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    • 10. 发明申请
    • Positional Diamondoid Mechanosynthesis
    • 位置金刚石机械合成
    • US20090093659A1
    • 2009-04-09
    • US12204642
    • 2008-09-04
    • Robert A. Freitas, JR.Ralph C. Merkle
    • Robert A. Freitas, JR.Ralph C. Merkle
    • C07C13/615B01J19/00
    • C07C2/00Y10S977/859Y10S977/877C07C13/615
    • The invention provides methods of using positionally controlled molecular tools in an inert environment (such as ultra high vacuum) to fabricate complex atomically precise structures, including diamond, graphite, nanotubes, fullerenes, additional sets of the selfsame molecular tools, and others. Molecular tools have atomically precise tooltips which interact directly with a workpiece to add, remove, and modify specific atoms and groups of atoms, and have handles by which they can be held and positioned; tools can be recharged after use. Specific tooltips are brought into contact with and bond to specific feedstock molecules distributed on a presentation surface, and then transfer said feedstock molecules to specific atomic sites on a workpiece using mechanosynthetic chemical reactions. Specific sites on a workpiece can be made chemically reactive, facilitating the transfer of specific groups to them. Repeated applications of molecular tools at different locations on a workpiece can build a desired atomically precise structure.
    • 本发明提供了在惰性环境(例如超高真空)中使用位置控制的分子工具来制造复杂的原子精确结构的方法,包括金刚石,石墨,纳米管,富勒烯,附加的一系列相同的分子工具等。 分子工具具有原子精确的工具提示,其与工件直接相互作用以添加,移除和修饰特定的原子和原子团,并具有可被保持和定位的手柄; 使用后可以对工具进行充电。 特定工具提示与分布在呈现表面上的特定原料分子接触并结合,然后使用机械合成化学反应将所述原料分子转移到工件上的特定原子位点。 工件上的特定位置可以化学反应,便于将特定组转移到它们。 分子工具在工件上不同位置的重复应用可以建立所需的原子精确结构。