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1. 发明授权

US07094901B2 Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom 失效
标题翻译：包括羟基或静止反应性官能团的膨胀的阴离子化合物及其催化剂活化剂
公开(公告)号：US07094901B2
公开(公告)日：2006-08-22
申请号：US10875475
申请日：2004-06-24
申请人： David A. Babb , David R. Neithamer , Richard E. Campbell, Jr. , Grant B. Jacobsen , Edmund M. Carnahan
发明人： David A. Babb , David R. Neithamer , Richard E. Campbell, Jr. , Grant B. Jacobsen , Edmund M. Carnahan
IPC分类号： B01J31/00 , C07F15/00 , C07D233/00 , C07D487/00 , C03F4/06
CPC分类号： C08F10/00 , C07F5/027 , C07F5/062 , C07F5/066 , C07F7/0803 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F210/16 , C08F4/61908 , C08F4/65908 , C08F210/14 , C08F2500/12
摘要： A cocatalyst or cocatalyst component, including a compound corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of from 1 to 80 atoms, not counting hydrogen atoms, Z* is an anion group of from 1 to 50 atoms, not counting hydrogen atoms, containing two or more Lewis base sites; J* is a Lewis acid of from 1 to 80, not counting hydrogen atoms, coordinated to at least one Lewis base site, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d, and provided further that one or more of A*, Z* or J* comprises a hydroxyl group or a polar group containing quiescent reactive functionality.
摘要翻译：助催化剂或助催化剂组分，包括对应于下列化学式的化合物：（A * a + b）b（Z * J * 其中：A *是1至80个原子的阳离子，不计数氢原子，Z *是1至50个原子的阴离子基团，不是计数含有两个或更多个路易斯碱基位点的氢原子; J *是1至80的路易斯酸，不计数氢原子，与至少一个路易斯碱基位点配位，并且任选地两个或更多个这样的J *基团可以在具有多个路易斯酸官能团的部分中连接在一起，j是 2至12，a，b，c和d为1至3的整数，条件是axb等于cxd，并进一步提供A *，Z *或J *中的一种或多种包含羟基或含有静止反应性官能团的极性基团。

2. 发明授权

US06627573B2 Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom 失效
标题翻译：包括羟基或静止反应性官能团的膨胀的阴离子化合物及其催化剂活化剂
公开(公告)号：US06627573B2
公开(公告)日：2003-09-30
申请号：US09904422
申请日：2001-07-12
申请人： David A. Babb , Richard E. Campbell, Jr. , David R. Neithamer , Grant B. Jacobsen , Edmund M. Carnahan
发明人： David A. Babb , Richard E. Campbell, Jr. , David R. Neithamer , Grant B. Jacobsen , Edmund M. Carnahan
IPC分类号： B01J3000
CPC分类号： C08F10/00 , C07F5/027 , C07F5/062 , C07F5/066 , C07F7/0803 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F210/16 , C08F4/61908 , C08F4/65908 , C08F210/14 , C08F2500/12
摘要： A compound useful as a cocatalyst or cocatalyst component, especially for use as an addition polymerization catalyst compound, corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, said A* having a charge +a, Z* is an anion group of from 1 to 50, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d, and provided further that one or more of A*, Z* or J* comprises a hydroxyl group or a polar group containing quiescent reactive functionality.
摘要翻译：用作助催化剂或助催化剂组分的化合物，特别是用作加成聚合催化剂化合物，其对应于下式：其中：A *是不计氢原子的1至80个，优选1至60个原子的阳离子，所述化合物 A *具有电荷+ a，Z *是1至50个，优选1至30个原子的阴离子基团，不计算氢原子，进一步含有两个或更多个路易斯碱基位点; J *各自独立地为路易斯酸 1至80个，优选1至60个原子，不计数氢原子，与Z *的至少一个路易斯碱碱基位点配位，并且任选地两个或多个这样的J *基团可以连接在具有多个路易斯酸官能团的部分中， j是2至12的数字，a，b，c和d是1至3的整数，条件是axb等于cxd，进一步提供A *，Z *或J *中的一个或多个包括羟基或含有静止反应性官能团的极性基团。

