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1. 发明授权

US11359032B2 Self-regulating external electron donor-containing catalyst used for alpha-olefin polymerization, and application of catalyst 有权
公开(公告)号：US11359032B2
公开(公告)日：2022-06-14
申请号：US16335910
申请日：2017-10-25
申请人： Yingkou Xiangyang Catalyst Co., Ltd. , Dalian University of Technology
发明人： Licai Wang , Zhanxian Gao , Qinghai Sun , Limei Yu , Huan Wang , Wei Li , Guotong Zheng , Qingxin Dong , Yongqiang Wang , Wenwei Wang , Zhe Yuan , Yang Li
IPC分类号： C08F4/642 , C08F10/06 , C08F4/647 , C08F110/06 , C08F2/38 , C08F4/649 , C08F4/659 , C08F210/02 , C08F210/06 , C08F2/34 , C08F210/08
摘要： Disclosed are a Z-N catalyst for α-olefin polymerization and an application thereof, specifically, an industrial production catalyst consisting of (A) a solid catalyst component, (B) a cocatalyst organoaluminum compound and (C) an external electron donor compound and used for α-olefin polymerization or copolymerization processes. The catalyst component is prepared from a transition metal such as titanium and magnesium and a composite aromatic diacid diester/1,3-diether as an internal electron donor. One or more organoaluminum compounds or a mixture thereof serve as the cocatalyst. One or more structure control agent hydrocarbyl alkoxysilicons are compounded with one or more activity regulator organic acid esters as the external electron donor capable of automatically adjusting the polymerization rate. The Z-N catalyst is used for α-olefin polymerization/copolymerization, and can automatically adjust the polymerization rate at a higher polymerization temperature so as to maintain stable operation of a reactor.

2. 发明授权

US11318564B2 Device and method for electromagnetic induction heating-assisted laser additive manufacturing of titanium matrix composite 有权
公开(公告)号：US11318564B2
公开(公告)日：2022-05-03
申请号：US16964036
申请日：2020-01-06
申请人： DALIAN UNIVERSITY OF TECHNOLOGY
发明人： Guangyi Ma , Chao Yu , Yang Li , Aidi He , Fangyong Niu , Dongjiang Wu
IPC分类号： B33Y30/00 , B23K26/34 , H05B6/00 , B22F12/41 , B23K26/70 , B33Y10/00 , B33Y50/00 , B23K26/342 , B23K26/60 , B22F12/00 , B22F12/90 , B22F10/28 , B23K26/03 , B23K26/08 , H05B6/10 , H05B6/40 , H05B6/44 , B23K103/14 , F16H1/06
摘要： The present invention provides a device and method for electromagnetic induction heating-assisted laser additive manufacturing of a titanium matrix composite and belongs to the technical field of laser additive manufacturing. The device includes a coaxial-powder feeding laser deposition system and an electromagnetic induction heating synchronous auxiliary system. The coaxial-powder feeding laser deposition system includes a substrate, a deposition sample, a laser head and an infrared thermometer. The electromagnetic induction heating synchronous auxiliary system includes an electromagnetic induction power supply auxiliary unit, a coil, a steering heightening mechanism, a driven shaft and a transverse sliding groove. The coil is connected to an output end of the electromagnetic induction power supply auxiliary unit. The coil and the laser head do synchronous movement to implement small-area real-time preheating and slow cooling on the deposition sample.

