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    • 1. 发明授权
    • Aqueous gels
    • 水性凝胶
    • US4148746A
    • 1979-04-10
    • US836863
    • 1977-09-26
    • Daniel F. KlemmensenRichard G. Bauer
    • Daniel F. KlemmensenRichard G. Bauer
    • C08F220/04C08F220/12C09K8/512C09K8/588C09K8/88E21B33/138
    • C09K8/887C08F220/04C08F220/12C09K8/512C09K8/588Y10S507/936Y10S524/914
    • There is disclosed an aqueous medium comprising water to which has been added a water thickening amount of a water thickening polymer which is prepared by polymerizing at least one alkyl acrylate monomer and at least one carboxylic polymerizable monomer selected from the group consisting of acrylic acid and methacrylic acid which are present from 20 to 95 parts by weight per hundred parts of total monomer being polymerized and utilizing, as an ionic emulsifier, an emulsifier selected from the group consisting of disodium or diammonium nonylphenoxy polyethoxy sulfosuccinate having the general formula:CH.sub.3 (CH.sub.2).sub.8 C.sub.6 H.sub.4 O(CH.sub.2 CH.sub.2 O).sub.8-16 COCH.sub.2 CH(COOM)SO.sub.3 Qwherein Q is sodium or ammonium and a sodium or ammonium lauryl polyethoxysulfate having the general formula:CH.sub.2 (CH.sub.2).sub.11 O(CH.sub.2 CH.sub.2 O).sub.8-16 SO.sub.3 Qwherein Q is sodium or ammonium, said polymer in latex form being neutralized to a pH ranging between a pH of 5.5 to 11.5. Such polymers may also be gelled with water soluble polyvalent compounds such as sodium dichromate and water soluble reducing agents such as sodium hydrosulfite. The aqueous gels are employed in enhanced oil recovery.
    • 公开了包含水的水性介质,其中加入了水增稠量的水增稠聚合物,其通过聚合至少一种丙烯酸烷基酯单体和至少一种选自丙烯酸和甲基丙烯酸酯的羧基可聚合单体制备 酸,其以每100份总共单体为20至95重量份聚合并且作为离子乳化剂使用选自具有以下通式的二钠或壬基苯氧基聚乙氧基磺基琥珀酸二铵的乳化剂:
    • 3. 发明授权
    • Asphalt cement modification
    • 沥青水泥改性
    • US5637640A
    • 1997-06-10
    • US621277
    • 1996-03-25
    • Gerald O. SchulzDaniel F. Klemmensen
    • Gerald O. SchulzDaniel F. Klemmensen
    • C08F236/10C08L95/00C08L33/26C08L9/08C08L33/10
    • C08L95/00C08F236/10
    • It has been determined that rubbery terpolymers of a conjugated diolefin monomer, a vinyl aromatic monomer, and N-(isobutoxymethyl) acrylamide (IBMA) tan be used to modify asphalt cement to greatly enhance the resistance to shoving, rutting, and low temperature cracking of asphalt concretes made therewith. These rubbery polymers have a Mooney viscosity which is within the range of about 35 to about 80. It has further been determined that these rubbery terpolymers are compatible with virtually all types of asphalt. It is particularly preferred for the rubbery polymers of this invention to also contain repeat units which are derived from hydroxypropyl methacrylate (HPMA). The subject invention more specifically relates to a modified asphalt cement which is comprised of (1) from about 90 weight percent to about 99 weight percent of asphalt; and (2) from about 1 weight percent to about 10 weight percent of a rubbery polymer which is comprised of repeat units which are derived from (a) about 64 weight percent to about 84.9 weight percent of a conjugated diolefin monomer, (b) about 15 weight percent to about 33 weight percent of a vinyl aromatic monomer, and (c) about 0.1 weight percent to about 3 weight percent of isobutoxymethyl acrylamide.
    • 已经确定,使用共轭二烯烃单体,乙烯基芳族单体和N-(异丁氧基甲基)丙烯酰胺(IBMA)棕褐色的橡胶状三元共聚物来改性沥青粘合剂,以大大提高拉伸,车辙和低温开裂的抗性 沥青混凝土制成。 这些橡胶状聚合物的门尼粘度在约35至约80的范围内。进一步确定这些橡胶状三元共聚物几乎与所有类型的沥青相容。 特别优选本发明的橡胶状聚合物还含有衍生自甲基丙烯酸羟丙酯(HPMA)的重复单元。 本发明更具体地涉及一种改性沥青胶泥,其包含(1)约90重量%至约99重量%的沥青; (2)约1重量%至约10重量%的橡胶状聚合物,其由衍生自(a)约64重量%至约84.9重量%的共轭二烯烃单体的重复单元组成,(b)约 15重量%至约33重量%的乙烯基芳族单体,和(c)约0.1重量%至约3重量%的异丁氧基甲基丙烯酰胺。
    • 4. 发明授权
    • Asphalt cement modification
    • 沥青水泥改性
    • US5534568A
    • 1996-07-09
    • US386779
    • 1995-02-10
    • Gerald O. SchulzDaniel F. Klemmensen
    • Gerald O. SchulzDaniel F. Klemmensen
    • C08F236/10C08L95/00
    • C08L95/00C08F236/10
    • It has been determined that rubbery terpolymers of a conjugated diolefin monomer, a vinyl aromatic monomer, and N-(isobutoxymethyl) acrylamide (IBMA) can be used to modify asphalt cement to greatly enhance the resistance to shoving, rutting, and low temperature cracking of asphalt concretes made therewith. These rubbery polymers have a Mooney viscosity which is within the range of about 35 to about 80. It has further been determined that these rubbery terpolymers are compatible with virtually all types of asphalt. It is particularly preferred for the rubbery polymers of this invention to also contain repeat units which are derived from hydroxypropyl methacrylate (HPMA). The subject invention more specifically relates to a modified asphalt cement which is comprised of (1) from about 90 weight percent to about 99 weight percent of asphalt; and (2) from about 1 weight percent to about 10 weight percent of a rubbery polymer which is comprised of repeat units which are derived from (a) about 64 weight percent to about 84.9 weight percent of a conjugated diolefin monomer, (b) about 15 weight percent to about 33 weight percent of a vinyl aromatic monomer, and (c) about 0.1 weight percent to about 3 weight percent of isobutoxymethyl acrylamide.
    • 已经确定,可以使用共轭二烯烃单体,乙烯基芳族单体和N-(异丁氧基甲基)丙烯酰胺(IBMA)的橡胶状三元共聚物来改性沥青混凝土,以大大增强对冲击,车辙和低温开裂的抵抗力 沥青混凝土制成。 这些橡胶状聚合物的门尼粘度在约35至约80的范围内。进一步确定这些橡胶状三元共聚物几乎与所有类型的沥青相容。 特别优选本发明的橡胶状聚合物还含有衍生自甲基丙烯酸羟丙酯(HPMA)的重复单元。 本发明更具体地涉及一种改性沥青胶泥,其包含(1)约90重量%至约99重量%的沥青; (2)约1重量%至约10重量%的橡胶状聚合物,其由衍生自(a)约64重量%至约84.9重量%的共轭二烯烃单体的重复单元组成,(b)约 15重量%至约33重量%的乙烯基芳族单体,和(c)约0.1重量%至约3重量%的异丁氧基甲基丙烯酰胺。