devore , David R. Neithamer , Robert E. LaPointe , Robert D. Mussell
发明人： David D. Devore , David R. Neithamer , Robert E. LaPointe , Robert D. Mussell
IPC分类号： C07F7/02 , C07F5/02 , C07F7/08 , C07F7/30 , C07F17/00 , C08F4/60 , C08F4/659 , C08F4/6592 , C08F10/00 , C25B3/02 , C07F7/04
CPC分类号： C25B3/02 , C07F17/00 , C07F5/027 , C07F7/0809 , C07F7/082 , C08F10/00 , C08F4/65908 , C08F4/6592
摘要： Catalyst systems useful in addition polymerization reactions comprising a Group 4 metal complex and a silylium salt activating cocatalyst are prepared by contacting the metal complex with a silylium salt of a compatible, non-coordinating anion, optionally the silylium salt is prepared by electrochemical oxidation and splitting of the corresponding disilane compound.
摘要翻译：通过使金属络合物与相容的非配位阴离子的甲硅烷鎓盐接触来制备可用于包含第4族金属络合物和甲硅烷鎓盐活化助催化剂的加成聚合反应中的催化剂体系，任选地，通过电化学氧化和裂解制备甲硅烷基盐的相应的乙硅烷化合物。

7. 发明授权

US5959016A Composition for preparing a solvent-resistant coating 失效
标题翻译：用于制备耐溶剂涂层的组合物
公开(公告)号：US5959016A
公开(公告)日：1999-09-28
申请号：US904087
申请日：1997-07-31
申请人： Donald L. Schmidt , Robert D. Mussell
发明人： Donald L. Schmidt , Robert D. Mussell
IPC分类号： C08L101/08 , C08K5/00 , C09D5/00 , C09D5/02 , C09D157/00 , C08K3/00
CPC分类号： C09D5/008 , C08K5/0091
摘要： A water-based polymer composition containing a polyvalent metal complex and a polymer having pendant strong cationic groups and weak acid salt groups forms fast dry-to-the-touch coatings that are resistant to water and many organic solvents. These coatings can be removed with ammonia-containing solvents.
摘要翻译：含有多价金属络合物和具有强阳离子基团和弱酸盐基团的聚合物的水基聚合物组合物形成耐水和许多有机溶剂的快速干 - 接触涂层。这些涂层可以用含氨溶剂除去。

8. 发明授权

US5882810A Active layer for membrane electrode assembly 失效
标题翻译：膜电极组件的活性层
公开(公告)号：US5882810A
公开(公告)日：1999-03-16
申请号：US813773
申请日：1997-03-07
申请人： Robert D. Mussell , Timothy J. Rehg
发明人： Robert D. Mussell , Timothy J. Rehg
IPC分类号： H01M4/86 , H01M4/88 , H01M4/92 , H01M8/02 , H01M8/04 , H01M8/10
CPC分类号： H01M4/8657 , H01M4/8642 , H01M4/8668 , H01M4/926 , H01M8/1004 , H01M2300/0082 , H01M4/8605 , H01M8/0228 , H01M8/04291
摘要： Described is a membrane electrode assembly having an ion exchange membrane, and at least two active layers positioned on the same side of the membrane; wherein the active layers containing catalytically-active particles and an ionomer; the average equivalent weights of the ionomers in the layers differ by at least 50; and the active layer positioned closest to the membrane contains the ionomer with the lower average equivalent weight. This membrane electrode assembly, when utilized in a fuel cell, provides a relatively high voltage at a given current density and gas flow rate.
摘要翻译：描述了具有离子交换膜和位于膜的同一侧上的至少两个活性层的膜电极组件; 其中所述活性层含有催化活性颗粒和离聚物; 层中离聚物的平均当量重量至少为50; 最靠近膜的活性层含有平均当量较低的离聚物。当在燃料电池中使用时，该膜电极组件在给定的电流密度和气体流速下提供相对较高的电压。

