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1. 发明申请

US20080103325A1 Mixed metal oxide catalysts for the ammoxidation of propane and isobutane 审中-公开
标题翻译：用于丙烷和异丁烷氨氧化的混合金属氧化物催化剂
公开(公告)号：US20080103325A1
公开(公告)日：2008-05-01
申请号：US11590153
申请日：2006-10-31
申请人： Claus Lugmair , Benjamin Mork , Jessica Zysk Fryer , Anthony F. Volpe , Joseph Peter Bartek , Hailian Li , Alakananda Bhattacharyya , James F. Brazdil , Bruce I. Rosen , Eric Moore
发明人： Claus Lugmair , Benjamin Mork , Jessica Zysk Fryer , Anthony F. Volpe , Joseph Peter Bartek , Hailian Li , Alakananda Bhattacharyya , James F. Brazdil , Bruce I. Rosen , Eric Moore
IPC分类号： C07C253/26
CPC分类号： C07C253/24 , B01J2523/00 , C07C255/08 , B01J2523/3756 , B01J2523/47 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/3725 , B01J2523/3737 , B01J2523/3706 , B01J2523/3718 , B01J2523/3743 , B01J2523/375 , B01J2523/3762 , B01J2523/3768 , B01J2523/3775 , B01J2523/3781 , B01J2523/3787 , B01J2523/3793 , B01J2523/3712 , B01J2523/11
摘要： A catalyst composition comprising molybdenum, vanadium, antimony niobium, at least one element select from the group consisting of titanium, tin, germanium, zirconium, and hafnium, and at least one lanthanide selected from the group consisting of lanthanum, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium; with the proviso that catalyst contains germanium (in the absence of at last one of titanium, tin, zirconium, hafnium) only in combination with neodymium and/or praseodymium and no other lanthanides. Such catalyst compositions are effective for the gas-phase conversion of propane to acrylonitrile and isobutane to methacrylonitrile (via ammoxidation).
摘要翻译：一种催化剂组合物，其包含钼，钒，锑铌，至少一种选自钛，锡，锗，锆和铪的元素，以及至少一种选自镧，镨，钕，钐的镧系元素铕，钆，铽，镝，钬，铒，ium，镱和镥; 条件是催化剂仅与钕和/或镨组合而不与其他镧系元素结合使用锗（不存在钛，锡，锆，铪中的最后一种）。这种催化剂组合物可有效地将丙烷气相转化为丙烯腈和异丁烷至甲基丙烯腈（通过氨氧化）。

2. 发明授权

US6087524A Preparation of vanadium antimonate based catalysts using Sno.sub.2 .multidot.xH.sub.2 o 失效
标题翻译：使用Sno2xxH2o制备锑酸锑基催化剂
公开(公告)号：US6087524A
公开(公告)日：2000-07-11
申请号：US293452
申请日：1999-04-16
申请人： James Frank Brazdil, Jr. , Joseph Peter Bartek
发明人： James Frank Brazdil, Jr. , Joseph Peter Bartek
IPC分类号： B01J23/20 , B01J23/14 , B01J23/16 , B01J23/18 , B01J23/22 , B01J23/24 , B01J23/26 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/847 , B01J27/057 , B01J37/04 , C07B61/00 , C07C51/265 , C07C253/00 , C07C253/24 , C07C253/26 , C07C253/28 , C07C255/08 , C07C255/51 , C07D213/84
CPC分类号： C07D213/84 , B01J23/18 , B01J23/22 , C07C253/24 , C07C253/26 , Y02P20/52
摘要： A method of preparing a catalyst having the elements and the proportions indicated by the following empirical formula:VSb.sub.m A.sub.a D.sub.d O.sub.xwhereA is one or more Ti, Sn, where Sn is always presentD is one or more Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and Mn whereinm is 0.5 to 10a is greater than zero to 10d is zero to 10x is determined by the oxidation state of the cations present,comprising making an aqueous slurry of a mixture of source batch materials comprising compounds of said elements to be included in the final catalyst, followed by drying and heat calcining the mixture to an active catalyst, wherein the source batch material for the tin is a solution which comprises SnO.sub.2 .multidot.xH.sub.2 O wherein x.gtoreq.0 dispersed in tetraalkyl ammonium hydroxide wherein the tetraalkyl ammonium hydroxide is defined by the following formula:C.sub.n H.sub.2n+1 NOHwherein 5.gtoreq.n.gtoreq.1,drying said slurry and calcining the mixture to an upper calcination temperature of at least 500.degree. C.
摘要翻译：制备具有以下经验式所示元素和比例的催化剂的方法：VSbmAaDdOx其中A是一种或多种Ti，Sn，其中Sn总是存在D是一种或多种Li，Mg，Ca，Sr，Ba，Co ，Fe，Cr，Ga，Ni，Zn，Ge，Nb，Zr，Mo，W，Cu，Te，Ta，Se，Bi，Ce，In，As，B，Al和Mn，其中m为0.5〜大于0至10天是零至10倍，由存在的阳离子的氧化态确定，包括制备包含待包含在最终催化剂中的所述元素化合物的源批料的混合物的含水浆料，然后干燥并且将所述混合物热煅烧为活性催化剂，其中所述锡的所述源批料为包含分散在四烷基氢氧化铵中的其中x≥0的SnO 2·xH 2 O的溶液，其中所述四烷基氢氧化铵由下式定义：CnH2n + 1NOH其中干燥所述浆料并将混合物煅烧至上煅烧温度至少500℃

