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1. 发明申请

US20210206948A1 SILANE, RUBBER MIXTURE CONTAINING THE SILANE, AND VEHICLE TIRE HAVING THE RUBBER MIXTURE IN AT LEAST ONE COMPONENT 有权
公开(公告)号：US20210206948A1
公开(公告)日：2021-07-08
申请号：US16978841
申请日：2019-02-19
申请人： Continental Reifen Deutschland GmbH
发明人： David-Raphael Dauer , Andreas Jacob , Julian Strohmeier
IPC分类号： C08K9/06 , C08K3/36 , C08K5/548 , C07F7/18 , B60C1/00
摘要： The invention relates to a silane, to a rubber mixture containing the silane and to a vehicle tire comprising the rubber mixture in at least one component.
The silane according to the invention has the following formula I) (R1)oSi—R2—X-A-Y—[R7—Y—]m—R7—S-G, I) wherein according to the invention it has a spacer group between the silyl group and the S-G moiety, wherein the spacer group has an aromatic group A and at least one further aromatic group and/or an alkylene group and also the linking units X and Y, wherein the group X is selected from the groups —HNC(═O)—, —C(═O)NH—, —C(═O)O—, —OC(═O)—, —OC(═O)NH—, —HNC(═O)O—, —R3NC(═O)NR3—, —R3NC(═NR3)NR3—, —R3NC(═S)NR3—, wherein at least one R3 within the group X is a hydrogen atom, and wherein the groups Y are selected from the groups —HNC(═O)—, —C(═O)NH—, —C(═O)O—, —OC(═O)—, —OC(═O)NH—, —HNC(═O)O—, —R4NC(═O)NR4—, —R4NC(═NR4)NR4—, —R4NC(═S)NR4—, wherein at least one R4 within each group Y is a hydrogen atom, and wherein the radicals R7 are selected from aromatic groups A and alkylene radicals having 1 to 20 carbon atoms, which may have cyclic, branched and/or aliphatically unsaturated groups; and wherein G is a hydrogen atom or a —C(═O)—R8 group or a —SiR83 group, wherein R8 is selected from linear, branched and cyclic C1-C20-alkyl groups, C6-C20-aryl groups, C2-C20-alkenyl groups and C7-C20-aralkyl groups, and wherein m can take the values 0 to 4.
The rubber mixture according to the invention contains at least one silane according to the invention.

2. 发明申请

US20200377700A1 SULFUR-CROSSLINKABLE RUBBER MIXTURE, VULCANIZATE OF THE RUBBER MIXTURE, AND VEHICLE TIRE 审中-公开
公开(公告)号：US20200377700A1
公开(公告)日：2020-12-03
申请号：US16765034
申请日：2018-09-04
申请人： Continental Reifen Deutschland GmbH
发明人： Julia Schoeffel , Norbert Mueller , Carla Recker , Christine Weber , Gesa Tarantola , David-Raphael Dauer , Fabian Schax , Nils Hojdis
IPC分类号： C08L9/06
摘要： The invention relates to a sulfur-crosslinkable rubber mixture, to a vulcanizate thereof and to a vehicle tire. The sulfur-crosslinkable rubber mixture contains at least the following constituents: at least one diene rubber; and 10 to 300 phr of at least one silica; and 1 to 30 phf of at least one silane A having general empirical formula A-I) (R1)oSi—R2—S—H; and A-I) 0.5 to 30 phf of at least one silane B having general empirical formula B-I) (R1)oSi—R3—(S—R4)u—(S—R5)v—Si(R1)o, B-I) wherein u is 0, 1, 2 or 3 and v is 0 or 1.

3. 发明公开

US20230312874A1 COMPOUND, RUBBER MIXTURE CONTAINING THE COMPOUND, VEHICLE TIRE WHICH HAS AT LEAST ONE COMPONENT COMPRISING THE RUBBER MIXTURE, METHOD FOR PRODUCING THE COMPOUND, AND USE OF THE COMPOUND AS AN AGING PROTECTION AGENT AND/OR ANTIOXIDANT AGENT AND/OR ANTIOZONANT AND/OR DYE 审中-公开
公开(公告)号：US20230312874A1
公开(公告)日：2023-10-05
申请号：US18247163
申请日：2021-09-29
申请人： Continental Reifen Deutschland GmbH
发明人： Andreas Jacob , David-Raphael Dauer , Julian Strohmeier , Anna-Lena Dreier , Carla Recker , Jörg-August Becker , Florian Matz , Rebecca Graf , Jan Flormann
IPC分类号： C08K5/18 , C08L21/00 , C07C213/06
CPC分类号： C08K5/18 , C08L21/00 , C07C213/06
摘要： The invention relates to a compound, to a rubber mixture containing the compound, to a vehicle tire comprising the rubber mixture in at least one component, to a process for producing the compound and to the use of the compound as an aging stabilizer and/or antioxidant and/or dye.
The compound according to the invention has the formula I).