9. 发明授权

US5702755A Process for preparing a membrane/electrode assembly 失效
标题翻译：制备膜/电极组件的方法
公开(公告)号：US5702755A
公开(公告)日：1997-12-30
申请号：US554066
申请日：1995-11-06
申请人： Robert D. Mussell
发明人： Robert D. Mussell
IPC分类号： H01M4/86 , H01M4/88 , H01M4/92 , H01M8/02 , H01M8/04 , H01M8/10
CPC分类号： H01M4/8828 , H01M4/8605 , H01M4/8882 , H01M4/926 , H01M8/1004 , H01M2300/0082 , H01M8/04291
摘要： A composition comprising (a) catalytically-active particles, (b) an organic compound having a pKa of at least about 18 and a basicity parameter, .beta., of less than 0.66, and (c) a polymeric binder. Also described is a process for preparing a membrane/electrode assembly, which comprises the sequential steps of (i) applying a layer of the composition of the invention to a solid polymer electrolyte, a carbon fiber paper, or a release substrate; (ii) heating the composition under conditions sufficient to volatilize at least 95 percent of component (b); and (iii) positioning the composition in contact with the solid polymer electrolyte, if the composition was not applied directly to the solid polymer electrolyte, forming the membrane/electrode assembly thereby. It has been discovered that the composition and process of the invention, when used to prepare a membrane electrode assembly (MEA) having a solid polymer electrolyte, provides an MEA which provides a relatively high voltage at a given current density and gas flow rate in a fuel cell.
摘要翻译：一种组合物，其包含（a）催化活性颗粒，（b）具有至少约18的pKa和碱度参数β的小于0.66的有机化合物，和（c）聚合物粘合剂。还描述了制备膜/电极组件的方法，其包括以下顺序步骤：（i）将本发明的组合物层施加到固体聚合物电解质，碳纤维纸或剥离基材上; （ii）在足以挥发至少95％的组分（b）的条件下加热组合物; 和（iii）将组合物定位为与固体聚合物电解质接触，如果该组合物没有直接施加到固体聚合物电解质上，则由此形成膜/电极组合物。已经发现，当用于制备具有固体聚合物电解质的膜电极组件（MEA）时，本发明的组合物和方法提供了MEA，其以给定的电流密度和气体流速提供相对高的电压燃料电池。

10. 发明授权

US5620807A Flow field assembly for electrochemical fuel cells 失效
标题翻译：电化学燃料电池的流场组装
公开(公告)号：US5620807A
公开(公告)日：1997-04-15
申请号：US522482
申请日：1995-08-31
申请人： Robert D. Mussell , Steven P. Webb , Carey L. Scortichini , Keith R. Plowman
发明人： Robert D. Mussell , Steven P. Webb , Carey L. Scortichini , Keith R. Plowman
IPC分类号： H01M4/92 , H01M8/10
CPC分类号： H01M4/926 , H01M8/1004 , H01M2300/0082
摘要： An electrochemical fuel cell having a membrane electrode assembly and a layer of an electrically conductive porous material adjacent thereto which has at least two portions with different mean pore sizes, wherein a first portion of the layer adjacent to the membrane electrode assembly has a porosity no greater than a second portion of the layer adjacent to the opposite side of the layer; the second portion has a porosity of at least about 82 percent; and the second portion has an mean pore size which is at least about 10 microns and at least ten times greater than the mean pore size of the first portion.
摘要翻译：一种具有膜电极组件和与其相邻的导电多孔材料层的电化学燃料电池，其具有至少两个具有不同平均孔径的部分，其中与膜电极组件相邻的层的第一部分的孔隙率不大比层的与相对侧相邻的层的第二部分; 第二部分具有至少约82％的孔隙率; 并且第二部分具有比第一部分的平均孔径大至少约10微米且至少十倍的平均孔径。

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