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1. 发明授权

US08034251B2 Azeotropic compositions of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf), 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb), and hydrogen fluoride (HF) 有权
标题翻译： 2-氯-3,3,3-三氟丙烯（HCFC-1233xf），2-氯-1,1,1,2-四氟丙烷（HCFC-244bb）和氟化氢（HF）的共沸组合物，
公开(公告)号：US08034251B2
公开(公告)日：2011-10-11
申请号：US12406653
申请日：2009-03-18
申请人： Daniel C. Merkel , Konstantin A. Pokrovski , Hsuehsung Tung , Hang T. Pham , Rajiv R. Singh
发明人： Daniel C. Merkel , Konstantin A. Pokrovski , Hsuehsung Tung , Hang T. Pham , Rajiv R. Singh
IPC分类号： C09K5/04 , C11D7/50 , C07C17/383
CPC分类号： C07C21/18 , C07C19/10
摘要： Provided are ternary azeotropic and azeotrope-like compositions of 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb), and hydrogen fluoride (HF). Such azeotropic and azeotrope-like compositions are useful as intermediates in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf).
摘要翻译：提供了2-氯-3,3,3-三氟丙烯（HCFO-1233xf），2-氯-1,1,1,2-四氟丙烷（HCFC-244bb）和氟化氢（的三元共沸和类共沸组合物） HF）。这种共沸和类共沸组合物可用作生产2,3,3,3-四氟丙烯（HFO-1234yf）的中间体。

2. 发明申请

US20090256110A1 AZEOTROPIC COMPOSITIONS OF 2-CHLORO-3,3,3-TRIFLUOROPROPENE (HCFC-1233xf), 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE (HCFC-244bb), AND HYDROGEN FLUORIDE (HF) 有权
标题翻译：二氯-3,3,3-三氟丙烯（HCFC-1233xf），2-氯代-1,1,1,2-四氢呋喃（HCFC-244bb）和氟化氢（HF）的AZEOTROPIC组合物
公开(公告)号：US20090256110A1
公开(公告)日：2009-10-15
申请号：US12406653
申请日：2009-03-18
申请人： DANIEL C. MERKEL , Konstantin A. Pokrovski , Hsuehsung Tung , Hang T. Pham , Rajiv R. Singh
发明人： DANIEL C. MERKEL , Konstantin A. Pokrovski , Hsuehsung Tung , Hang T. Pham , Rajiv R. Singh
IPC分类号： C09K3/00 , B01D3/36
CPC分类号： C07C21/18 , C07C19/10
摘要： Provided are ternary azeotropic and azeotrope-like compositions of 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb), and hydrogen fluoride (HF). Such azeotropic and azeotrope-like compositions are useful as intermediates in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf).
摘要翻译：提供了2-氯-3,3,3-三氟丙烯（HCFO-1233xf），2-氯-1,1,1,2-四氟丙烷（HCFC-244bb）和氟化氢（的三元共沸和类共沸组合物） HF）。这种共沸和类共沸组合物可用作生产2,3,3,3-四氟丙烯（HFO-1234yf）的中间体。

3. 发明申请

US20110210289A9 AZEOTROPIC COMPOSITIONS OF 2-CHLORO-3,3,3-TRIFLUOROPROPENE (HCFC-1233XF), 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE (HCFC-244BB), AND HYDROGEN FLUORIDE (HF) 有权
标题翻译：（HCFC-1233XF），2-氯代-1,1,1,2-四氢呋喃（HCFC-244BB）和氟化氢（HF）的AZEOOPOPIC组合物
公开(公告)号：US20110210289A9
公开(公告)日：2011-09-01
申请号：US12406653
申请日：2009-03-18
申请人： DANIEL C. MERKEL , Konstantin A. Pokrovski , Hsuehsung Tung , Hang T. Pham , Rajiv R. Singh
发明人： DANIEL C. MERKEL , Konstantin A. Pokrovski , Hsuehsung Tung , Hang T. Pham , Rajiv R. Singh
IPC分类号： C09K3/00 , B01D3/36
CPC分类号： C07C21/18 , C07C19/10
摘要： Provided are ternary azeotropic and azeotrope-like compositions of 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb), and hydrogen fluoride (HF). Such azeotropic and azeotrope-like compositions are useful as intermediates in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf).
摘要翻译：提供了2-氯-3,3,3-三氟丙烯（HCFO-1233xf），2-氯-1,1,1,2-四氟丙烷（HCFC-244bb）和氟化氢（的三元共沸和类共沸组合物） HF）。这种共沸和类共沸组合物可用作生产2,3,3,3-四氟丙烯（HFO-1234yf）的中间体。