4. 发明授权

US11384103B2 Silane, rubber mixture containing the silane, and vehicle tire having the rubber mixture in at least one component 有权
公开(公告)号：US11384103B2
公开(公告)日：2022-07-12
申请号：US16980039
申请日：2019-02-05
申请人： Continental Reifen Deutschland GmbH
发明人： David-Raphael Dauer , Andreas Jacob , Julian Strohmeier
IPC分类号： C07F7/08 , C07F7/18 , B60C1/00 , C08K5/548 , C08K9/06
摘要： The invention relates to a silane, to a rubber mixture comprising the silane and to a vehicle tire comprising the rubber mixture in at least one component.
The inventive silane has the following formula (I): (R1)oSi—R2—X-A-Y—[R7—Y—]m—R7—Sk—R7—[—Y—R7]m—Y-A-X—R2—Si(R1)o, wherein according to the invention it has spacer groups between the respective silyl groups and the Sk moiety, which have an aromatic group A and at least one alkylene group R7 and also the linking units X and Y, wherein the groups X within a molecule may be identical or different from each other and are selected from the groups —HNC(═O)—, —C(═O)NH—, —C(═O)O—, —OC(═O)—, —OC(═O)NH—, —HNC(═O)O—, —R3NC(═O)NR3—, —R3NC(═NR3)NR3—, —R3NC(═S)NR3—, wherein at least one R3 within each group X is a hydrogen atom; and wherein the groups Y within a molecule may be identical or different from each other and are selected from the groups —HNC(═O)—, —C(═O)NH—, —C(═O)O—, —OC(═O)—, —OC(═O)NH—, —HNC(═O)O—, —R4NC(═O)NR4—, —R4NC(═NR4)NR4—, —R4NC(═S)NR4—, wherein at least one R4 within each group Y is a hydrogen atom, and wherein the radicals R7 within a molecule may be identical or different and comprise alkylene radicals having 1 to 20 carbon atoms, which may have cyclic, branched and/or aliphatically unsaturated groups. The inventive rubber mixture comprises at least one inventive silane.

5. 发明公开

US20240294730A1 SULFUR-CROSSLINKABLE RUBBER MIXTURE, VULCANIZATE OF THE RUBBER MIXTURE, AND VEHICLE TIRE 审中-公开
公开(公告)号：US20240294730A1
公开(公告)日：2024-09-05
申请号：US18564972
申请日：2022-05-03
申请人： Continental Reifen Deutschland GmbH
发明人： David-Raphael Dauer , Julien Davin , Nils Hojdis , Norbert Müller , Carla Recker , Fabian Schax , Julia Schöffel , Gesa Tarantola , Christine Weber
IPC分类号： C08K3/06 , B60C1/00 , C08K3/36 , C08K5/548 , C08L9/06
CPC分类号： C08K3/06 , B60C1/0016 , C08K3/36 , C08K5/548 , C08L9/06 , C08K2201/014
摘要： A sulfur-crosslinkable rubber mixture, to the vulcanizate thereof, and to a vehicle tire. The sulfur-crosslinkable rubber mixture comprises at least the following constituents: —at least one solution-polymerized styrene-butadiene rubber (SSBR) having a glass transition temperature Tg according to DSC of −35° C. to −85° C.; and —at least one silica; and —1 to 30 phf of at least one silane A having the general empirical formula A-I) (R1)oSi—R2—(S—R3)q—S—X; and —0.5 to 30 phf of at least one silane B having the general empirical formula B-I) (R1)oSi—R2—(S—R3)u—S—R2—Si(R1)o, where q=1 or 2 or 3; and u=1 or 2 or 3; and X is a hydrogen atom or a —C(═O)—R8 group where R8 is selected from hydrogen, C1-C20 alkyl groups, C6-C20 aryl groups, C2-C20 alkenyl groups and C7-C20 aralkyl groups.

