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1. 发明授权

US06846772B2 Hydrogenation catalysts 失效
标题翻译：氢化催化剂
公开(公告)号：US06846772B2
公开(公告)日：2005-01-25
申请号：US10348424
申请日：2003-01-21
申请人： Cornelis Martinus Lok , Gavin Gray , Stephen Derek Rogers , Stephen Bailey
发明人： Cornelis Martinus Lok , Gavin Gray , Stephen Derek Rogers , Stephen Bailey
IPC分类号： B01J21/08 , B01J23/755 , B01J35/10 , B01J37/03 , B01J37/08 , C11C3/12 , B01J21/18 , B01J27/24 , C07C51/36
CPC分类号： B01J37/086 , B01J21/08 , B01J23/755 , B01J35/0053 , B01J35/1019 , B01J35/1061 , B01J37/031 , C11C3/123
摘要： Production of nickel/silica hydrogenation catalyst precursors by heating a slurry of particulate silica, e.g. kieselguhr, in an aqueous nickel ammine carbonate solution for a total period of at least 200 minutes at a pH above 7.5, followed by filtration, washing, drying, and optionally calcination.
摘要翻译：通过加热颗粒二氧化硅的浆料，例如制备镍/二氧化硅氢化催化剂前体。硅藻土，在镍氨水溶液中，在高于7.5的pH下总共至少200分钟，然后过滤，洗涤，干燥和任选煅烧。

2. 发明授权

US09487711B2 Process for the conversion of fatty acids and derivatives thereof 有权
标题翻译：脂肪酸及其衍生物的转化方法
公开(公告)号：US09487711B2
公开(公告)日：2016-11-08
申请号：US12865797
申请日：2009-01-26
申请人： David Davis , Cornelis Martinus Lok , Michael John Watson , Aalbert Zwijnenburg
发明人： David Davis , Cornelis Martinus Lok , Michael John Watson , Aalbert Zwijnenburg
IPC分类号： C07C1/20 , C10G3/00 , B01J29/064 , B01J29/076 , C10G45/60 , C07C1/207 , B01J23/40 , B01J23/70 , B01J29/22 , B01J29/67 , B01J29/68 , B01J29/74
CPC分类号： C10G3/47 , B01J23/40 , B01J23/70 , B01J29/064 , B01J29/076 , B01J29/22 , B01J29/67 , B01J29/68 , B01J29/7415 , C10G3/45 , C10G3/49 , C10G3/50 , C10G45/60 , C10G2300/1011 , C10G2400/30 , Y02P30/20
摘要： A process for the production of a hydrocarbon product comprises contacting a feedstock with a catalyst composition comprising an active metal selected from platinum, palladium, nickel, cobalt, copper, ruthenium, rhodium and rhenium and an active porous material which is active for the isomerization of unsaturated hydrocarbons, wherein the feedstock comprises a fatty acid a fatty acid ester, a monoglyceride, a diglyceride or a triglyceride.
摘要翻译：一种用于生产烃产物的方法包括使原料与包含选自铂，钯，镍，钴，铜，钌，铑和铼的活性金属的催化剂组合物接触，以及活性多孔材料，其对于异构化不饱和烃，其中原料包括脂肪酸脂肪酸酯，单甘油酯，甘油二酯或甘油三酯。

3. 发明授权

US07560413B2 Copper-containing materials 失效
标题翻译：含铜材料
公开(公告)号：US07560413B2
公开(公告)日：2009-07-14
申请号：US10759137
申请日：2004-01-20
申请人： Cornelis Martinus Lok
发明人： Cornelis Martinus Lok
IPC分类号： B01J31/00
CPC分类号： B01J37/0203 , B01J20/0237 , B01J20/0277 , B01J20/06 , B01J20/08 , B01J20/223 , B01J20/28004 , B01J20/28061 , B01J20/28073 , B01J20/28083 , B01J20/3007 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J21/04 , B01J23/72 , B01J35/0053 , B01J37/03
摘要： Copper/alumina compositions for use as, e.g., catalysts are made by impregnating a porous transition alumina support with an aqueous solution of a copper ammine carbonate complex, draining off any excess of the impregnating solution, and then heating the impregnated support to a temperature above 80° C. to decompose the complex, thereby depositing a basic copper carbonate compound on the surfaces of the pores of the transition alumina support. After reduction, the composition has a high copper surface area, expressed per unit weight of copper in the composition.
摘要翻译：用作例如催化剂的铜/氧化铝组合物通过用碳酸氨铜络合物的水溶液浸渍多孔过渡氧化铝载体，排出任何过量的浸渍溶液，然后将浸渍的载体加热到上述温度 80℃以分解复合物，从而在过渡氧化铝载体的孔的表面上沉积碱式碳酸铜化合物。还原后，组合物具有高的铜表面积，表示组合物中每单位重量的铜。

