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1. 发明申请

US20100133186A1 High Performance Cross-Linked Polybenzoxazole and Polybenzothiazole Polymer Membranes 有权
标题翻译：高性能交联聚苯并恶唑和聚苯并噻唑聚合物膜
公开(公告)号：US20100133186A1
公开(公告)日：2010-06-03
申请号：US12412633
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01D71/06 , B01D61/36
CPC分类号： B01D53/228 , B01D61/362 , B01D67/0006 , B01D71/62 , B01D2256/10 , B01D2256/24 , B01D2257/104 , B01D2257/108 , B01D2257/304 , B01D2257/504 , B01D2258/05 , B01D2258/06 , B01D2323/30 , Y02C10/10 , Y02C20/20
摘要： In the present invention high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes and methods for making and using these membranes have been developed. The cross-linked polybenzoxazole and polybenzothiazole polymer membranes are prepared by: 1) first synthesizing polyimide polymers comprising pendent functional groups (e.g., —OH or —SH) ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone; 2) fabricating polyimide membranes from these polymers; 3) converting the polyimide membranes to polybenzoxazole or polybenzothiazole membranes by heating under inert atmosphere such as nitrogen or vacuum; and 4) finally converting the membranes to high performance cross-linked polybenzoxazole or polybenzothiazole membranes by a crosslinking treatment, preferably UV radiation. The membranes can be fabricated into any convenient geometry. The high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes of the present invention are suitable for a variety of liquid, gas, and vapor separations.
摘要翻译：在本发明中，开发了高性能交联聚苯并恶唑和聚苯并噻唑聚合物膜以及制备和使用这些膜的方法。交联的聚苯并恶唑和聚苯并噻唑聚合物膜是通过以下步骤制备的：1）首先合成聚酰亚胺聚合物，其包含与杂环酰亚胺氮邻接的侧基官能团（例如-OH或-SH）和聚合物主链中的可交联官能团; 2）从这些聚合物制造聚酰亚胺膜; 3）通过在惰性气氛如氮气或真空下加热将聚酰亚胺膜转化为聚苯并恶唑或聚苯并噻唑膜; 和4）最后通过交联处理，优选UV辐射将膜转化成高性能交联聚苯并恶唑或聚苯并噻唑膜。膜可以制造成任何方便的几何形状。本发明的高性能交联聚苯并恶唑和聚苯并噻唑聚合物膜适用于各种液体，气体和蒸气分离。

2. 发明授权

US08127937B2 High performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes 有权
公开(公告)号：US08127937B2
公开(公告)日：2012-03-06
申请号：US12412633
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01D71/64 , B01D71/66 , B01D71/60 , B01D59/12 , B01D53/22 , B01D61/00
CPC分类号： B01D53/228 , B01D61/362 , B01D67/0006 , B01D71/62 , B01D2256/10 , B01D2256/24 , B01D2257/104 , B01D2257/108 , B01D2257/304 , B01D2257/504 , B01D2258/05 , B01D2258/06 , B01D2323/30 , Y02C10/10 , Y02C20/20
摘要： In the present invention high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes and methods for making and using these membranes have been developed. The cross-linked polybenzoxazole and polybenzothiazole polymer membranes are prepared by: 1) first synthesizing polyimide polymers comprising pendent functional groups (e.g., —OH or —SH) ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone; 2) fabricating polyimide membranes from these polymers; 3) converting the polyimide membranes to polybenzoxazole or polybenzothiazole membranes by heating under inert atmosphere such as nitrogen or vacuum; and 4) finally converting the membranes to high performance cross-linked polybenzoxazole or polybenzothiazole membranes by a crosslinking treatment, preferably UV radiation. The membranes can be fabricated into any convenient geometry. The high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes of the present invention are suitable for a variety of liquid, gas, and vapor separations.