3. 发明授权

US06344529B1 Zwitterionic catalyst activator 有权
标题翻译：两性离子催化剂活化剂
公开(公告)号：US06344529B1
公开(公告)日：2002-02-05
申请号：US09445209
申请日：1999-12-06
申请人： Edmund M. Carnahan , Grant B. Jacobsen , Jerzy Klosin , Peter N. Nickias , David J. Schwartz , David R. Neithamer
发明人： Edmund M. Carnahan , Grant B. Jacobsen , Jerzy Klosin , Peter N. Nickias , David J. Schwartz , David R. Neithamer
IPC分类号： C08F452
CPC分类号： C07F5/066 , C07F5/00 , C07F5/027 , C08F4/65916 , C08F4/65922 , C08F10/00 , C08F4/65908
摘要： Disclosed are compounds useful as catalyst activators for olefin polymerization, comprising structures of the following formulae: wherein: L+ is a protonated derivative of an element of Group 15 of the Periodic Table of the Elements, additionally bearing two hydrocarbyl substituents of from 1 to 50 carbons each, or a positively charged derivative of an element of Group 14 of the Periodic Table of the Elements, said Group 14 element being substituted with three hydrocarbyl substituents of from 1 to 50 carbons each; R1 is a divalent linking group of from 1 to 40 non-hydrogen atoms; R2 independently each occurrence is a ligand group of from 1 to 50 nonhydrogen atoms with the proviso that in a sufficient number of occurrences to balance charge in the compound, R2 is L+—R1—; M1 is boron, aluminum or gallium; Arf independently each occurrence is a monovalent, fluorinated organic group containing from 6 to 100 non-hydrogen atoms; Y is a Group 15 element; and Z is a Group 14 element.
摘要翻译：公开了可用作烯烃聚合的催化剂活化剂的化合物，其包含下式的结构：其中：L +是元素周期表第15族元素的质子化衍生物，另外带有1至50个碳的烃基取代基每个元素或元素周期表第14族元素的带正电荷的衍生物，所述第14族元素被各自为1至50个碳的三个烃基取代基取代; R 1为1至40的二价连接基团非氢原子; R2各自独立地为1至50个非氢原子的配体基团，条件是在足够数量的化合物中平衡电荷的情况下，R2为L + -R1-; M1为硼，铝或镓; Arf各自独立地为含有6至100个非氢原子的单价氟化有机基团; Y为第15族元素; 而Z是第14组元素。

4. 发明授权

US07491672B2 Chemically-modified supports and supported catalyst systems prepared therefrom 失效
标题翻译：由其制备的化学改性的载体和负载的催化剂体系
公开(公告)号：US07491672B2
公开(公告)日：2009-02-17
申请号：US11526242
申请日：2006-09-25
申请人： Edmund M. Carnahan , David R. Neithamer
发明人： Edmund M. Carnahan , David R. Neithamer
IPC分类号： B01J21/00
CPC分类号： B01J31/14 , B01J31/0239 , B01J31/0254 , B01J31/0268 , B01J31/0274 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F4/65916 , C08F210/14
摘要： The present invention provides a chemically-modified support comprising an inorganic oxide containing optionally functionalized hydroxyl groups, having chemically linked thereto the cation of a cation/anion pair. The present invention further provides a supported catalyst system comprising the chemically-modified support as described above, and a transition metal compound of Groups 3-10 (preferably a Group 4 metal compound) containing at least one π-bonded anionic ligand group, said transition metal compound being capable of reacting with the chemically-modified support through the cation of the cation/anion pair to thereby render the transition metal compound catalytically active. The present invention further provides a process for preparing the chemically-modified support of the invention. The present invention further provides an addition polymerization process comprising contacting one or more addition polymerizable monomers with the supported catalyst system of the invention under addition polymerization conditions.
摘要翻译：本发明提供一种化学修饰的载体，其包含含有任选官能化羟基的无机氧化物，其与阳离子/阴离子对的阳离子化学连接。本发明进一步提供了一种载体催化剂体系，其包括如上所述的化学改性的载体和含有至少一个π键合的阴离子配体基团的3-10族（优选第4族金属化合物）的过渡金属化合物，所述转变金属化合物能够通过阳离子/阴离子对的阳离子与化学改性的载体反应，从而使过渡金属化合物具有催化活性。本发明还提供了制备本发明的化学改性载体的方法。本发明进一步提供加成聚合方法，其包括在加成聚合条件下使一种或多种可加聚的单体与本发明的负载型催化剂体系接触。

