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1. 发明申请

US20210355077A1 BRANCHED FLUORINE-CONTAINING COMPOUND 有权
公开(公告)号：US20210355077A1
公开(公告)日：2021-11-18
申请号：US17387004
申请日：2021-07-28
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Masahiro HIGASHI , Moe HOSOKAWA , Akiyoshi YAMAUCHI , Sumi ISHIHARA , Yosuke KISHIKAWA
IPC分类号： C07C235/12 , C07C55/02 , C07C65/21 , C07C233/47
摘要： A novel branched fluorine-containing compound represented by formula (1): wherein L represents a predetermined carbon-containing linker moiety; Rf, in each occurrence, is the same or different and represents fluoroalkyl optionally having at least one ether bond; Y, in each occurrence, is the same or different and represents a predetermined divalent linking group or a bond; RY, in each occurrence, is the same or different and represents hydrogen or an organic group; L represents an (n1+n2)-valent carbon-containing linker moiety having at least one carbon atom; n1 represents a number greater than or equal to 1; n2 represents a number greater than or equal to 1; n1+n2 is a number from 3 to 6; X, in each occurrence, is the same or different and represents a divalent linking group or a bond; A, in each occurrence, is the same or different and represents -ArSO3M or the like; M, in each occurrence, is the same or different and represents hydrogen, —NR4, or a metal salt; and R represents hydrogen or a C1-4 organic group.

2. 发明申请

US20160221900A1 METHOD FOR PRODUCING 1,1-DIBROMO-1-FLUOROETHANE 有权
标题翻译：生产1,1-二溴-1-氟代乙醇的方法
公开(公告)号：US20160221900A1
公开(公告)日：2016-08-04
申请号：US14915677
申请日：2014-09-03
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Atsushi SHIRAI , Masatoshi NOSE , Yosuke KISHIKAWA , Tatsuya OHTSUKA , Sumi ISHIHARA
IPC分类号： C07C17/25 , C07C17/087
CPC分类号： C07C17/25 , C07C17/087 , C07C17/208 , C07C19/14 , C07C21/14 , C07C21/18 , C07C19/075
摘要： An object of the present invention is to provide a production method that makes it possible to produce 1,1-dibromo-1-fluoroethane easily and sustainably.The present invention provides a method for producing 1,1-dibromo-1-fluoroethane, the method comprising step A of reacting 1,1-dibromoethylene with hydrogen fluoride to obtain 1,1-dibromo-1-fluoroethane.
摘要翻译：本发明的目的是提供一种能够容易且可持续地制造1,1-二溴-1-氟乙烷的制造方法。本发明提供1,1-二溴-1-氟乙烷的制造方法，该方法包括使1,1-二溴乙烯与氟化氢反应得到1,1-二溴-1-氟乙烷的步骤A。

3. 发明申请

US20210108008A1 PRODUCTION METHOD FOR FLUOROPOLYMER, SURFACTANT FOR POLYMERIZATION, AND USE OF SURFACTANT 有权
公开(公告)号：US20210108008A1
公开(公告)日：2021-04-15
申请号：US16499047
申请日：2018-03-30
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Taketo KATO , Satoru YONEDA , Manabu FUJISAWA , Kazuya ASANO , Takahiro KITAHARA , Masahiro HIGASHI , Akiyoshi YAMAUCHI , Sumi ISHIHARA , Yosuke KISHIKAWA , Shinnosuke NITTA , Marina NAKANO , Hirotoshi YOSHIDA , Yoshinori NANBA , Kengo ITO , Chiaki OKUI , Hirokazu AOYAMA , Masamichi SUKEGAWA , Taku YAMANAKA , Yuuji TANAKA , Kenji ICHIKAWA , Yohei FUJIMOTO , Hiroyuki SATO
IPC分类号： C08F14/26 , C08K5/42 , C08K5/098
摘要： A method for producing a fluoropolymer of the invention which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a surfactant to provide a fluoropolymer. The surfactant includes at least one selected from the group consisting of a surfactant represented by R1a—CO—R2a—CO—R3a-Aa and a surfactant represented by R1b—CO—(CR2b2)n—(OR3b)p—(CR4b2)q-L-Ab.