4. 发明授权

US06673743B2 Nickel catalysts on transition alumina 有权
标题翻译：镍催化剂在过渡氧化铝上的应用
公开(公告)号：US06673743B2
公开(公告)日：2004-01-06
申请号：US09927060
申请日：2001-08-10
申请人： Cornelis Martinus Lok
发明人： Cornelis Martinus Lok
IPC分类号： B01J23755
CPC分类号： B01J35/0053 , B01J23/755 , B01J35/1019 , B01J35/1061 , B01J37/03
摘要： A particulate catalyst suitable for the hydrogenation of fats or oils containing 5 to 75% by weight of nickel may be made by slurrying a transition alumina powder having a surface-weighted mean diameter D[3,2] in the range 1 &mgr;m to 20 &mgr;m with an aqueous solution of a nickel ammine complex, followed by heating to deposit an insoluble nickel compound and then reducing the latter. Catalysts containing up to about 55% by weight of nickel have a nickel surface area above 130 m2/g of nickel. Catalysts having greater nickel contents made using alumina having an average pore diameter above 12 &mgr;m may have a lower nickel surface area but are surprisingly active and selective.
摘要翻译：适用于含有5至75重量％镍的脂肪或油的氢化的颗粒催化剂可以通过将表面加权平均直径D [3,2]的过渡氧化铝粉末在1μm至20μm范围内与镍氨络合物的水溶液，然后加热沉积不溶性镍化合物，然后还原后者。含有高达约55重量％的镍的催化剂的镍表面积高于130m 2 / g的镍。具有使用平均孔径高于12μm的氧化铝制成的具有更大镍含量的催化剂可具有较低的镍表面积，但令人惊奇的是活性和选择性。

5. 发明授权

US06316643B1 Process for the preparation of derivatives of fatty acids 失效
标题翻译：脂肪酸衍生物的制备方法
公开(公告)号：US06316643B1
公开(公告)日：2001-11-13
申请号：US09242428
申请日：1999-10-12
申请人： Glyn Roberts , Cornelis Martinus Lok , Christopher John Adams , Kenneth Richard Seddon , Martyn John Earle , Jennifer Therese Hamill
发明人： Glyn Roberts , Cornelis Martinus Lok , Christopher John Adams , Kenneth Richard Seddon , Martyn John Earle , Jennifer Therese Hamill
IPC分类号： C09F700
CPC分类号： C07C51/353 , C07C67/347 , C07C53/128 , C07C69/34
摘要： The preparation of a mixture comprising branched fatty acids and oligomerised fatty acids comprises contacting a source of unsaturated fatty acids or their derivatives with an ionic liquid.
摘要翻译：包含支链脂肪酸和低聚脂肪酸的混合物的制备包括使不饱和脂肪酸源或其衍生物与离子液体接触。

6. 发明授权

US06204400B1 Process for the preparation of derivatives of fatty acids 有权
公开(公告)号：US06204400B1
公开(公告)日：2001-03-20
申请号：US09242428
申请日：1999-10-12
申请人： Glyn Roberts , Cornelis Martinus Lok , Christopher John Adams , Kenneth Richard Seddon , Martyn John Earle , Jennifer Therese Hamill
发明人： Glyn Roberts , Cornelis Martinus Lok , Christopher John Adams , Kenneth Richard Seddon , Martyn John Earle , Jennifer Therese Hamill
IPC分类号： C09F700
摘要： The preparation of a mixture comprising branched fatty acids and oligomerised fatty acids comprises contacting a source of unsaturated fatty acids or their derivatives with an ionic liquid.

7. 发明授权

US5874381A Cobalt on alumina catalysts 失效
标题翻译：氧化铝催化剂上的钴
公开(公告)号：US5874381A
公开(公告)日：1999-02-23
申请号：US776570
申请日：1997-04-08
申请人： Raimond Laurentius Bonne , Cornelis Martinus Lok
发明人： Raimond Laurentius Bonne , Cornelis Martinus Lok
IPC分类号： B01J21/04 , B01J23/75 , B01J35/10 , B01J37/03 , C07C5/10 , B01J23/38 , B01J23/40
CPC分类号： B01J35/10 , B01J23/75 , B01J35/0053 , B01J35/1009 , B01J35/1014 , B01J37/031 , B01J21/04
摘要： A cobalt on transition alumina catalyst, containing between 3 and 40% by weight of cobalt has a cobalt surface area above 30 m.sup.2 /.sub.g of cobalt, preferably above 50 m.sup.2 /.sub.g of cobalt, most preferably above 80 m.sup.2 /.sub.g of cobalt.
摘要翻译： PCT No.PCT / EP95 / 02836 Sec。 371日期1997年4月8日 102（e）日期1997年4月8日PCT提交1995年7月17日PCT公布。公开号WO96 / 04072 日期：1996年2月15日，钴含量在3〜40重量％之间的钴的过渡型氧化铝催化剂具有钴表面积高于30m2 / g的钴，优选为50m2 / g以上的钴，最优选为80m2 / g钴。