6. 发明授权

US10858499B1 Silane, rubber mixture containing the silane and vehicle tyre having the rubber mixture in at least one component 有权
公开(公告)号：US10858499B1
公开(公告)日：2020-12-08
申请号：US16622966
申请日：2018-05-14
申请人： Continental Reifen Deutschland GmbH
发明人： Andreas Jacob , David-Raphael Dauer , Julian Strohmeier , Julia Schoeffel , Carla Recker , Kirsten Schwekendiek , Norbert Mueller
IPC分类号： C07F7/04 , C08K5/548 , B60C1/00 , C08L21/00 , C07F7/08
摘要： The invention relates to a silane, to a rubber mixture comprising the silane and to a vehicle tire comprising the rubber mixture in at least one component.The inventive silane has the following formula I) (R1)oSi—R2—X-A-Y-[A-Y-]m-A-Sk-A-[-Y-A]mY-A-X—R2—Si(R1)o, wherein, according to the invention, the silane has spacer groups between the respective silyl groups and the Sk moiety which have at least two aromatic groups A and the linking units X and Y, wherein the groups X within a molecule may be identical or different from each other and are selected from the groups —HNC(═O)—, —C(═O)NH—, —C(═O)O—, —OC(═O)—, —OC(═O)NH—, —HNC(═O)O—, —R3NC(═O)NR3—, —R3NC(═NR3)NR3—, —R3NC(═S)NR3—, wherein at least one R3 within each group X is a hydrogen atom; and wherein the groups Y within a molecule may be identical or different from each other and are selected from the groups —HNC(═O)—, —C(═O)NH—, —C(═O)O—, —OC(═O)—, —OC(═O)NH—, —HNC(═O)O—, —R4NC(═O)NR4—, —R4NC(═NR4)NR4—, —R4NC(═S)NR4—, wherein at least one R4 within each group Y is a hydrogen atom. The inventive rubber mixture comprises at least one inventive silane.

7. 发明申请

US20200377702A1 SULFUR-CROSSLINKABLE RUBBER MIXTURE, VULCANIZATE OF THE RUBBER MIXTURE, AND VEHICLE TIRE 审中-公开
公开(公告)号：US20200377702A1
公开(公告)日：2020-12-03
申请号：US16765051
申请日：2018-08-09
申请人： Continental Reifen Deutschland GmbH
发明人： Julia Schoeffel , Norbert Mueller , Carla Recker , Christine Weber , Gesa Tarantola , David-Raphael Dauer , Fabian Schax , Nils Hojdis
IPC分类号： C08L9/06 , B60C1/00 , B60C11/00
摘要： The invention relates to a sulfur-crosslinkable rubber mixture, to a vulcanizate thereof and to a vehicle tire. The sulfur-crosslinkable rubber mixture contains at least the following constituents: at least one diene rubber; and 10 to 300 phr of at least one silica; and 1 to 30 phf of at least one silane A having general empirical formula A-I) and/or A-XI) A-I) (R1)oSi—R2—(S—R3)q—Sx—(R3—S)q—R2—Si(R1)o; A-XI) (R1)oSi—R2—(S—R3)s—S—X; and 0.5 to 30 phf of at least one silane B having general empirical formula B-I) B-I) (R1)oSi—R4—Si(R1)o wherein x is an integer from 2 to 10, q is 0, 1, 2 or 3 and s is 1, 2 or 3 and X is a hydrogen atom or a C(═O)—R8 group wherein R8 is selected from hydrogen C1-C20-alkyl groups, C6-C20-aryl groups, C2-C20-alkenyl groups and C7-C20-aralkyl groups.

8. 发明公开

US20240368086A1 COMPOUND, RUBBER BLEND CONTAINING THE COMPOUND, VEHICLE TIRE COMPRISING THE RUBBER BLEND IN AT LEAST ONE COMPONENT, PROCESS FOR PRODUCING THE COMPOUND, AND USE OF THE COMPOUND AS AN AGEING PROTECTANT AND/OR ANTIOZONANT AND/OR DYE 审中-公开
公开(公告)号：US20240368086A1
公开(公告)日：2024-11-07
申请号：US18291150
申请日：2022-06-14
申请人： Continental Reifen Deutschland GmbH
发明人： Andreas Jacob , David-Raphael Dauer , Julian Strohmeier , Elisabeth Wittenberg
IPC分类号： C07D219/08 , B60C1/00 , C08K5/3437
CPC分类号： C07D219/08 , B60C1/0016 , B60C1/0025 , C08K5/3437
摘要： A compound, a rubber mixture containing the compound, a vehicle tire comprising the rubber mixture in at least one component, a process for producing the compound and the use of the compound as an aging stabilizer and/or antiozonant and/or dye, in which, the compound has the formula (I), wherein R1 is selected from the group consisting of benzyl radicals, 1-phenylalkyl radicals having altogether 7 to 18 carbon atoms and linear, branched and cyclic aliphatic C3- to C12-radicals.