4. 发明申请

US20200270203A9 BRANCHED FLUORINE-CONTAINING COMPOUND 审中-公开
公开(公告)号：US20200270203A9
公开(公告)日：2020-08-27
申请号：US16332962
申请日：2017-09-13
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Masahiro HIGASHI , Moe HOSOKAWA , Akiyoshi YAMAUCHI , Sumi ISHIHARA , Yosuke KISHIKAWA
IPC分类号： C07C235/12 , C07C233/47 , C07C55/02 , C07C65/21
摘要： A novel branched fluorine-containing compound represented by formula (1): (Rf—Yn1LX-A)n2 (1) wherein L represents a predetermined carbon-containing linker moiety; Rf, in each occurrence, is the same or different and represents fluoroalkyl optionally having at least one ether bond; Y, in each occurrence, is the same or different and represents a predetermined divalent linking group or a bond; RY, in each occurrence, is the same or different and represents hydrogen or an organic group; L represents an (n1+n2)-valent carbon-containing linker moiety having at least one carbon atom; n1 represents a number greater than or equal to 1; n2 represents a number greater than or equal to 1; n1+n2 is a number from 3 to 6; X, in each occurrence, is the same or different and represents a divalent linking group or a bond; A, in each occurrence, is the same or different and represents —ArSO3M or the like; M, in each occurrence, is the same or different and represents hydrogen, —NR4, or a metal salt; and R represents hydrogen or a C1-4 organic group.

5. 发明申请

US20200172476A1 SULFURIC ACID ESTER OR SALT THEREOF, AND SURFACTANT 审中-公开
公开(公告)号：US20200172476A1
公开(公告)日：2020-06-04
申请号：US16338250
申请日：2017-09-29
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Satoru YONEDA , Manabu FUJISAWA , Kazuya ASANO , Takahiro KITAHARA , Masahiro HIGASHI , Akiyoshi YAMAUCHI , Sumi ISHIHARA , Yosuke KISHIKAWA
IPC分类号： C07C305/04
摘要： A sulfuric acid ester containing a plurality of carbonyl groups or a salt thereof, and a surfactant. The sulfuric acid ester is a compound represented by the following formula: R1—C(═O)—R2—C(═O)—R3—OSO3X wherein R1, R2 and R3 are as defined herein; X is H, a metal atom, NR44, imidazolium optionally containing a substituent, pyridinium optionally containing a substituent, or phosphonium optionally containing a substituent, where R4s are each H or an organic group and are the same as or different from each other; and any two of R1, R2, and R3 optionally bind to each other to form a ring.

6. 发明申请

US20160318842A1 PRODUCTION METHOD FOR ALPHA-FLUORO ACRYLIC ACID ESTERS 有权
标题翻译：丙烯酸丙酯酸酯的生产方法
公开(公告)号：US20160318842A1
公开(公告)日：2016-11-03
申请号：US15107204
申请日：2014-12-26
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Akihiro GOTOU , Manaho MIYAZAKI , Sumi ISHIHARA , Takashi NAMIKAWA , Tatsuya OHTSUKA , Yosuke KISHIKAWA
IPC分类号： C07C67/36
CPC分类号： C07C67/36 , C07C69/653 , C07C69/65
摘要： An object of the present invention is to provide a process for producing α-fluoroacrylic acid esters at a high starting material conversion and a high yield.The present invention provides, as a means to achieve the object, a process for producing a compound represented by formula (1): wherein R2 and R2 are the same or different and each represent alkyl, fluoroalkyl, aryl optionally substituted with at least one substituent, halogen, or hydrogen; and R3 represents alkyl, fluoroalkyl, or aryl optionally substituted with at least one substituent, the process comprising step A of reacting a compound represented by formula (2): wherein the symbols are as defined above, with carbon monoxide and an alcohol represented by formula (3): R3—OH (3) wherein the symbol is as defined above, in the presence of a transition metal complex catalyst containing at least one bidentate phosphine ligand and a base to thereby obtain the compound represented by formula (1).
摘要翻译：本发明的目的是提供一种在高原料转化率和高产率下生产± - 氟代丙烯酸酯的方法。本发明提供作为实现该目标的手段，制备由式（1）表示的化合物的方法：其中R 1和R 2相同或不同，并且各自表示烷基，氟烷基，任选被至少取代的芳基一个取代基，卤素或氢; 并且R 3表示任选被至少一个取代基取代的烷基，氟代烷基或芳基，所述方法包括步骤A，使式（2）表示的化合物：其中符号如上定义，与一氧化碳和以公式（3）：€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒR3 -OH€ƒ€ƒ€ƒ€ƒ（3）其中符号如上所述，在存在含有至少一个二齿膦配体和碱的过渡金属络合物催化剂，由此得到式（1）所示的化合物。

