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    • 1. 发明授权
    • Additives to prevent degradation of alkyl-hydrogen siloxanes
    • 用于防止烷基氢硅氧烷降解的添加剂
    • US07531590B2
    • 2009-05-12
    • US11496135
    • 2006-07-31
    • Daniel J. TeffGregory B. SmithJohn L. ChagollaTim S. Andreyka
    • Daniel J. TeffGregory B. SmithJohn L. ChagollaTim S. Andreyka
    • C08K5/05
    • C23C16/4402C08G77/12C08K5/13C08L83/04Y10T428/31663
    • An organohydrosiloxane composition comprising: a) one or more organohydrosiloxane compounds, each having at least one [—HSiR—O—] unit, wherein R═C1-C18 linear, branched, or cyclic alkyl, C1-C18 linear, branched, or cyclic alkoxy, or substituted or unsubstituted aryl, and b) an antioxidant compound shown in Formula (1) wherein the antioxidant compound is a phenolic compound and is present in a concentration from about 1 ppm to about 5,000 ppm and wherein R1 through R5 can each independently be H, OH, C1-C18 linear, branched, or cyclic alkyl, C1-C18 linear, branched, or cyclic alkoxy or substituted or unsubstituted aryl. The compositions of present invention exhibit stability and significantly extend the shelf life of organohydrosiloxane products and allow greater flexibility in handling these products in chemical processes or semiconductor manufacturing. The resulting stabilization of siloxanes prevents the possibility of complete polymerization (i.e., solidification) of product in chemical delivery lines or valves, which lowers equipment maintenance and costs and reduces time the machinery is out of production.
    • 一种有机氢硅氧烷组合物,其包含:a)一种或多种有机氢化硅氧烷化合物,其各自具有至少一个[-HSi-O-]单元,其中R-C1-C18直链,支链或环状烷基,C1-C18直链,支链或环状 烷氧基或取代或未取代的芳基,和b)式(1)所示的抗氧化剂化合物,其中抗氧化剂化合物是酚类化合物,并且以约1ppm至约5,000ppm的浓度存在,并且其中R 1至R 5可以各自独立地 是H,OH,C 1 -C 18直链,支链或环状烷基,C 1 -C 18直链,支链或环状烷氧基或取代或未取代的芳基。 本发明的组合物表现出稳定性并且显着地延长了有机氢硅氧烷产品的保存期限,并且在化学工艺或半导体制造中处理这些产品时具有更大的灵活性。 所得的硅氧烷稳定化防止化学输送管线或阀门中产物完全聚合(即固化)的可能性,这降低了设备维护和成本,并缩短了机器停产的时间。