3. 发明授权

US08127936B2 High performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes 有权
标题翻译：高性能交联聚苯并恶唑和聚苯并噻唑聚合物膜
公开(公告)号：US08127936B2
公开(公告)日：2012-03-06
申请号：US12412629
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01D71/64 , B01D71/68 , B01D71/50 , B01D61/00
CPC分类号： C08G75/32 , B01D67/0093 , B01D71/62 , B01D2323/30 , B01D2323/345 , B01J20/26 , B01J20/262 , B01J20/267 , C08G73/1042 , C08G73/22
摘要： In the present invention high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes and methods for making and using these membranes have been developed. The cross-linked polybenzoxazole and polybenzothiazole polymer membranes are prepared by: 1) first synthesizing polyimide polymers comprising pendent functional groups (e.g., —OH or —SH) ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone; 2) fabricating polyimide membranes from these polymers; 3) converting the polyimide membranes to polybenzoxazole or polybenzothiazole membranes by heating under inert atmosphere such as nitrogen or vacuum; and 4) finally converting the membranes to high performance cross-linked polybenzoxazole or polybenzothiazole membranes by a crosslinking treatment, preferably UV radiation. The membranes can be fabricated into any convenient geometry. The high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes of the present invention are suitable for a variety of liquid, gas, and vapor separations.
摘要翻译：在本发明中，开发了高性能交联聚苯并恶唑和聚苯并噻唑聚合物膜以及制备和使用这些膜的方法。交联的聚苯并恶唑和聚苯并噻唑聚合物膜是通过以下步骤制备的：1）首先合成聚酰亚胺聚合物，其包含与杂环酰亚胺氮邻接的侧基官能团（例如-OH或-SH）和聚合物主链中的可交联官能团; 2）从这些聚合物制造聚酰亚胺膜; 3）通过在惰性气氛如氮气或真空下加热将聚酰亚胺膜转化为聚苯并恶唑或聚苯并噻唑膜; 和4）最后通过交联处理，优选UV辐射将膜转化成高性能交联聚苯并恶唑或聚苯并噻唑膜。膜可以制造成任何方便的几何形状。本发明的高性能交联聚苯并恶唑和聚苯并噻唑聚合物膜适用于各种液体，气体和蒸气分离。

4. 发明授权

US08613362B2 Polymer membranes derived from aromatic polyimide membranes 有权
标题翻译：衍生自芳族聚酰亚胺膜的聚合物膜
公开(公告)号：US08613362B2
公开(公告)日：2013-12-24
申请号：US12412653
申请日：2009-03-27
申请人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
发明人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
IPC分类号： B01D71/64 , B01D71/28 , B01D69/00
CPC分类号： B01D71/64 , B01D67/0088 , B01D2323/08 , B01D2323/30
摘要： The present invention discloses a new type of high performance polymer membranes derived from aromatic polyimide membranes and methods for making and using these membranes. The polymer membranes described in the present invention were derived from aromatic polyimide membranes by crosslinking followed by thermal treating. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The high performance polymer membranes showed significantly improved permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The high performance polymer membranes also showed significantly improved selectivity for gas separations compared to the thermal-treated but non-UV-crosslinked aromatic polyimide membranes. The high performance polymer membranes of the present invention are suitable for liquid, gas, and vapor separations, as well as for catalysis and fuel cell applications.
摘要翻译：本发明公开了一种衍生自芳族聚酰亚胺膜的新型高性能聚合物膜以及制造和使用这些膜的方法。本发明中描述的聚合物膜通过交联然后进行热处理从芳族聚酰亚胺膜得到。芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。与没有任何处理的芳族聚酰亚胺膜相比，高性能聚合物膜显示出显着改善气体分离的渗透性。与热处理但非UV交联的芳族聚酰亚胺膜相比，高性能聚合物膜还显示出对气体分离的选择性显着提高。本发明的高性能聚合物膜适用于液体，气体和蒸汽分离，以及催化和燃料电池应用。

