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    • 1. 发明申请
    • ADHESIVE AGENT COMPOSITION FOR MULTILAYER SEMICONDUCTOR
    • 多层半导体的粘合剂组合物
    • US20160215183A1
    • 2016-07-28
    • US15025143
    • 2014-09-25
    • DAICEL CORPORATION
    • Hiroki TANAKAKatsuhiro NAKAGUCHIKiyoharu TSUTSUMIYousuke ITONaoko TSUJI
    • C09J163/00C09J7/02H01L23/00
    • C09J163/00C08G59/68C09J7/35C09J2203/326C09J2463/00H01L23/293H01L24/83H01L25/065H01L25/07H01L25/18H01L2224/83855H01L2924/0002H01L2924/00
    • Provided is an adhesive composition for multilayer semiconductors. The adhesive composition gives, when applied and dried by heating, an adhesive layer that has approximately no adhesiveness at a temperature lower than 50° C., but, when heated at such a temperature as to less cause damage to semiconductor chips, offers adhesiveness and is rapidly cured thereafter. This adhesive composition for multilayer semiconductors includes a polymerizable compound (A), at least one of a cationic-polymerization initiator (B1) and an anionic-polymerization initiator (B2), and a solvent (C). The polymerizable compound (A) contains 80% by weight or more of an epoxide having a softening point or melting point of 50° C. or higher. The cationic-polymerization initiator (B1) gives a composition having a thermal curing time of 3.5 minutes or longer at 130° C., where the composition contains 1 part by weight of the cationic-polymerization initiator (B1) and 100 parts by weight of 3,4-epoxycyclohexylmethyl (3,4-epoxy)cyclohexanecarboxylate. The anionic-polymerization initiator (B2) gives a composition having a thermal curing time of 3.5 minutes or longer at 130° C., where the composition contains 1 part by weight of the anionic-polymerization initiator (B2) and 100 parts by weight of bisphenol-A diglycidyl ether.
    • 提供了一种用于多层半导体的粘合剂组合物。 粘合剂组合物通过加热施加和干燥时,在低于50℃的温度下具有大致无粘合性的粘合剂层,但是当在较低温度下加热以致对半导体芯片造成损害时,提供粘合性和 此后迅速治愈。 该多层半导体用粘合剂组合物包含聚合性化合物(A),阳离子聚合引发剂(B1)和阴离子聚合引发剂(B2)中的至少一种和溶剂(C)。 可聚合化合物(A)含有80重量%以上的软化点或熔点为50℃以上的环氧化物。 阳离子聚合引发剂(B1)在130℃下得到热固化时间为3.5分钟以上的组合物,其中组合物含有1重量份的阳离子聚合引发剂(B1)和100重量份的 3,4-环氧环己基甲基(3,4-环氧)环己烷羧酸酯。 阴离子聚合引发剂(B2)在130℃下得到热固化时间为3.5分钟以上的组合物,其中组合物含有1重量份的阴离子聚合引发剂(B2)和100重量份的 双酚A二缩水甘油醚。