4. 发明授权

US07803283B2 Azeotrope-like compositions of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf) and 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) 有权
标题翻译： 2-氯-3,3,3-三氟丙烯（HCFC-1233xf）和2-氯-1,1,1,2-四氟丙烷（HCFC-244bb）的类共沸组合物
公开(公告)号：US07803283B2
公开(公告)日：2010-09-28
申请号：US12405347
申请日：2009-03-17
申请人： Hang T. Pham , Rajiv R. Singh , Hsuehsung Tung , Konstantin A. Pokrovski , Daniel C. Merkel
发明人： Hang T. Pham , Rajiv R. Singh , Hsuehsung Tung , Konstantin A. Pokrovski , Daniel C. Merkel
IPC分类号： C09K5/04
CPC分类号： C07C19/10 , C07C17/386 , C07C21/18
摘要： Provided are azeotropic and azeotrope-like compositions of 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) and 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb). Such azeotropic and azeotrope-like compositions are useful as intermediates in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf).
摘要翻译：提供了2-氯-3,3,3-三氟丙烯（HCFO-1233xf）和2-氯-1,1,1,2-四氟丙烷（HCFC-244bb）的共沸和类共沸组合物。这种共沸和类共沸组合物可用作生产2,3,3,3-四氟丙烯（HFO-1234yf）的中间体。

5. 发明授权

US06759381B1 Azeotrope-like compositions of 1-chloro-1,3,3,3-tetrafluoropropane and 1,2-dichloro-3,3,3-trifluoropropene 有权
标题翻译： 1-氯-1,3,3,3-四氟丙烷和1,2-二氯-3,3,3-三氟丙烯的类共沸组合物
公开(公告)号：US06759381B1
公开(公告)日：2004-07-06
申请号：US10430078
申请日：2003-05-06
申请人： Robert C. Johnson , Daniel C. Merkel , Hsuehsung Tung
发明人： Robert C. Johnson , Daniel C. Merkel , Hsuehsung Tung
IPC分类号： C11D730
CPC分类号： C11D7/5045 , C07C17/206 , C07C19/10 , C07C21/18 , C11D7/28
摘要： Provided are azeotropic and azeotrope-like mixtures of 1-chloro-1,3,3,3-tetrafluoropropane and 1,2-dichloro-3,3,3-trifluoropropene that are useful as an intermediate in the production of HFC-245fa. HFC-245fa is useful as a nontoxic, zero ozone depleting fluorocarbon useful as solvents, blowing agents, refrigerants, cleaning agents, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing compositions and power cycle working fluids.
摘要翻译：提供了可用作HFC-245fa生产中间体的1-氯-1,3,3,3-四氟丙烷和1,2-二氯-3,3,3-三氟丙烯的共沸和类共沸混合物。 HFC-245fa可用作无毒，无臭氧消耗的氟烃，可用作溶剂，发泡剂，制冷剂，清洁剂，气溶胶推进剂，传热介质，气体电介质，灭火组合物和动力循环工作流体。

6. 发明授权

US07829748B1 Process for the manufacture of 1,3,3,3-tetrafluoropropene 有权
标题翻译：制备1,3,3,3-四氟丙烯的方法
公开(公告)号：US07829748B1
公开(公告)日：2010-11-09
申请号：US12563458
申请日：2009-09-21
申请人： Hsuehsung Tung , Robert C. Johnson , Daniel C. Merkel , Haiyou Wang
发明人： Hsuehsung Tung , Robert C. Johnson , Daniel C. Merkel , Haiyou Wang
IPC分类号： C07C17/00
CPC分类号： C07C17/21 , B01J21/18 , B01J27/10 , B01J27/138 , C07C17/087 , C07C17/25 , C07C21/18 , C07C19/10 , C07C19/08
摘要： The invention provides an economic process for the manufacture of 1,3,3,3-tetrafluoropropene (HFO-1234ze) by a two stage process. A vapor phase hydrofluorination of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) into 1-chloro-1,3,3,3-tetrafluoropropane (HCFC-244fa) and/or 1,1,1,3,3-pentafluoropropane (HFC-245fa) is conducted, followed by the thermal dehydrochlorination of HCFC-244fa and dehydro fluorination of HFC-245fa into HFO-1234ze in the presence of a catalyst which comprises one or more of alkali metal halides, alkaline earth metal halides, halogenated metal oxides, zero oxidation state metals, zinc halides, palladium halides, and activated carbon.
摘要翻译：本发明提供了通过两阶段方法制备1,3,3,3-四氟丙烯（HFO-1234ze）的经济方法。将1-氯-3,3,3-三氟丙烯（HCFC-1233zd）汽相氢氟化为1-氯-1,3,3,3-四氟丙烷（HCFC-244fa）和/或1,1,1,3 进行3-五氟丙烷（HFC-245fa），随后在含有一种或多种碱金属卤化物，碱土金属的催化剂存在下，将HCFC-244fa的热脱氯化氢和HFC-245fa的脱氟化氢分解成HFO-1234 卤化金属氧化物，零氧化态金属，卤化锌，钯卤化物和活性炭。