3. 发明申请

US20140061125A1 WASTEWATER PROCESSING METHOD OF HYDROLYSIS-ACIDIFICATION ENHANCED BY ADDITION OF ZERO-VALENT IRON (ZVI) 有权
标题翻译：通过添加零价铁（ZVI）增强水解加氢的废水处理方法
公开(公告)号：US20140061125A1
公开(公告)日：2014-03-06
申请号：US13981887
申请日：2011-09-21
申请人： DALIAN UNIVERSITY OF TECHNOLOGY
发明人： Xie Quan , Yaobin Zhang , Yiwen Liu , Huimin Zhao , Shuo Chen , Yang Li
IPC分类号： C02F3/28
CPC分类号： C02F3/28 , C02F1/705 , C02F3/101 , C02F3/107 , C02F3/2826 , Y02W10/15
摘要： The invention discloses a wastewater processing method of hydrolysis-acidification enhanced by addition of zero-valent iron (ZVI), including the following steps: 3˜6 ZVI-filling layers are settled in the middle of an anaerobic hydrolysis-acidification reactor. Excess sludge taken from sewage treatment plant using as seed sludge is added into this anaerobic hydrolysis-acidification reactor for startup and domestication. In the present invention, ZVI are added into this anaerobic hydrolysis-acidification reactor to accelerate organic matters degradation and produce more acetic acids, accompanied with higher COD removal obtained. ZVI can be protected from rust in this anaerobic biological environment due to the air isolation. Also, ZVI can enhance anaerobic hydrolysis of wastewater through reducing refractory pollutants involved in wastewaters. This novel method made the effluent from the hydrolysis-acidification reactor present less COD concentration and simpler substrate form, benefiting for the following anaerobic methanogenesis or aerobic treatment.
摘要翻译：本发明公开了通过添加零价铁（ZVI）提高水解酸化的废水处理方法，包括以下步骤：3〜6个ZVI填充层沉淀在厌氧水解酸化反应器的中间。将用作种子污泥的污水处理厂取得的多余污泥加入到厌氧水解酸化反应器中进行启动和驯化。在本发明中，将ZVI加入到该厌氧水解酸化反应器中以加速有机物降解并产生更多的乙酸，伴随着更高的COD去除。由于空气隔离，ZVI可以在这种厌氧生物环境中防止生锈。此外，ZVI可以通过减少废水中的难溶性污染物来增强废水的厌氧水解。这种新方法使得水解酸化反应器的流出物具有更少的COD浓度和更简单的底物形式，有利于以下厌氧甲烷生成或需氧处理。

4. 发明申请

US20190211116A1 SELF-REGULATING EXTERNAL ELECTRON DONOR-CONTAINING CATALYST USED FOR ALPHA-OLEFIN POLYMERIZATION, AND APPLICATION OF CATALYST 审中-公开
公开(公告)号：US20190211116A1
公开(公告)日：2019-07-11
申请号：US16335910
申请日：2017-10-25
申请人： Yingkou Xiangyang Catalyst Co., Ltd. , Dalian University of Technology
发明人： Licai Wang , Zhanxian Gao , Qinghai Sun , Limei Yu , Huan Wang , Wei Li , Guotong Zheng , Qingxin Dong , Yongqiang Wang , Wenwei Wang , Zhe Yuan , Yang Li
IPC分类号： C08F4/642 , C08F2/38 , C08F210/02 , C08F210/06 , C08F210/08 , C08F4/649 , C08F4/659 , C08F2/34
CPC分类号： C08F4/6421 , C08F2/34 , C08F2/38 , C08F4/642 , C08F4/649 , C08F4/6494 , C08F4/654 , C08F4/65916 , C08F10/06 , C08F10/08 , C08F210/02 , C08F210/06 , C08F210/08
摘要： Disclosed are a Z-N catalyst for α-olefin polymerization and an application thereof, specifically, an industrial production catalyst consisting of (A) a solid catalyst component, (B) a cocatalyst organoaluminum compound and (C) an external electron donor compound and used for α-olefin polymerization or copolymerization processes. The catalyst component is prepared from a transition metal such as titanium and magnesium and a composite aromatic diacid diester/1,3-diether as an internal electron donor. One or more organoaluminum compounds or a mixture thereof serve as the cocatalyst. One or more structure control agent hydrocarbyl alkoxysilicons are compounded with one or more activity regulator organic acid esters as the external electron donor capable of automatically adjusting the polymerization rate. The Z-N catalyst is used for α-olefin polymerization/copolymerization, and can automatically adjust the polymerization rate at a higher polymerization temperature so as to maintain stable operation of a reactor.

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