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    • 2. 发明授权
    • Polymerizing bis-maleimides and polyimides therefrom
    • 聚合双马来酰亚胺和聚酰亚胺
    • US3929713A
    • 1975-12-30
    • US49749274
    • 1974-08-14
    • DU PONT
    • D ALELIO GAETANO F
    • C08G73/12C08G73/10
    • C08G73/12C08G73/125C08G73/126C08G73/127
    • Processes for preparing polyimides from bis-maleimides are provided. In these processes, the bis-maleimides are B-staged in solvents by passing through the solution oxygen or oxygencontaining inert gases at a temperature from about 100*C. to about the boiling point of the solvent. These solutions can be used directly as coatings and impregnants, particularly in the presence of catalytic quantities of Bronsted acid salt catalysts. From these solutions, the solid B-staged product can be isolated and then mixed with catalysts, activators, fillers and the like and used in molding processes and the like. When cured, the polymers are highly thermally stable in both nitrogen and air.
    • 提供了从双马来酰亚胺制备聚酰亚胺的方法。 在这些方法中,双马来酰亚胺在溶剂中通过在约100℃至约沸点的溶剂中通过溶液氧或含氧惰性气体而分段进行。 这些溶液可以直接用作涂料和浸渍剂,特别是在催化量的布朗斯台德酸盐催化剂的存在下。 从这些溶液中,可以分离固体B阶产物,然后与催化剂,活化剂,填料等混合并用于成型工艺等中。 当固化时,聚合物在氮气和空气中都是高度热稳定的。