7. 发明申请

US20160297740A1 METHOD FOR PRODUCING alpha-FLUOROACRYLIC ACID ESTER 审中-公开
标题翻译：生产α-氟代丙烯酸酯的方法
公开(公告)号：US20160297740A1
公开(公告)日：2016-10-13
申请号：US15183163
申请日：2016-06-15
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Tatsuya OHTSUKA , Akihiro GOTOU , Sumi ISHIHARA , Yoshihiro YAMAMOTO , Akinori YAMAMOTO , Yoshichika KUROKI , Yuzo KOMATSU , Yousuke KISHIKAWA
IPC分类号： C07C67/36 , B01J27/13 , B01J31/24 , B01J23/44
CPC分类号： C07C67/36 , B01J23/44 , B01J27/13 , B01J31/0237 , B01J31/24 , B01J31/2404 , B01J31/2409 , B01J2231/321 , B01J2231/49 , B01J2531/824 , C07C69/653
摘要： The object of the present invention is to provide a process for producing α-fluoroacrylic acid ester at a high starting material conversion, high selectivity, and high yield. The present invention provides a process for producing the compound represented by the formula (1) wherein R represents alkyl optionally substituted with one or more fluorine atoms, the process comprising step A of reacting a compound represented by the formula (2) wherein X represents a bromine atom or a chlorine atom with an alcohol represented by the formula (3) wherein the symbol is as defined above, and carbon monoxide in the presence of a transition metal catalyst and a base to thereby obtain the compound represented by the formula (1).

8. 发明申请

US20220259337A1 METHOD FOR PRODUCING AQUEOUS FLUOROPOLYMER DISPERSION, DRAINAGE TREATMENT METHOD, AND AQUEOUS FLUOROPOLYMER DISPERSION 有权
公开(公告)号：US20220259337A1
公开(公告)日：2022-08-18
申请号：US17606368
申请日：2020-04-27
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Satoru YONEDA , Masahiro HIGASHI , Sumi ISHIHARA , Hirotoshi YOSHIDA , Yohei FUJIMOTO
IPC分类号： C08F6/20 , C08F2/30 , C08F2/44 , C08F14/26 , C08L27/18
摘要： A method for producing a fluoropolymer aqueous dispersion, including a step A of performing ultrafiltration, microfiltration, or dialysis membrane treatment, or a combination thereof on a pretreatment aqueous dispersion containing a fluoropolymer obtained by polymerization in the presence of a polymer (I) including a polymerized unit (I) derived from a monomer represented by the following general formula (I), with the proviso that the fluoropolymer is other than the polymer (I): CX1X3═CX2R(—CZ1Z2-A0)m (I) wherein X1 and X3 are each independently F, Cl, H, or CF3; X2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A0 is an anionic group; R is a linking group; Z1 and Z2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more.

9. 发明申请

US20210002199A1 METHOD FOR PRODUCING CARBONYL COMPOUND 有权
公开(公告)号：US20210002199A1
公开(公告)日：2021-01-07
申请号：US16978997
申请日：2019-03-07
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Masahiro HIGASHI , Satoru YONEDA , Sumi ISHIHARA , Yosuke KISHIKAWA
IPC分类号： C07C45/34 , C07C51/373 , C07B41/06 , B01J23/44
摘要： A method for producing a carbonyl compound represented by formula (1): wherein R1 is hydrogen or an organic group; R2 is hydrogen or an organic group; and R3 is hydrogen or an organic group; or two or three of R1, R2, and R3 may be linked to form a ring that may have at least one substituent, the method comprising step A of oxidizing an olefin compound represented by formula (2): wherein symbols are as defined above, by an oxidizing agent in the presence of (a) a non-alcohol organic solvent, (b) water, (c) a metal catalyst, and (d) an additive represented by the formula: MXn, wherein M is an element belonging to any one of Group 1, Group 2, Group 13, Group 14, and Group 15 in the periodic table, or NR4, wherein R is hydrogen or a C1-10 organic group; X is halogen; and n is a number of 1 to 5.

10. 发明申请

US20200024229A1 SULFONIC ACID, CARBOXYLIC ACID, AND SALTS THEREOF 审中-公开
公开(公告)号：US20200024229A1
公开(公告)日：2020-01-23
申请号：US16495641
申请日：2018-03-30
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Masahiro HIGASHI , Satoru YONEDA , Akiyoshi YAMAUCHI , Sumi ISHIHARA , Yosuke KISHIKAWA , Marina NAKANO , Shinnosuke NITTA , Hirokazu AOYAMA
IPC分类号： C07C309/10 , C07C53/126 , C07C59/347
摘要： A sulfonic acid or carboxylic acid containing a carbonyl group, or a salt thereof represented by the following formula: R1—C(═O)—(CR22)—(OR3)p—(CR42)q-L-A wherein R1, R2, R3, R4, n, p, q, A and L are as defined herein.

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