5. 发明授权

US08132678B2 Polybenzoxazole polymer-based mixed matrix membranes 有权
标题翻译：聚苯并恶唑聚合物基混合基质膜
公开(公告)号：US08132678B2
公开(公告)日：2012-03-13
申请号：US12412647
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01D71/02 , B01D71/40 , B01D71/64 , B01D71/82 , B01D59/12 , B01D69/00
CPC分类号： B01D69/148 , B01D53/228 , B01D67/0079 , B01D71/028 , B01D71/62 , B01D2256/16 , B01D2256/18 , B01D2256/24 , B01D2257/108 , B01D2257/304 , B01D2257/504 , B01D2258/06 , H01M8/1048 , H01M2300/0082 , Y02C10/10 , Y02C20/20
摘要： The present invention discloses new types of polybenzoxazole-based mixed matrix membranes and methods for making and using these membranes. The polybenzoxazole-based mixed matrix membranes are prepared by fabricating a polyimide-based mixed matrix membrane by dispersing molecular sieve particles in a continuous aromatic polyimide matrix with pendent hydroxyl groups ortho to the heterocyclic imide nitrogen; and then converting the polyimide-based mixed matrix membrane to a polybenzoxazole-based mixed matrix membrane by heating between 200° and 600° C. under inert atmosphere or vacuum. The polybenzoxazole-based mixed matrix membranes of the present invention can be fabricated into any convenient geometry such as flat sheet (or spiral wound), tube, hollow fiber, or thin film composite. These polybenzoxazole-based mixed matrix membranes exhibit high thermal stability, significantly higher selectivity than the neat polybenzoxazole polymer membranes, and much higher permeability than traditional mixed matrix membranes.
摘要翻译：本发明公开了新型的基于苯并恶唑的混合基质膜，以及制造和使用这些膜的方法。基于聚苯并恶唑的混合基质膜通过将分子筛颗粒分散在具有与杂环酰亚胺氮原子相邻的侧羟基的连续芳族聚酰亚胺基体中制备聚酰亚胺基混合基质膜来制备; 然后通过在惰性气氛或真空下在200℃和600℃之间加热将聚酰亚胺基混合基质膜转变成聚苯并恶唑类混合基质膜。本发明的基于聚苯并恶唑的混合基质膜可以制成任何方便的几何形状，例如平板（或螺旋缠绕），管，中空纤维或薄膜复合材料。这些基于聚苯并恶唑的混合基质膜具有高的热稳定性，比纯聚苯并恶唑聚合物膜显着更高的选择性，并且比传统的混合基质膜具有更高的渗透性。

6. 发明申请

US20100243567A1 Polymer Membranes Derived from Aromatic Polyimide Membranes 有权
标题翻译：衍生自芳族聚酰亚胺膜的聚合物膜
公开(公告)号：US20100243567A1
公开(公告)日：2010-09-30
申请号：US12412653
申请日：2009-03-27
申请人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
发明人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
IPC分类号： B01D53/22 , B01D71/64 , B01D61/00 , C08L77/06 , C08F2/48
CPC分类号： B01D71/64 , B01D67/0088 , B01D2323/08 , B01D2323/30
摘要： The present invention discloses a new type of high performance polymer membranes derived from aromatic polyimide membranes and methods for making and using these membranes. The polymer membranes described in the present invention were derived from aromatic polyimide membranes by crosslinking followed by thermal treating. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The high performance polymer membranes showed significantly improved permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The high performance polymer membranes also showed significantly improved selectivity for gas separations compared to the thermal-treated but non-UV-crosslinked aromatic polyimide membranes. The high performance polymer membranes of the present invention are suitable for liquid, gas, and vapor separations, as well as for catalysis and fuel cell applications.
摘要翻译：本发明公开了一种衍生自芳族聚酰亚胺膜的新型高性能聚合物膜以及制造和使用这些膜的方法。本发明中描述的聚合物膜通过交联然后进行热处理从芳族聚酰亚胺膜衍生而来。芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。与没有任何处理的芳族聚酰亚胺膜相比，高性能聚合物膜显示出显着改善气体分离的渗透性。与热处理但非UV交联的芳族聚酰亚胺膜相比，高性能聚合物膜还显示出对气体分离的选择性显着提高。本发明的高性能聚合物膜适用于液体，气体和蒸汽分离，以及催化和燃料电池应用。