5. 发明授权

US6087293A Supported catalyst containing tethered cation forming activator 失效
标题翻译：负载催化剂含有束缚阳离子形成活化剂
公开(公告)号：US6087293A
公开(公告)日：2000-07-11
申请号：US117470
申请日：1998-03-02
申请人： Edmund M. Carnahan , Michael J. Carney , David R. Neithamer , Peter N. Nickias , Keng-Yu Shih , Lee Spencer
发明人： Edmund M. Carnahan , Michael J. Carney , David R. Neithamer , Peter N. Nickias , Keng-Yu Shih , Lee Spencer
IPC分类号： C08F4/02 , C08F4/603 , C08F4/619 , C08F4/6192 , C08F4/643 , C08F4/645 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , B01J31/00 , C08F4/06 , C08F4/44
CPC分类号： C08F10/00 , C08F10/02 , C08F4/025 , C08F110/02 , C08F210/16 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65912 , C08F4/6592 , C08F4/65925 , Y10S526/943
摘要： A support for use in preparing supported catalysts for addition polymerizations comprising the reaction product of: (A) an inorganic oxide material comprising reactive surface hydroxyl groups, at least some of said hydroxyl groups optionally having been functionalized an converted to a reactive silano moiety corresponding to the formula: --OSiR.sub.2 H, wherein R, independently each occurrence, is hydrogen C.sub.1-20 hydrocarbyl, or C.sub.1-20 hydrocarbyloxy, said inorganic oxide or functionalized derivative thereof comprising less than 1.0 mmol of reactive surface hydroxyl functionality per gram, and (B) an activator compound comprising: b.sub.1) a cation which is capable of reacting with a transition metal compound to form a catalytically active transition metal complex, and b.sub.2) a compatible anion containing at least one substituent able to react with the inorgnaic oxide, with residual hydroxyl functionality of the inorganic oxide, or with the reactive silane moiety, hereby covalently bonding the compatible anion to the support, catalysts formed therefrom, process of manufacture and the method to use.
摘要翻译： PCT No.PCT / US96 / 17140 Sec。 371日期1998年3月2日 102（e）1998年3月2日PCT PCT 1996年10月25日PCT公布。公开号WO97 / 19959 日期1997年6月5日，用于制备用于加成聚合的载体催化剂的载体，其包括以下反应产物：（A）包含反应性表面羟基的无机氧化物材料，至少一些所述羟基任选已被官能化转化为对应于式-OSiR 2 H的反应性硅烷基部分，其中R各自独立地为氢C 1-20烃基或C 1-20烃氧基，所述无机氧化物或其官能化衍生物包含小于1.0mmol反应性表面羟基官能度/克和（B）活化剂化合物，其包含：b1）能够与过渡金属化合物反应形成催化活性过渡金属络合物的阳离子，和b2）含有至少一个能够与无规性反应的取代基的相容阴离子氧化物，具有无机氧化物的残余羟基官能团，或与反应性硅烷部分共价共轭将相容的阴离子与载体，由其形成的催化剂，制备方法和使用方法相结合。