7. 发明申请

US20090182179A1 HYDROFLUORINATION OF 2-CHLORO-3,3,3-TRIFLUOROPROPENE TO 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE WITH CATALYSTS OF SBCL3, SBCL5, SBF5, TICL4, SNCL4, CR2O3 AND FLUORINATED CR2O3 审中-公开
标题翻译：将2-氯代-3,3,3-三氟苯酚与SBCL3，SBCL5，SBF5，TICL4，SNCL4，CR2O3和氟化物CR2O3的催化剂氢化成2-氯代-1,1,1,2-四氢呋喃
公开(公告)号：US20090182179A1
公开(公告)日：2009-07-16
申请号：US12338466
申请日：2008-12-18
申请人： Daniel C. Merkel , Robert C. Johnson , Hsuehsung Tung
发明人： Daniel C. Merkel , Robert C. Johnson , Hsuehsung Tung
IPC分类号： C07C19/10
CPC分类号： C07C17/087 , C07C19/10
摘要： A process for making 2-chloro-1,1,1,2-tetrafluoropropane comprising hydrofluorinating 2-chloro-3,3,3-trifluoropropene in the presence of a catalyst selected from the group consisting of: SbCl3, SbCl5, SbF5, TiCl4, SnCl4, Cr2O3, and fluorinated Cr2O3.
摘要翻译：一种制备2-氯-1,1,1,2-四氟丙烷的方法，包括在选自SbCl 3，SbCl 5，SbF 5，TiCl 4的催化剂存在下氢化2-氯-3,3,3-三氟丙烯，SnCl 4，Cr 2 O 3和氟化的Cr 2 O 3。

8. 发明授权

US07112708B2 Method of making difluoromethane, 1,1,1-trifluoroethane and 1,1-difluoroethane 有权
标题翻译：制备二氟甲烷，1,1,1-三氟乙烷和1,1-二氟乙烷的方法
公开(公告)号：US07112708B2
公开(公告)日：2006-09-26
申请号：US10816447
申请日：2004-04-01
申请人： Daniel C Merkel , Hsuehsung Tung , Ian Shankland
发明人： Daniel C Merkel , Hsuehsung Tung , Ian Shankland
IPC分类号： C07C17/20 , C07C17/21 , C07C17/93
CPC分类号： B01J27/125 , B01J21/18 , B01J27/08 , B01J27/135 , B01J37/26 , C07C17/206 , C07C17/208 , C07C17/21 , C07C19/08 , Y02P20/582
摘要： A process for the production of difluoromethane (HFC-32), 1,1,1-trifluoroethane (HFC-143a) and 1,1-difluoroethane (HFC-152a). In the process the following steps are employed: (a) providing a reaction vessel, (b) providing in the reaction vessel activated carbon impregnated with a strong Lewis acid fluorination catalys selected from halides of As, Sb, Al, Tl, In, V, Nb, Ta, Ti, Zr and Hf, (c) activating the catalyst by passing through the activated carbon impregnated with a strong Lewis acid fluorination catalyst anhydrous hydrogen fluoride gas and chlorine gas, (d) contacting, in a vapor state in the reaction vessel containing the activated catalyst, hydrogen fluoride and one or more halogenated hydrocarbons selected from chlorofluoromethane, dichloromethane, 1,1,1-trichloroethane, vinyl chloride, 1,1-dichloroethylene, 1,2-dichloroethylene, 1,2-dichloroethane, and 1,1-dichloroethane for a time and at a temperature to produce a product stream comprising hydrofluorocarbon product(s) corresponding to the chlorinated hydrocarbon reactant(s), and one or more of hydrogen chloride, unreactacted chlorinated hydrocarbon reactant(s), under-fluorinated intermediates, and unreacted hydrogen fluoride, and (e) separating the hydrofluorocarbon product(s) from the product stream.
摘要翻译：制备二氟甲烷（HFC-32），1,1,1-三氟乙烷（HFC-143a）和1,1-二氟乙烷（HFC-152a）的方法。在该过程中，采用以下步骤：（a）提供反应容器，（b）在反应容器中提供浸渍有选自As，Sb，Al，Tl，In，V ，Nb，Ta，Ti，Zr和Hf，（c）通过浸渍有强路易斯酸氟化催化剂的无水氟化氢气体和氯气的活性炭活化催化剂，（d）以蒸气状态在含有活化催化剂的反应容器，氟化氢和一种或多种选自氯氟甲烷，二氯甲烷，1,1,1-三氯乙烷，氯乙烯，1,1-二氯乙烯，1,2-二氯乙烯，1,2-二氯乙烷，和1,1-二氯乙烷在一段时间和在一个温度下产生包含对应于氯代烃反应物的氢氟烃产物的产物流，以及一种或多种氯化氢，未反应的氯代烃反应物，非氟化中间体和未反应的氟化氢，和（e）从产物流中分离氢氟烃产物。