7. 发明申请

US20100137124A1 High Performance Cross-Linked Polybenzoxazole and Polybenzothiazole Polymer Membranes 有权
公开(公告)号：US20100137124A1
公开(公告)日：2010-06-03
申请号：US12412629
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01J20/28 , C08G69/48 , C08J3/28
CPC分类号： C08G75/32 , B01D67/0093 , B01D71/62 , B01D2323/30 , B01D2323/345 , B01J20/26 , B01J20/262 , B01J20/267 , C08G73/1042 , C08G73/22
摘要： In the present invention high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes and methods for making and using these membranes have been developed. The cross-linked polybenzoxazole and polybenzothiazole polymer membranes are prepared by: 1) first synthesizing polyimide polymers comprising pendent functional groups (e.g., —OH or —SH) ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone; 2) fabricating polyimide membranes from these polymers; 3) converting the polyimide membranes to polybenzoxazole or polybenzothiazole membranes by heating under inert atmosphere such as nitrogen or vacuum; and 4) finally converting the membranes to high performance cross-linked polybenzoxazole or polybenzothiazole membranes by a crosslinking treatment, preferably UV radiation. The membranes can be fabricated into any convenient geometry. The high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes of the present invention are suitable for a variety of liquid, gas, and vapor separations.

8. 发明申请

US20100133192A1 Polymer Membranes Prepared from Aromatic Polyimide Membranes by Thermal Treating and UV Crosslinking 有权
标题翻译：通过热处理和UV交联从芳族聚酰亚胺膜制备的聚合物膜
公开(公告)号：US20100133192A1
公开(公告)日：2010-06-03
申请号：US12412649
申请日：2009-03-27
申请人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01D53/22 , B01D39/16 , B01D61/02 , C08G73/10
CPC分类号： B01D71/62 , B01D53/228 , B01D67/0093 , B01D2323/08 , B01D2323/30 , B01D2323/345 , C08G73/1039 , C08G73/1042 , C08G73/1046 , C08G73/1064 , C08G73/16 , C08L79/08 , Y02C20/20
摘要： The present invention discloses a new type of high performance polymer membranes prepared from aromatic polyimide membranes by thermal treating and crosslinking and methods for making and using these membranes. The polymer membranes were prepared from aromatic polyimide membranes by thermal treating under inert atmosphere followed by crosslinking preferably by using a UV radiation source. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The membranes showed significantly improved selectivity and permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The membranes can be fabricated into any convenient geometry and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used for other applications such as for catalysis and fuel cell applications.
摘要翻译：本发明公开了通过热处理和交联由芳族聚酰亚胺膜制备的新型高性能聚合物膜以及制造和使用这些膜的方法。聚合物膜由芳族聚酰亚胺膜通过在惰性气氛下热处理制备，然后优选通过使用UV辐射源进行交联。芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。与没有任何处理的芳族聚酰亚胺膜相比，膜显示出气体分离的选择性和渗透性显着提高。膜可以制造成任何方便的几何形状，并且不仅适用于各种液体，气体和蒸汽分离，而且还可以用于其它应用，例如用于催化和燃料电池应用。