9. 发明公开

US20240336564A1 COMPOUND, RUBBER MIXTURE CONTAINING THE COMPOUND, VEHICLE TIRE WHICH HAS AT LEAST ONE COMPONENT COMPRISING THE RUBBER MIXTURE, PROCESS FOR PREPARING THE COMPOUND, AND USE OF THE COMPOUND AS AN AGING PROTECTION AGENT AND/OR ANTIOZONANT AND/OR COLORANT 审中-公开
公开(公告)号：US20240336564A1
公开(公告)日：2024-10-10
申请号：US18291152
申请日：2022-06-14
申请人： CONTINENTAL REIFEN DEUTSCHLAND GMBH
发明人： Andreas Jacob , David-Raphael Dauer , Julian Strohmeier
IPC分类号： C07D209/14 , B60C1/00 , C08K5/3417 , C09B57/00
CPC分类号： C07D209/14 , B60C1/0016 , B60C1/0025 , C08K5/3417 , C09B57/00
摘要： A compound, a rubber mixture containing the compound, a vehicle tire comprising the rubber mixture in at least one component, a process for producing the compound and the use of the compound as an aging stabilizer and/or antiozonant and/or dye, in which, the compound has the formula (I), wherein A is an aromatic radical optionally bearing additional substituents, and wherein R1 is selected from the group consisting of xi) aromatic radicals, wherein the aromatic radicals optionally bear substituents selected from the group consisting of halogen radicals, cyano radicals, ester radicals, ketone radicals, ether radicals and thioether radicals, and xii) linear, branched and cyclic aliphatic C1- to C12-radicals, and xiii) combinations of aromatic and aliphatic C1- to C12-radicals.

10. 发明授权

US11932753B2 Silane, rubber mixture containing the silane, and vehicle tire having the rubber mixture in at least one component 有权
公开(公告)号：US11932753B2
公开(公告)日：2024-03-19
申请号：US16978841
申请日：2019-02-19
申请人： Continental Reifen Deutschland GmbH
发明人： David-Raphael Dauer , Andreas Jacob , Julian Strohmeier
IPC分类号： C08K9/06 , B60C1/00 , C07F7/18 , C08K3/36 , C08K5/548
CPC分类号： C08K9/06 , B60C1/0016 , C07F7/1804 , C08K3/36 , C08K5/548 , B60C2001/0033
摘要： The invention relates to a silane, to a rubber mixture containing the silane and to a vehicle tire comprising the rubber mixture in at least one component.
The silane according to the invention has the following formula I)

(R1)oSi—R2—X-A-Y—[R7—Y—]m—R7—S-G, I)

wherein according to the invention it has a spacer group between the silyl group and the S-G moiety, wherein the spacer group has an aromatic group A and at least one further aromatic group and/or an alkylene group and also the linking units X and Y, wherein the group X is selected from the groups —HNC(═O)—, —C(═O)NH—, —C(═O)O—, —OC(═O)—, —OC(═O)NH—, —HNC(═O)O—, —R3NC(═O)NR3—, —R3NC(═NR3)NR3—, —R3NC(═S)NR3—, wherein at least one R3 within the group X is a hydrogen atom, and wherein the groups Y are selected from the groups —HNC(═O)—, —C(═O)NH—, —C(═O)O—, —OC(═O)—, —OC(═O)NH—, —HNC(═O)O—, —R4NC(═O)NR4—, —R4NC(═NR4)NR4—, —R4NC(═S)NR4—, wherein at least one R4 within each group Y is a hydrogen atom, and wherein the radicals R7 are selected from aromatic groups A and alkylene radicals having 1 to 20 carbon atoms, which may have cyclic, branched and/or aliphatically unsaturated groups; and wherein G is a hydrogen atom or a —C(═O)—R8 group or a —SiR83 group, wherein R8 is selected from linear, branched and cyclic C1-C20-alkyl groups, C6-C20-aryl groups, C2-C20-alkenyl groups and C7-C20-aralkyl groups, and wherein m can take the values 0 to 4.

The rubber mixture according to the invention contains at least one silane according to the invention.

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