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1. 发明申请

US20050260448A1 Novel organometallic compounds for use in electroluminescent devices 有权
标题翻译：用于电致发光器件的新型有机金属化合物
公开(公告)号：US20050260448A1
公开(公告)日：2005-11-24
申请号：US11032885
申请日：2005-01-10
申请人： Chun Lin , Jui-Yi Tsai , Jason Brooks , Bert Alleyne , Mark Thompson , Peter Djurovich , Arnold Tamayo , Tissa Sajoto , Robert Walters
发明人： Chun Lin , Jui-Yi Tsai , Jason Brooks , Bert Alleyne , Mark Thompson , Peter Djurovich , Arnold Tamayo , