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    • 3. 发明申请
    • METHOD FOR PREPARING A HIGH THERMAL CONDUCTIVITY AND LOW DISSIPATION FACTOR ADHESIVE VARNISH FOR BUILD-UP ADDITIONAL INSULATION LAYERS
    • 制备高导热性和低消耗因子的方法粘合剂用于建立附加绝缘层
    • US20110077337A1
    • 2011-03-31
    • US12567255
    • 2009-09-25
    • Yun-Chao YEHChung-Hao CHANGCheng-Nan YENLi-Hung LIU
    • Yun-Chao YEHChung-Hao CHANGCheng-Nan YENLi-Hung LIU
    • C08K3/34C08K3/28C08K3/38C08K3/22C08K3/14
    • C08G59/686C08G59/18C08G59/38C08G59/4284C08L63/00C08L2666/22
    • A method for preparing a high thermal conductivity and low dissipation factor adhesive varnish for build-up (combining) additional insulation layers is disclosed, where the adhesive varnish is used for high-density interconnected printed circuit boards or package substrates. The method comprises steps of: selecting at least two epoxy resins from a group including a tri-functional epoxy resin, a rubber-modified or Dimmer-acid-modified epoxy resin, a bromide-contained epoxy resin, a halogen-free/phosphorus-contained epoxy resin, a halogen-free/phosphorus-free epoxy resin, a long-chain/halogen-free epoxy resin, and a bisphenol A (BPA) epoxy resin; adding selected epoxy resins into a pre-treatment vessel with a certain ratio; heating and mixing them well to form an epoxy resin precursor; cooling the epoxy resin precursor; during the cooling process, adding a solvent to the epoxy resin precursor to adjust the viscosity of the epoxy resin precursor; adding a bi-hardener solution, a catalyst, a solvent, and a flow modifier and mixing them well with the epoxy resin precursor; adding an inorganic filler with high thermal conductivity and mixing it with the mixture in step (d) in vacuum to obtain a suitable viscosity value; and leaving the mixture in step (e) undisturbed for a period of time to form the high thermal conductivity and low dissipation factor adhesive varnish for build-up (combining) additional insulation layers.
    • 公开了一种用于制备(组合)附加绝缘层的高热导率和低耗散因子粘合剂清漆的方法,其中粘合剂清漆用于高密度互连的印刷电路板或封装基板。 该方法包括以下步骤:从包括三官能环氧树脂,橡胶改性或二聚酸改性环氧树脂,溴化物包含的环氧树脂,无卤素/磷 - 不含环氧树脂,无卤/无磷环氧树脂,长链/无卤素环氧树脂和双酚A(BPA)环氧树脂; 以一定的比例将选定的环氧树脂加入到预处理容器中; 加热混合,形成环氧树脂前体; 冷却环氧树脂前体; 在冷却过程中,向环氧树脂前体添加溶剂以调节环氧树脂前体的粘度; 加入双硬化剂溶液,催化剂,溶剂和流动改性剂,并与环氧树脂前体充分混合; 加入具有高导热性的无机填料,并在真空中将其与步骤(d)中的混合物混合以获得合适的粘度值; 并使步骤(e)中的混合物不受干扰一段时间以形成用于积聚(组合)附加绝缘层的高热导率和低耗散因子粘合剂清漆。