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1. 发明授权

US4579718A Apparatus for continuous production of polymer beads of controlled size 失效
标题翻译：用于连续生产受控尺寸的聚合物珠粒的装置
公开(公告)号：US4579718A
公开(公告)日：1986-04-01
申请号：US560327
申请日：1983-12-12
申请人： Claude R. L. Vairetti , Michel R. L. Desnoyers , Jack Carbonel , Paul D. A. Grammont , Arkadyi B. Pachkov , Vladimir A. Grigoriev , Vladimir I. Firsov
发明人： Claude R. L. Vairetti , Michel R. L. Desnoyers , Jack Carbonel , Paul D. A. Grammont , Arkadyi B. Pachkov , Vladimir A. Grigoriev , Vladimir I. Firsov
IPC分类号： B01J19/00 , C08F2/00 , C08F2/18 , C08F2/20 , C08J9/00
CPC分类号： B01J19/0006 , C08F2/18
摘要： An apparatus for the continuous production of spherical polymer beads in a restricted size range. Monomer droplets are produced in said size range by subjecting a fine monomer dispersion containing a controlled amount of a surface protective agent to controlled coalescence during passage through a tube (11) under laminar flow conditions. The monomer droplets are delivered from the tube (11) to the top of a polymerizing column (12) of variable cross-section wherein they undergo suspension polymerization in a laminar liquid stream descending through the column. Further polymerization in a separate reactor (30a, 30b) provides the desired polymer beads.
摘要翻译：用于连续生产限制尺寸范围的球形聚合物珠粒的方法和设备。通过在层流条件下通过管（11）通过含有受控量的表面保护剂的精细单体分散体来控制聚结，在所述尺寸范围内产生单体液滴。单体液滴从管（11）输送到可变横截面的聚合塔（12）的顶部，其中它们在通过塔下降的层流液流中进行悬浮聚合。在单独的反应器（30a，30b）中进一步聚合提供所需的聚合物珠粒。

2. 发明授权

US4424318A Continuous production of polymer beads of controlled size 失效
标题翻译：连续生产受控尺寸的聚合物珠粒
公开(公告)号：US4424318A
公开(公告)日：1984-01-03
申请号：US305647
申请日：1981-09-18
申请人： Claude R. L. Vairetti , Michel R. L. Desnoyers , Jack Carbonel , Paul D. A. Grammont , Arkadyi B. Pachkov , Vladimir A. Grigoriev , Vladimir I. Firsov
发明人： Claude R. L. Vairetti , Michel R. L. Desnoyers , Jack Carbonel , Paul D. A. Grammont , Arkadyi B. Pachkov , Vladimir A. Grigoriev , Vladimir I. Firsov
IPC分类号： B01J19/00 , C08F2/00 , C08F2/18 , C08F2/20
CPC分类号： B01J19/0006 , C08F2/18
摘要： A process and apparatus for the continuous production of spherical polymer beads in a restricted size range. Monomer droplets are produced in said size range by subjecting a fine monomer dispersion containing a controlled amount of a surface protective agent to controlled coalescence during passage through a tube (11) under laminar flow conditions. The monomer droplets are delivered from the tube (11) to the top of a polymerizing column (12) of variable cross-section wherein they undergo suspension polymerization in a laminar liquid stream descending through the column. Further polymerization in a separate reactor (30a, 30b) provides the desired polymer beads.
摘要翻译： PCT No.PCT / EP81 / 00069 Sec。 371日期1981年9月18日 102（e）1981年9月18日PCT申请1981年6月10日PCT公布。公开号WO81 / 03659 日期为1981年12月24日。用于连续生产限制尺寸范围的球形聚合物珠粒的方法和装置。通过在层流条件下通过管（11）通过含有受控量的表面保护剂的精细单体分散体来控制聚结，在所述尺寸范围内产生单体液滴。单体液滴从管（11）输送到可变横截面的聚合塔（12）的顶部，其中它们在通过塔下降的层流液流中进行悬浮聚合。在单独的反应器（30a，30b）中进一步聚合提供所需的聚合物珠粒。