6. 发明授权

US06696379B1 Supported modified alumoxane catalyst activator 失效
标题翻译：负载改性铝氧烷催化剂活化剂
公开(公告)号：US06696379B1
公开(公告)日：2004-02-24
申请号：US09502502
申请日：2000-02-11
申请人： Edmund M. Carnahan , Grant B. Jacobsen , Eugene Y. Chen , James C. Stevens
发明人： Edmund M. Carnahan , Grant B. Jacobsen , Eugene Y. Chen , James C. Stevens
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C07F5/068 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F210/16 , C08F4/65912 , C08F4/642 , C08F4/6428 , C08F2/34 , C08F210/08 , C08F210/14 , C08F2500/12 , C08F2500/08
摘要： A supported catalyst composition comprising: A1) a mixture of aluminum containing Lewis acids of the formulas: [(—AlQ1—O—)z(—AlArf—O—)z′] and (Arfz″Al2Q16−z″) where; Q1 independently each occurrence is C1-20 alkyl; Arf is a fluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms; z is a number from 1 to 50; z′ is a number from 1 to 50; and z″ is an number from 0 to 6; or A2) a fluorohydrocarbyl-substituted alumoxane compound corresponding to the formula: R1—(AlR3O)m—R2, wherein: R1 and R2 independently each occurrence is a C1-40 aliphatic or aromatic group or a fluorinated derivative thereof or R1 and R2 together form a covalent bond; R3 independently each occurrence is a monovalent, fluorinated organic group containing from 1 to 100 carbon atoms or R1, with the proviso that in at least one occurrence per molecule, R3 is a monovalent, fluorinated organic group containing from 1 to 100 carbon atoms, and m is a number from 1 to 1000; B) a Group 3, 4, or Lanthanide metal complex containing from 1 to 3 &pgr;-bonded anionic or neutral ligand groups; and C) a support.
摘要翻译：一种载体催化剂组合物，其包含：A1）含有下式的含铝路易斯酸的混合物：其中; Q 1各自独立地为C 1-20烷基; Ar f为6至30碳的氟化芳族烃基部分原子; z是1至50的数; z'是1至50的数; andz“是从0到6的数字; 或A2）对应于下式的氟代烃基取代的铝氧烷化合物：其中：R 1和R 2各自独立地为C 1-4脂族或芳族基团或其氟化衍生物或R 1和R 2 >共同形成共价键; R 3各自独立地为含有1至100个碳原子或R 1的单价含氟有机基团，条件是在每分子至少一次出现时，R 3，是含有1至100个碳原子的单价氟化有机基团，并且m为1至1000的数; B）含有1至3个π键合的阴离子或中性配体基团的第3,4族或镧系元素金属络合物; 和C）支持。

7. 发明授权

US06475945B1 Functionalized catalyst supports and supported catalyst systems 有权
标题翻译：官能化催化剂载体和负载型催化剂体系
公开(公告)号：US06475945B1
公开(公告)日：2002-11-05
申请号：US09554805
申请日：2000-05-18
申请人： Edmund M. Carnahan , Grant B. Jacobsen
发明人： Edmund M. Carnahan , Grant B. Jacobsen
IPC分类号： B01J2904
CPC分类号： C08F10/02 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/16 , C08L23/0815 , C08L2314/06 , Y10S526/943 , C08F4/65916 , C08F2/14 , C08F210/08 , C08F2500/12 , C08F2500/14 , C08F2500/07
摘要： The present invention relates to functionalized catalyst supports that are useful in the formation of supported polymerization catalysts, supported catalysts derived from such functionalized catalyst supports, methods for preparing such functionalized catalyst supports and supported catalysts, and polymerization processes utilizing such supported catalysts. The functionalized catalyst support comprises a particulated support material having chemically bonded thereto a plurality of aluminum-containing groups derived from a non-ionic Lewis acid, said aluminum-containing groups: containing at least one fluoro-substituted hydrocarbyl ligand containing from 1 to 20 carbons, said hydrocarbyl ligand being bonded to aluminum, and being bonded to said support material, optionally through a bridging moiety, said composition being capable of activating a Group 3-10 metal complex for the addition polymerization of one or more addition polymerizable monomers.
摘要翻译：本发明涉及可用于形成负载型聚合催化剂的官能化催化剂载体，衍生自这种官能化催化剂载体的负载催化剂，制备这种官能化催化剂载体的方法和负载催化剂，以及使用这种负载型催化剂的聚合方法。官能化的催化剂载体包括具有化学键合到其上的多个含非离子路易斯酸的含铝基团的微粒支持材料，所述含铝基团：含有至少一个含有1至20个碳的氟取代的烃基配体所述烃基配体键合到铝上，并且任选地通过桥连部分键合到所述载体材料上，所述组合物能够活化用于加成聚合一种或多种可加聚单体的3-10族金属络合物。

