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1. 发明申请

US20140162912A1 SWELLABLE POLYMER WITH CATIONIC SITES 有权
标题翻译：可溶性聚合物与阳离子网站
公开(公告)号：US20140162912A1
公开(公告)日：2014-06-12
申请号：US14182901
申请日：2014-02-18
申请人： University of Kansas , ConocoPhillips Company
发明人： Ahmad MORADI-ARAGHI , James H. HEDGES , David R. ZORNES , Riley B. NEEDHAM , Huili GUAN , Jenn-Tai LIANG , Cory BERKLAND , James P. JOHNSON , Min CHENG , Faye Lynn SCULLY
IPC分类号： C09K8/88
CPC分类号： C09K8/887 , C09K8/588
摘要： The invention is directed to long lasting crosslinked water-soluble swellable polymers, methods for making same, and their uses. More particularly, the invention relates to a composition comprising expandable polymeric particles having cationic sites as well as labile crosslinkers and stable crosslinkers, said particle mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a target zones in the reservoirs and when the heat and/or a suitable pH in the reservoir cause degradation of the labile crosslinker and when the particle expands, the cationic sites in the polymer adsorb to negative sites of the rock in the formation, thus diverting water to lower permeability regions and improving oil recovery. However, many other uses are possible.
摘要翻译：本发明涉及长效交联水溶性可溶胀聚合物，其制备方法及其用途。更具体地说，本发明涉及包含具有阳离子位点的可发性聚合物颗粒以及不稳定的交联剂和稳定的交联剂的组合物，所述颗粒与流体混合。特别重要的用途是作为石油生产中的注入流体，其中将可发性聚合物颗粒注入到储存器中的目标区域中，并且当储存器中的热量和/或合适的pH引起不稳定交联剂的降解时，膨胀，聚合物中的阳离子部位吸附在地层中的岩石的负位点，从而将水转移到较低的渗透率区域并提高油的回收率。然而，许多其他用途是可能的。

2. 发明申请

US20180002592A1 NANOGELS FOR DELAYED GELATION 审中-公开
公开(公告)号：US20180002592A1
公开(公告)日：2018-01-04
申请号：US15708034
申请日：2017-09-18
申请人： ConocoPhillips Company , University of Kansas
发明人： Huili GUAN , Cory BERKLAND , Ahmad MORADI-ARAGHI , Jenn-Tai LIANG , Terry M. CHRISTIAN , Riley B. NEEDHAM , Min CHENG , Faye Lynn SCULLY , James H. HEDGES
IPC分类号： C09K8/588 , C08L5/00 , C08L1/28
摘要： The instant application relates to nanogels or compositions that hold multivalent metal ions until some level of nanogel degradation has occurred, then slowly release the multivalent metal ions for gelation with carboxylate containing polymers. Compositions comprising such nanogels, together with polymers that can be crosslinked with multivalent metal ions, allow the deployment of such mixtures in various applications, and greatly increased gelation times.

3. 发明申请

US20140202693A1 NANOGELS FOR DELAYED GELATION 有权
标题翻译：延迟凝胶的纳米胶
公开(公告)号：US20140202693A1
公开(公告)日：2014-07-24
申请号：US14143169
申请日：2013-12-30
申请人： The University of Kansas , CONOCOPHILLIPS COMPANY
发明人： Huili GUAN , Cory BERKLAND , Ahmad MORADI-ARAGHI , Jenn-Tai LIANG , Terry M. CHRISTIAN , Riley B. Needham , Min CHENG , Faye Lynn SCULLY , James H. HEDGES
IPC分类号： C09K8/588
CPC分类号： C09K8/588 , C08L1/286 , C08L5/00
摘要： The instant application relates to nanogels or compositions that hold multivalent metal ions until some level of nanogel degradation has occurred, then slowly release the multivalent metal ions for gelation with carboxylate containing polymers. Compositions comprising such nanogels, together with polymers that can be crosslinked with multivalent metal ions, allow the deployment of such mixtures in various applications, and greatly increased gelation times.
摘要翻译：本申请涉及保持多价金属离子直到发生一定程度的纳米凝胶降解的纳米凝胶或组合物，然后用含羧酸酯的聚合物缓慢释放多价金属离子用于凝胶化。包含这些纳米凝胶的组合物以及可与多价金属离子交联的聚合物允许在各种应用中部署这些混合物，并大大增加凝胶化时间。

4. 发明申请

US20140131043A1 SWELLABLE POLYMER WITH ANIONIC SITES 审中-公开
标题翻译：易溶聚合物与阴离子网站
公开(公告)号：US20140131043A1
公开(公告)日：2014-05-15
申请号：US14157902
申请日：2014-01-17
申请人： University of Kansas , ConocoPhillips Company
发明人： Ahmad MORADI-ARAGHI , James H. HEDGES , David R. ZORNES , Riley B. NEEDHAM , Huili GUAN , Jenn-Tai LIANG , Cory BERKLAND , James P. JOHNSON , Min CHENG , Faye Lynn SCULLY
IPC分类号： C09K8/588 , E21B43/16
CPC分类号： C09K8/588 , C09K8/12 , E21B43/16
摘要： The invention is directed to stable crosslinked water-soluble swellable polymers and methods for making same. More particularly, the invention relates to a composition comprising expandable polymeric particles having anionic sites and labile crosslinkers and stable crosslinkers, said particle mixed with a fluid and a cationic crosslinker that is capable of further crosslinking the particle on degradation of the labile crosslinker and exposure of the anionic sites so as to form a gel. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into target zone and when the heat and/or suitable pH of the target zone cause degradation of the labile crosslinker and the particle expands, the cationic crosslinker crosslinks the polymer to form a gel, thus diverting water to lower permeability regions and improving oil recovery.
摘要翻译：本发明涉及稳定的交联水溶性可溶胀聚合物及其制备方法。更具体地说，本发明涉及包含具有阴离子位点和不稳定交联剂和稳定交联剂的可发性聚合物颗粒的组合物，所述颗粒与流体和阳离子交联剂混合，所述流体和阳离子交联剂能够在不稳定交联剂降解时进一步交联颗粒，阴离子位点以形成凝胶。特别重要的用途是作为石油生产中的注入流体，其中将可发性聚合物颗粒注入目标区域，并且当目标区域的热和/或合适的pH导致不稳定交联剂和颗粒膨胀时，阳离子交联剂交联聚合物以形成凝胶，从而将水转移到较低渗透性区域并改善油回收率。

5. 发明申请

US20220325170A1 NANOGELS FOR DELAYED GELATION 有权
公开(公告)号：US20220325170A1
公开(公告)日：2022-10-13
申请号：US17847161
申请日：2022-06-22
申请人： ConocoPhillips Company
发明人： Huili GUAN , Cory BERKLAND , Ahmad MORADI-ARAGHI , Jenn-Tai LIANG , Terry M. CHRISTIAN , Riley B. NEEDHAM , Min CHENG , Faye Lynn SCULLY , James H. HEDGES
IPC分类号： C09K8/588 , C08L1/28 , C08L5/00
摘要： The instant application relates to nanogels or compositions that hold multivalent metal ions until some level of nanogel degradation has occurred, then slowly release the multivalent metal ions for gelation with carboxylate containing polymers. Compositions comprising such nanogels, together with polymers that can be crosslinked with multivalent metal ions, allow the deployment of such mixtures in various applications, and greatly increased gelation times.

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