9. 发明申请

US20100133187A1 Polybenzoxazole Polymer-Based Mixed Matrix Membranes 有权
标题翻译：聚苯并恶唑聚合物基混合基质膜
公开(公告)号：US20100133187A1
公开(公告)日：2010-06-03
申请号：US12412647
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01D61/36 , B01D53/22 , B01D71/06
CPC分类号： B01D69/148 , B01D53/228 , B01D67/0079 , B01D71/028 , B01D71/62 , B01D2256/16 , B01D2256/18 , B01D2256/24 , B01D2257/108 , B01D2257/304 , B01D2257/504 , B01D2258/06 , H01M8/1048 , H01M2300/0082 , Y02C10/10 , Y02C20/20
摘要： The present invention discloses new types of polybenzoxazole-based mixed matrix membranes and methods for making and using these membranes. The polybenzoxazole-based mixed matrix membranes are prepared by fabricating a polyimide-based mixed matrix membrane by dispersing molecular sieve particles in a continuous aromatic polyimide matrix with pendent hydroxyl groups ortho to the heterocyclic imide nitrogen; and then converting the polyimide-based mixed matrix membrane to a polybenzoxazole-based mixed matrix membrane by heating between 200° and 600° C. under inert atmosphere or vacuum. The polybenzoxazole-based mixed matrix membranes of the present invention can be fabricated into any convenient geometry such as flat sheet (or spiral wound), tube, hollow fiber, or thin film composite. These polybenzoxazole-based mixed matrix membranes exhibit high thermal stability, significantly higher selectivity than the neat polybenzoxazole polymer membranes, and much higher permeability than traditional mixed matrix membranes.
摘要翻译：本发明公开了新型的基于苯并恶唑的混合基质膜，以及制造和使用这些膜的方法。基于聚苯并恶唑的混合基质膜通过将分子筛颗粒分散在具有与杂环酰亚胺氮原子相邻的侧羟基的连续芳族聚酰亚胺基体中制备聚酰亚胺基混合基质膜来制备; 然后通过在惰性气氛或真空下在200℃和600℃之间加热将聚酰亚胺基混合基质膜转变成聚苯并恶唑类混合基质膜。本发明的基于聚苯并恶唑的混合基质膜可以制成任何方便的几何形状，例如平板（或螺旋缠绕），管，中空纤维或薄膜复合材料。这些基于聚苯并恶唑的混合基质膜具有高的热稳定性，比纯聚苯并恶唑聚合物膜显着更高的选择性，并且比传统的混合基质膜具有更高的渗透性。

10. 发明申请

US20100133171A1 Polybenzoxazole Polymer-Based Mixed Matrix Membranes 审中-公开
标题翻译：聚苯并恶唑聚合物基混合基质膜
公开(公告)号：US20100133171A1
公开(公告)日：2010-06-03
申请号：US12412643
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01D39/16
CPC分类号： B01D71/82 , B01D67/0079 , B01D69/148
摘要： The present invention discloses new types of polybenzoxazole-based mixed matrix membranes and methods for making and using these membranes. The polybenzoxazole-based mixed matrix membranes are prepared by fabricating a polyimide-based mixed matrix membrane by dispersing molecular sieve particles in a continuous aromatic polyimide matrix with pendent hydroxyl groups ortho to the heterocyclic imide nitrogen; and then converting the polyimide-based mixed matrix membrane to a polybenzoxazole-based mixed matrix membrane by heating between 300° and 600° C. under inert atmosphere or vacuum. The polybenzoxazole-based mixed matrix membranes of the present invention can be fabricated into any convenient geometry such as flat sheet (or spiral wound), tube, hollow fiber, or thin film composite. These polybenzoxazole-based mixed matrix membranes exhibit high thermal stability, significantly higher selectivity than the neat polybenzoxazole polymer membranes, and much higher permeability than traditional mixed matrix membranes.
摘要翻译：本发明公开了新型的基于苯并恶唑的混合基质膜，以及制造和使用这些膜的方法。基于聚苯并恶唑的混合基质膜通过将分子筛颗粒分散在具有与杂环酰亚胺氮原子相邻的侧羟基的连续芳族聚酰亚胺基体中制备聚酰亚胺基混合基质膜来制备; 然后通过在惰性气氛或真空下在300℃和600℃之间加热将聚酰亚胺基混合基质膜转变成聚苯并恶唑类混合基质膜。本发明的基于聚苯并恶唑的混合基质膜可以制成任何方便的几何形状，例如平板（或螺旋缠绕），管，中空纤维或薄膜复合材料。这些基于聚苯并恶唑的混合基质膜具有高的热稳定性，比纯聚苯并恶唑聚合物膜显着更高的选择性，并且比传统的混合基质膜具有更高的渗透性。

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