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    • 4. 发明申请
    • Preparation of graft copolymers by sequential polymerization using peroxide-containing polyolefins
    • 通过使用含过氧化物的聚烯烃进行顺序聚合制备接枝共聚物
    • US20060160954A1
    • 2006-07-20
    • US11302395
    • 2005-12-13
    • Vu DangCheng Song
    • Vu DangCheng Song
    • C08F297/02
    • C08F285/00
    • A process for making a graft copolymer of an olefin polymer material in at least two polymerization stages comprising: a) treating a reactive, peroxide-containing olefin polymer material (A) at a temperature from about 80° C. to a temperature below the softening point of the polymer material with about 5 to about 120 parts per hundred parts of the polymer material (A) by weight (pph) of at least one grafting monomer which is polymerizable by free radicals; b) treating the stage a) graft copolymer at a temperature from about 80° C. to a temperature below the softening point of the stage a) graft copolymer, which is the same as or different from the temperature used in stage a), with about 5 to about 120 pph of at least one grafting monomer which is different from the monomer used in stage a) and polymerizable by free radicals.
    • 一种在至少两个聚合阶段中制备烯烃聚合物材料的接枝共聚物的方法,包括:a)在约80℃的温度下将反应性过氧化物的烯烃聚合物材料(A)处理至低于软化温度 该聚合物材料具有约5至约120份/ 100份聚合物材料(A)(重量比)(pph)的至少一种可自由基聚合的接枝单体; b)处理阶段a)接枝共聚物在约80℃至低于阶段a)接枝共聚物的软化点的温度,其接触共聚物与步骤a)中使用的温度相同或不同, 约5至约120pph的至少一种不同于阶段a)中使用的单体的可接受自由基的单体。
    • 7. 发明申请
    • Irradiation process for making graft copolymers by sequential polymerization
    • 通过顺序聚合制备接枝共聚物的照射方法
    • US20060128824A1
    • 2006-06-15
    • US11302396
    • 2005-12-13
    • Vu DangCheng Song
    • Vu DangCheng Song
    • C08J3/28
    • C08F255/02C08F255/00C08F255/10C08F285/00
    • A process for making a graft copolymer of an olefin polymer material in at least two polymerization stages comprising: a) irradiating an olefin polymer material at a temperature of about 10° C. to about 85° C. with high energy ionizing radiation, thereby forming an irradiated olefin polymer material (A); b) treating the irradiated olefin polymer material (A) at a temperature from about 25° C. to about 90° C. with about 5 to about 120 pph of at least one grafting monomer which is polymerizable by free radicals, thereby forming a stage b) graft copolymer; c) treating the stage b) graft copolymer at a temperature from about 25° C. to about 90° C., which is the same as or different from the temperature used in stage b), with about 5 to about 120 pph of at least one grafting monomer which is different from the monomer used in stage b) and polymerizable by free radicals.
    • 一种在至少两个聚合阶段中制备烯烃聚合物材料的接枝共聚物的方法,包括:a)用高能电离辐射在约10℃至约85℃的温度下照射烯烃聚合物材料,从而形成 被照射的烯烃聚合物材料(A); b)在约25℃至约90℃的温度下用约5至约120pph的至少一种可通过自由基聚合的接枝单体处理经辐射的烯烃聚合物材料(A),由此形成阶段 b)接枝共聚物; c)处理阶段b)接枝共聚物在约25℃至约90℃的温度下,其与阶段b)中使用的温度相同或不同,其中约5至约120pph的 至少一种与步骤b)中使用的单体不同的接枝单体,并且可由自由基聚合。