3. 发明授权

US4818773A Alkylaminophosphonic chelating resins, their preparation and use in purifying brines 失效
标题翻译：烷基氨基膦酸螯合树脂，其制备和用于净化盐水
公开(公告)号：US4818773A
公开(公告)日：1989-04-04
申请号：US671720
申请日：1984-11-15
申请人： Michel A. G. Cornette , Jack Carbonel , Jacques E. A. Franc , Paul D. A. Grammont
发明人： Michel A. G. Cornette , Jack Carbonel , Jacques E. A. Franc , Paul D. A. Grammont
IPC分类号： C08F8/40
CPC分类号： C08F8/40
摘要： New macroporous alkylaminophosphonic chelating resins which exhibit excellent mechanical stability and strength and good chemical stability are characterized by having an apparent density of 0.35 to 0.425 g/ml, a granulometry smaller than 0.8 mm, a water retention of 50 to 60 percent in the acid form, a porosity of 800 to 1100 mm.sup.3 g, a total theoretical capacity for the fixation of calcium ions of not greater than 31 g/l of resin in the sodium form and an osmotic resistance such that more than 90 percent of the beads are intact after 30 shocks. The high resistance to osmotic shock combined with an adequate exchange capacity exhibited by the new resins makes them particularly suitable for use in highly concentrated solutions, such as concentrated electrolytic brines.A simple, effective, and economical procedure is described which makes it possible to eliminate, in the form of complexed cations, the impurities contained in the brines used for the electrolytic production of chlorine or alkali metals in membrane cells or diaphragm cells and for the electrolytic production of chlorates.
摘要翻译：表现出优异的机械稳定性和强度以及良好的化学稳定性的新型大孔烷基氨基膦酸螯合树脂，其表观密度为0.35〜0.425g / ml，粒度小于0.8mm，酸形式的保水率为50〜60％，孔隙度为800〜1100mm 3 g，钙离子固定不超过31g / l的钠离子型树脂的总理论容量和耐渗透性，使得90％以上的珠粒在30 冲击。高耐渗透冲击与新型树脂所具有的充分交换能力使其特别适用于高浓度溶液，如浓缩电解盐水。描述了一种简单，有效和经济的方法，其可以以复合阳离子的形式消除用于电解生产膜电池或隔膜电池中的氯或碱金属的盐水中的杂质和电解生产氯酸盐。

4. 发明授权

US4002564A Cation-exchange resins having cross-linked vinyl aromatic polymer matrix with attached amino alkylene phosphonic acid groups, their use, and preparation 失效
标题翻译：具有交联乙烯基芳族聚合物基质与连接的氨基亚烷基膦酸基团的阳离子交换树脂，它们的用途和制备
公开(公告)号：US4002564A
公开(公告)日：1977-01-11
申请号：US598526
申请日：1975-07-23
申请人： Jack Carbonel , Paul D. A. Grammont , Jean E. E. Herbin
发明人： Jack Carbonel , Paul D. A. Grammont , Jean E. E. Herbin
IPC分类号： C22B3/00 , B01J39/12 , B01J39/20 , B01J47/00 , C02F1/42 , C08F8/00 , C08F8/40 , C08F212/14 , C22B3/24 , C08F212/08
CPC分类号： B01J39/12 , C22B3/42 , Y02P10/234
摘要： Described is an ion exchange resin prepared from a cross-linked vinyl-aromatic polymer carrying recurring active units of the formula --CH.sub.2 NHRPO(OH).sub.2 wherein R is a lower alkylene radical. Such resins are useful in selectively removing metal ions from solutions, and may be prepared, e.g., by reaction of a primary amino-substituted cross-linked copolymer with a phosphorus trihalide and a simple (C.sub.1 -C.sub.3) aldehyde.
摘要翻译：描述了由交联乙烯基芳族聚合物制备的离子交换树脂，该交联乙烯基芳族聚合物带有式-CH2NHRPO（OH）2的重复活性单元，其中R是低级亚烷基。这种树脂可用于从溶液中选择性地除去金属离子，并且可以例如通过伯氨基取代的交联共聚物与三卤化磷和简单的（C 1 -C 3）醛的反应来制备。

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