8. 发明授权

US08536236B2 Shaped eggshell catalyst containing cobalt, use and preparation thereof 有权
标题翻译：含钴的形状蛋壳催化剂，用途及其制备
公开(公告)号：US08536236B2
公开(公告)日：2013-09-17
申请号：US11791769
申请日：2005-11-21
申请人： Cornelis Martinus Lok , Sharon Bale
发明人： Cornelis Martinus Lok , Sharon Bale
IPC分类号： B01J35/00 , B01J21/04 , B01J35/02 , B01J37/02 , B01J23/75 , B01J21/08 , C07C45/00 , C07C5/00 , C07C5/03
CPC分类号： B01J35/008 , B01J21/04 , B01J23/75 , B01J35/0006 , B01J35/023 , B01J35/026 , B01J37/0203 , B01J37/16 , C10G2/332 , C10G45/00 , C10G45/48
摘要： A method for the preparation of an eggshell catalyst is described comprising the steps of i) immersing shaped units of an oxidic support having a smallest unit dimension ≧0.5 mm in a solution of cobalt ammine carbonate, ii) heating the solution to a temperature between 60 and 120° C. to precipitate cobalt compounds onto the surface of the shaped units, iii) separating the resulting supported cobalt compounds from the remaining solution, and iv) drying the supported cobalt compounds. The cobalt compounds may be reduced to provide catalysts suitable for the hydrogenation of unsaturated compounds or the Fischer-Tropsch synthesis of hydrocarbons.
摘要翻译：描述了制备蛋壳催化剂的方法，其包括以下步骤：i）将具有最小单位尺寸≥0.5mm的最小单位尺寸≥0.5mm的氧化载体的成形单元浸入碳酸氨钙溶液中，ii）将溶液加热至 60℃和120℃，以将钴化合物沉淀到成形单元的表面上，iii）将所得负载的钴化合物与剩余的溶液分离，以及iv）干燥负载的钴化合物。可以将钴化合物还原以提供适用于不饱和化合物的氢化或烃的费 - 托合成的催化剂。

9. 发明申请

US20110105817A1 PROCESS FOR THE CONVERSION OF FATTY ACIDS AND DERIVATIVES THEREOF 有权
标题翻译：转化脂肪酸及其衍生物的方法
公开(公告)号：US20110105817A1
公开(公告)日：2011-05-05
申请号：US12865797
申请日：2009-01-26
申请人： Aalbert Zwijnenburg , David Davis , Cornelis Martinus Lok , Michael John Watson
发明人： Aalbert Zwijnenburg , David Davis , Cornelis Martinus Lok , Michael John Watson
IPC分类号： C07C1/213 , C07C1/207
CPC分类号： C10G3/47 , B01J23/40 , B01J23/70 , B01J29/064 , B01J29/076 , B01J29/22 , B01J29/67 , B01J29/68 , B01J29/7415 , C10G3/45 , C10G3/49 , C10G3/50 , C10G45/60 , C10G2300/1011 , C10G2400/30 , Y02P30/20
摘要： A process for the production of a hydrocarbon product comprises contacting a feedstock with a catalyst composition comprising an active metal selected from platinum, palladium, nickel, cobalt, copper, ruthenium, rhodium and rhenium and an active porous material which is active for the isomerisation of unsaturated hydrocarbons, wherein the feedstock comprises a fatty acid a fatty acid ester, a monoglyceride, a diglyceride or a triglyceride.
摘要翻译：用于生产烃产物的方法包括使原料与包含选自铂，钯，镍，钴，铜，钌，铑和铼的活性金属的催化剂组合物接触，以及活性多孔材料，其对于异构化不饱和烃，其中原料包括脂肪酸脂肪酸酯，单甘油酯，甘油二酯或甘油三酯。

10. 发明授权

US07851404B2 Process for preparing cobalt catalysts on titania support 有权
标题翻译：在二氧化钛载体上制备钴催化剂的方法
公开(公告)号：US07851404B2
公开(公告)日：2010-12-14
申请号：US10528527
申请日：2003-09-25
申请人： Cornelis Martinus Lok
发明人： Cornelis Martinus Lok
IPC分类号： B01J23/00
CPC分类号： B01J21/063 , B01J23/75 , B01J37/031 , C07C209/32 , C07C209/48 , C10G2/332 , C10G2300/202 , C10G2300/703
摘要： Catalysts comprising cobalt on a titania support are produced by mixing together particles of a solid titania support and an aqueous solution of cobalt ammine carbonate, and heating to an elevated temperature sufficient to effect decomposition of the cobalt ammine carbonate and precipitation of a cobalt species onto said support. The catalysts are useful in hydrogenation and Fischer-Tropsch reactions.
摘要翻译：包含二氧化钛载体上的钴的催化剂通过将固体二氧化钛载体的颗粒和碳酸氨铜的水溶液混合在一起并加热到足以实现碳酸钴铵分解的高温并将钴物质沉淀到所述支持。催化剂可用于氢化和费 - 托反应。

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