3. 发明授权

US5972833A Preparation of vanadium antimonate based catalysts using SnO.sub.2 .multidot.xH.sub.2 O 失效
标题翻译：使用SnO2xxH2O制备锑酸锑基催化剂
公开(公告)号：US5972833A
公开(公告)日：1999-10-26
申请号：US151463
申请日：1998-11-09
申请人： James Frank Brazdil, Jr. , Joseph Peter Bartek
发明人： James Frank Brazdil, Jr. , Joseph Peter Bartek
IPC分类号： B01J23/20 , B01J23/14 , B01J23/16 , B01J23/18 , B01J23/22 , B01J23/24 , B01J23/26 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/847 , B01J27/057 , B01J37/04 , C07B61/00 , C07C51/265 , C07C253/00 , C07C253/24 , C07C253/26 , C07C253/28 , C07C255/08 , C07C255/51 , C07D213/84 , B01J23/00 , B01J21/08
CPC分类号： C07D213/84 , B01J23/18 , B01J23/22 , C07C253/24 , C07C253/26 , Y02P20/52
摘要： A method of preparing a catalyst having the elements and the proportions indicated by the following empirical formula:VSb.sub.m A.sub.a D.sub.d O.sub.xwhereA is one or more Ti, Sn, where Sn is always presentD is one or more Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and Mn whereinm is 0.5 to 10a is greater than zero to 10d is zero to 10x is determined by the oxidation state of the cations present,comprising making an aqueous slurry of a mixture of source batch materials comprising compounds of said elements to be included in the final catalyst, followed by drying and heat calcining the mixture to an active catalyst, wherein the source batch material for the tin is a solution which comprises SnO.sub.2.xH.sub.2 O wherein x.gtoreq.0 dispersed in tetraalkyl ammonium hydroxide wherein the tetraalkyl ammonium hydroxide is defined by the following formula:C.sub.n H.sub.2n+1 NOHwherein 5.gtoreq.n.gtoreq.1,drying said slurry and calcining the mixture to an upper calcination temperature of at least 500.degree. C.
摘要翻译：制备具有以下经验式所示元素和比例的催化剂的方法：VSbmAaDdOx其中A是一种或多种Ti，Sn，其中Sn总是存在D是一种或多种Li，Mg，Ca，Sr，Ba，Co ，Fe，Cr，Ga，Ni，Zn，Ge，Nb，Zr，Mo，W，Cu，Te，Ta，Se，Bi，Ce，In，As，B，Al和Mn，其中m为0.5〜大于0至10天是零至10倍，由存在的阳离子的氧化态确定，包括制备包含待包含在最终催化剂中的所述元素化合物的源批料的混合物的含水浆料，然后干燥以及将所述混合物煅烧为活性催化剂，其中所述锡的所述源批料为包含SnO 2·xH 2 O的溶液，其中x 2 = 0分散在四烷基氢氧化铵中，其中所述四烷基氢氧化铵由下式定义：C n H 2n + 1NOH其中5> / = n> / = 1，干燥所述浆料并将混合物煅烧至上煅烧温度o f至少500℃

4. 发明授权

US5854172A Preparation of vanadium antimonate based catalysts using SnO.sub.2 .multidot.xH.sub.2 O 失效
标题翻译：使用SnO2xxH2O制备锑酸锑基催化剂
公开(公告)号：US5854172A
公开(公告)日：1998-12-29
申请号：US785543
申请日：1997-01-17
申请人： James Frank Brazdil, Jr. , Joseph Peter Bartek
发明人： James Frank Brazdil, Jr. , Joseph Peter Bartek
IPC分类号： B01J23/20 , B01J23/14 , B01J23/16 , B01J23/18 , B01J23/22 , B01J23/24 , B01J23/26 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/847 , B01J27/057 , B01J37/04 , C07B61/00 , C07C51/265 , C07C253/00 , C07C253/24 , C07C253/26 , C07C253/28 , C07C255/08 , C07C255/51 , C07D213/84 , B01J23/00 , B01J21/08
CPC分类号： C07D213/84 , B01J23/18 , B01J23/22 , C07C253/24 , C07C253/26 , Y02P20/52
摘要： A method of preparing a catalyst having the elements and the proportions indicated by the following empirical formula: VSb.sub.m A.sub.a D.sub.d O.sub.x where A is one or more Ti, Sn, where Sn is always present D is one or more Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and Mn wherein m is 0.5 to 10 a is greater than zero to 10 d is zero to 10 x is determined by the oxidation state of the cations present, comprising making an aqueous slurry of a mixture of source batch materials comprising compounds of said elements to be included in the final catalyst, followed by drying and heat calcining the mixture to an active catalyst, wherein the source batch material for the tin is a solution which comprises SnO.sub.2.xH.sub.2 O wherein x.gtoreq.0 dispersed in tetraalkyl ammonium hydroxide wherein the tetraalkyl ammonium hydroxide is defined by the following formula: C.sub.n H.sub.2n+1 NOH wherein 5.gtoreq.n.gtoreq.1, drying said slurry and calcining the mixture to an upper calcination temperature of at least 500.degree. C.
摘要翻译：制备具有以下经验式所示元素和比例的催化剂的方法：VSbmAaDdOx其中A是一种或多种Ti，Sn，其中Sn总是存在D是一种或多种Li，Mg，Ca，Sr，Ba，Co ，Fe，Cr，Ga，Ni，Zn，Ge，Nb，Zr，Mo，W，Cu，Te，Ta，Se，Bi，Ce，In，As，B，Al和Mn，其中m为0.5〜大于0至10天是零至10倍，由存在的阳离子的氧化态确定，包括制备包含待包含在最终催化剂中的所述元素化合物的源批料的混合物的含水浆料，然后干燥以及将所述混合物煅烧为活性催化剂，其中所述锡的所述源批料为包含SnO 2·xH 2 O的溶液，其中x 2 = 0分散在四烷基氢氧化铵中，其中所述四烷基氢氧化铵由下式定义：C n H 2n + 1NOH其中5> / = n> / = 1，干燥所述浆料并将混合物煅烧至上煅烧温度至少500℃