8. 发明授权

US08907034B2 Comb architecture olefin block copolymers 有权
标题翻译：梳结构烯烃嵌段共聚物
公开(公告)号：US08907034B2
公开(公告)日：2014-12-09
申请号：US13228892
申请日：2011-09-09
申请人： Phillip D. Hustad , Endre Szuromi , Francis J. Timmers , Edmund M. Carnahan , Thomas P. Clark , Gordon R. Roof , Sara B. Klamo , Daniel J. Arriola
发明人： Phillip D. Hustad , Endre Szuromi , Francis J. Timmers , Edmund M. Carnahan , Thomas P. Clark , Gordon R. Roof , Sara B. Klamo , Daniel J. Arriola
IPC分类号： C08F293/00 , C08F4/52 , C08F4/50 , C08F4/76 , C08F4/00 , C08F210/16 , C08F297/08
CPC分类号： C08F210/16 , C08F297/08 , C08F2410/01 , C08F2410/04 , C08F4/64048 , C08F4/64144 , C08F4/64193
摘要： Embodiments of the invention provide a comb architecture olefin block copolymer, a method of making the comb olefin block copolymer and blends comprising the comb olefin block copolymer.
摘要翻译：本发明的实施方案提供梳状结构烯烃嵌段共聚物，制备梳状烯烃嵌段共聚物的方法和包含梳形烯烃嵌段共聚物的共混物。

9. 发明授权

US07989551B2 Pseudo-block copolymers and process employing chain shuttling agent 有权
标题翻译：伪嵌段共聚物和使用链穿梭剂的方法
公开(公告)号：US07989551B2
公开(公告)日：2011-08-02
申请号：US11817344
申请日：2006-01-30
申请人： Daniel J. Arriola , Edmund M. Carnahan , Marilyn Bokota , Phillip D. Hustad , Roger L. Kuhlman , Timothy T. Wenzel , Pamela J. Stirn
发明人： Daniel J. Arriola , Edmund M. Carnahan , Marilyn Bokota , Phillip D. Hustad , Roger L. Kuhlman , Timothy T. Wenzel , Pamela J. Stirn
IPC分类号： C08F2/38 , C08F297/08 , C08F4/646
CPC分类号： C08F10/00 , C08F4/659 , C08F4/65908 , C08F4/6592 , C08F4/65927 , C08F210/06 , C08F210/16 , C08F297/06 , C08F297/08 , C08F297/083 , C08F2410/01 , C08L23/10 , C08L23/16 , C08L2308/00 , C08F4/65912 , C08F4/6465 , C08F2/38 , C08L2666/06 , C08F2500/17 , C08F2500/08 , C08F2500/20 , C08F2500/03 , C08F4/64048 , C08F4/64193 , C08F4/64144
摘要： A process for the polymerization of one or more addition polymerizable monomers to form a copolymer comprising multiple regions or segments of differentiated polymer composition or properties comprising contacting an addition polymerizable monomer or mixture of monomers under addition polymerization conditions with a composition comprising at least one olefin polymerization catalyst, a cocatalyst and a chain shuttling agent, said process being characterized by formation of at least some of the growing polymer chains under differentiated process conditions such that two or more blocks or segments formed within at least some of the resulting polymer are chemically or physically distinguishable.
摘要翻译：一种用于聚合一种或多种可加聚的单体以形成共聚物的方法，所述共聚物包含分化聚合物组合物或性质的多个区域或链段，包括在加成聚合条件下使加成聚合单体或单体混合物与包含至少一种烯烃聚合催化剂，助催化剂和链穿梭剂，所述方法的特征在于在不同的工艺条件下形成至少一些生长的聚合物链，使得在至少一些所得聚合物内形成的两个或多个嵌段或链段是化学或物理的可区分

10. 发明申请

US20110124818A1 Catalyst Composition Comprising Shuttling Agent for Ethylene Multi-Block Copolymer Formation 有权
公开(公告)号：US20110124818A1
公开(公告)日：2011-05-26
申请号：US12962822
申请日：2010-12-08
申请人： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
发明人： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
IPC分类号： C08F210/16 , C08F4/30 , C08F216/04
CPC分类号： B32B27/327 , B32B27/06 , B32B27/32 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/14 , C08F210/16 , C08F295/00 , C08F297/00 , C08F297/08 , C08F297/083 , C08F297/086 , C08F2410/01 , C08F2410/04 , C08F2420/02 , C08L23/02 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08L23/10 , C08L53/00 , C08L53/005 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , C08F2/38 , C08F4/65904 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F4/64148 , C08F4/64193 , C08F4/64048 , C08F4/6411 , C08F4/64144 , C08F2500/08 , C08F4/64113 , C08L2666/02 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F210/08 , C08F2500/11 , C08F2500/21 , C08F210/02 , C08F212/08 , C08F232/02 , C08F232/08
摘要： A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

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