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    • 7. 发明授权
    • Polyethylene compositions, methods of making the same, and articles prepared therefrom
    • 聚乙烯组合物,其制备方法和由其制备的制品
    • US08344068B2
    • 2013-01-01
    • US12446652
    • 2007-10-19
    • William J. Michie, Jr.Dane ChangLonnie G. HazlittStephanie M. WhitedMichael A. KinnanAnthony C. NeubauerThoi H. Ho
    • William J. Michie, Jr.Dane ChangLonnie G. HazlittStephanie M. WhitedMichael A. KinnanAnthony C. NeubauerThoi H. Ho
    • C08F8/00C08L23/04
    • C08L23/26C08L23/0815C08L2205/02C08L2666/06
    • The invention is related to compositions suitable for the fabrication of pipes, and other articles, with excellent performance properties. The invention provides a composition, comprising a blend, wherein said blend comprises a high molecular weight ethylene-based interpolymer and a low molecular weight ethylene-based interpolymer, and the high molecular weight ethylene-based interpolymer is a heterogeneously branched linear or a homogeneously branched linear ethylene-based interpolymer, and has a density from 0.922 g/cc to 0.929 g/cc, and a high load melt index (I21) from 0.2 g/10 min to 1.0 g/10 min, and the low molecular weight ethylene-based interpolymer is heterogeneously branched linear or a homogeneously branched linear ethylene-based interpolymer, and has a density from 0.940 g/cc to 0.955 g/cc, and a melt index (I2) from 6 g/10 min to 50 g/10 min. The blend has a single peak in an ATREF profile eluting above 30° C., and has a coefficient of viscosity average molecular weight (CM?) less than −0.0032 in the log(calculated Mv) versus elution temperature, said CMv calculated in the range of elution temperatures from 70° C. to 90° C. The Mv is the viscosity average molecular weight.
    • 本发明涉及适于制造具有优异性能的管道和其它制品的组合物。 本发明提供一种包含共混物的组合物,其中所述共混物包含高分子量乙烯基互聚物和低分子量乙烯基互聚物,并且高分子量乙烯基互聚物是非均匀支化的线性或均匀分支的 线性乙烯类互聚物,密度为0.922g / cc〜0.929g / cc,高负荷熔融指数(I21)为0.2g / 10min〜1.0g / 10min,低分子量乙烯 - 基于异构支化的线型或均匀支化的线性乙烯基互聚物,其密度为0.940g / cc至0.955g / cc,熔体指数(I 2)为6g / 10min至50g / 10min 。 共混物在30℃以上洗脱的ATREF谱中具有单峰,并且在对数(计算的Mv)相对于洗脱温度具有小于-0.0032的粘均分子量(CM 3)系数,所述CMv计算为 洗脱温度范围为70℃至90℃.Mv为粘均分子量。
    • 10. 发明授权
    • Catalyst and process for producing amines
    • 催化剂和生产胺的方法
    • US5952529A
    • 1999-09-14
    • US105568
    • 1998-06-26
    • Dane ChangFred A. Sherrod
    • Dane ChangFred A. Sherrod
    • B01J23/889B01J23/89C07C209/02C07C209/16C07C211/10C07C209/26
    • C07C209/16B01J23/8896B01J23/8986Y02P20/582
    • This invention includes catalysts comprising rhenium (atomic number 75), nickel, cobalt, boron and copper and/or ruthenium impregnated on a support material and a process for preparing said catalyst, said process comprising (i) impregnating a mixture of metals comprising rhenium, cobalt, copper and/or ruthenium, boron and nickel on a support material selected from the group consisting of alpha-alumina, silica, silica-alumina, kiesolguhrs or diatomaceous earths, and silica-titanias; and (ii) activating said catalyst by heating the catalyst in the presence of hydrogen at an effective temperature preferably in the range of about 150.degree. C. to about 500.degree. C. for a sufficient period preferably of from about 30 minutes to about 6 hours. A further feature of the present invention is a method for producing amine products by the catalytic amination of alkane or arylalkane derivatives including epoxides, monols, diols, polyethers, polyols, alcoholamines, ketones, imino compounds iminoalcohols, ether alcohols, and mixtures thereof, said process comprising contacting said lower alkane or arylalkane derivatives with ammonia and/or reactant amine at an effective temperature preferably from 150.degree. C. to about 500.degree. C. and in the presence of hydrogen and the nickel-rhenium-cobalt-boron-copper and/or ruthenium catalyst as described hereinabove.
    • 本发明包括包含浸渍在载体材料上的铼(原子序号75),镍,钴,硼和铜和/或钌的催化剂和所述催化剂的制备方法,所述方法包括(i)浸渍包含铼, 钴,铜和/或钌,硼和镍在选自α-氧化铝,二氧化硅,二氧化硅 - 氧化铝,硅藻土或硅藻土的载体材料上,以及二氧化硅 - 钛合金; 和(ii)通过在优选约150℃至约500℃的有效温度下在氢气存在下加热催化剂来活化所述催化剂足够的时间,优选约30分钟至约6小时 。 本发明的另一个特征是通过烷烃或芳基烷烃衍生物的催化胺化产生胺产物的方法,包括环氧化物,单醇,二醇,聚醚,多元醇,醇胺,酮,亚氨基化合物亚氨基醇,醚醇及其混合物。 方法包括使所述低级烷烃或芳基烷烃衍生物与氨和/或反应物胺在有效温度,优选150℃至约500℃,在氢气和镍 - 铼 - 钴 - 硼 - 铜和 /或如上所述的钌催化剂。