5. 发明授权

US06372908B1 Preparation of vanadium antimonate based catalyst using sno2h2o 失效
标题翻译：使用sno2h2o制备锑酸锑基催化剂
公开(公告)号：US06372908B1
公开(公告)日：2002-04-16
申请号：US09567674
申请日：2000-05-09
申请人： James Frank Brazdil, Jr. , Joseph Peter Bartek
发明人： James Frank Brazdil, Jr. , Joseph Peter Bartek
IPC分类号： C07D21384
CPC分类号： C07D213/84 , B01J23/18 , B01J23/22 , C07C253/24 , C07C253/26 , Y02P20/52 , C07C255/08 , C07C255/51
摘要： A method of preparing a catalyst having the elements and the proportions indicated by the following empirical formula: VSbmAaDdOx where A is one or more Ti, Sn, where Sn is always present D is one or more Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and Mn wherein m is 0.5 to 10 a is greater than zero to 10 d is zero to 10 x is determined by the oxidation state of the cations present, comprising making an aqueous slurry of a mixture of source batch materials comprising compounds of said elements to be included in the final catalyst, followed by drying and heat calcining the mixture to an active catalyst, wherein the source batch material for the tin is a solution which comprises SnO2.xH2O wherein x≧0 dispersed in tetraalkyl ammonium hydroxide wherein the tetraalkyl ammonium hydroxide is defined by the following formula: CnH2n+1NOH wherein 5≧n≧1, drying said slurry and calcining the mixture to an upper calcination temperature of at least 500° C.
摘要翻译：一种制备具有以下经验式所示元素和比例的催化剂的方法：其中A是一个或多个Ti，Sn，其中Sn总是存在D是一种或多种Li，Mg，Ca，Sr，Ba，Co，Fe ，Cr，Ga，Ni，Zn，Ge，Nb，Zr，Mo，W，Cu，Te，Ta，Se，Bi，Ce，In，As，B，Al和Mn，其中m为0.5〜 10d为零至10x由存在的阳离子的氧化态确定，包括制备包含待包含在最终催化剂中的所述元素化合物的源批料的混合物的水性浆料，然后干燥并将该混合物加热煅烧活性催化剂，其中锡的源批料是包含SnO 2·xH 2 O的溶液，其中x = 0分散在四烷基氢氧化铵中，其中四烷基氢氧化铵由下式定义：其中5> = n> = 1 ，干燥所述浆料并将混合物煅烧至至少500℃的上煅烧温度

6. 发明授权

US5994259A Catalysts for the ammoxidation of alkanes 失效
标题翻译：用于烷烃氨氧化的催化剂
公开(公告)号：US5994259A
公开(公告)日：1999-11-30
申请号：US124956
申请日：1998-07-29
申请人： James Frank Brazdil, Jr. , Joseph Peter Bartek
发明人： James Frank Brazdil, Jr. , Joseph Peter Bartek
IPC分类号： B01J23/847 , C07C253/24 , C07C255/08 , B01J23/00 , B01J23/16 , B01J23/58
CPC分类号： B01J23/8472 , C07C253/24 , Y02P20/52
摘要： An ammoxidation catalyst characterized by the following empirical formula comprising:VSb.sub.a Sn.sub.b Ti.sub.c Fe.sub.d O.sub.xwhere1.ltoreq.a.ltoreq.1.80.ltoreq.b.ltoreq.0.350.ltoreq.c.ltoreq.0.150 1.2then 0
摘要翻译：一种氨氧化催化剂，其特征在于以下经验式，其包括：VSbaSnbTicFedOx，其中1≤b≤0.08,0≤b≤0.30≤c≤0.15,0 1.2时，0

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