9. 发明授权

US07205444B1 1,1,1,3,3,3-hexafluoropropane purification with photochlorination equipment 有权
标题翻译：用光氯化设备净化1,1,1,3,3,3-六氟丙烷
公开(公告)号：US07205444B1
公开(公告)日：2007-04-17
申请号：US11271580
申请日：2005-11-10
申请人： Yuon Chiu , David C. Merkel , Hsuehsung Tung
发明人： Yuon Chiu , David C. Merkel , Hsuehsung Tung
IPC分类号： C07C17/38 , C07C19/08
CPC分类号： C07C17/38 , C07C17/395 , C07C19/08
摘要： A continuous, vapor phase method for purifying a crude mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated fluorocarbon compounds, the process comprising: a) providing a photochlorinator vessel comprising 1) a UV lamp unit comprising a UV lamp located in a transparent inner well, the transparent inner well being located within a transparent outer well, the outer well being provided with material for cooling walls of the inner and outer wells; the inner well and the outer well defining separate chambers isolated from each other; and 2) a reaction vessel into which the UV lamp unit has been inserted; b) introducing into the reaction vessel a gaseous mixture of Cl2 and a distillation inseparable mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated fluorocarbon compounds; c) reacting, in the gaseous state and in the presence of UV light from the photochlorinator, the mixture with Cl2 with the distillation inseparable mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated compounds to saturate unsaturated fluorocarbons into a reacted mixture, and d) separating a purified 1,1,1,3,3,3-hexafluoropropane product containing less than 1000 ppm, most preferably less than 100 ppm unsaturated fluorocarbons.
摘要翻译：一种用于纯化1,1,1,3,3,3-六氟丙烷和一种或多种不饱和碳氟化合物的粗混合物的连续气相法，该方法包括

10. 发明申请

US20070102281A1 1,1,1,3,3,3-HEXAFLUOROPROPANE PURIFICATION WITH PHOTOCHLORINATION EQUIPMENT 有权
标题翻译： 1,1,1,3,3,3-HEXAFLORORROPANE用光电设备进行纯化
公开(公告)号：US20070102281A1
公开(公告)日：2007-05-10
申请号：US11271580
申请日：2005-11-10
申请人： Yuon Chiu , Daniel Merkel , Hsuehsung Tung
发明人： Yuon Chiu , Daniel Merkel , Hsuehsung Tung
IPC分类号： C07C17/00
CPC分类号： C07C17/38 , C07C17/395 , C07C19/08
摘要： A continuous, vapor phase method for purifying a crude mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated fluorocarbon compounds, the process comprising: a) providing a photochlorinator vessel comprising: 1) a UV lamp unit comprising a UV lamp located in a transparent inner well, the transparent inner well being located within a transparent outer well, the outer well being provided with material for cooling walls of the inner and outer wells; the inner well and the outer well defining separate chambers isolated from each other; and 2) a reaction vessel into which the UV lamp unit has been inserted; b) introducing into the reaction vessel a gaseous mixture of Cl2 and a distillation inseparable mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated fluorocarbon compounds; c) reacting, in the gaseous state and in the presence of UV light from the photochlorinator, the mixture with Cl2 with the distillation inseparable mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated compounds to saturate unsaturated fluorocarbons into a reacted mixture, and d) separating a purified 1,1,1,3,3,3-hexafluoropropane product containing less than 1000 ppm, most preferably less than 100 ppm unsaturated fluorocarbons.
摘要翻译：一种用于纯化1,1,1,3,3,3-六氟丙烷和一种或多种不饱和碳氟化合物的粗混合物的连续气相法，该方法包括：a）提供光氯化器容器，其包括：1）UV灯该单元包括位于透明内部井中的UV灯，所述透明内部井位于透明外部井内，所述外部井具有用于冷却所述内部和外部井的壁的材料; 所述内部井和所述外部井定义分离的彼此隔离的室; 和2）UV灯单元插入其中的反应容器; b）向反应容器中加入Cl 2 Cl 2与1,1,1,3,3,3-六氟丙烷与一种或多种不饱和碳氟化合物的蒸馏不可分离混合物的气态混合物; c）以气态和在来自光氯提取器的紫外光存在下，将Cl 2与Cl 2的混合物与1,1,1,3,3,3-六氟丙烷的蒸馏不可分离的混合物反应和一种或多种不饱和化合物使不饱和碳氟化合物饱和到反应混合物中，以及d）分离含有小于1000ppm，最优选小于100ppm的不饱和碳氟化合物的纯化1,1,1,3,3,3-六氟丙烷产物。

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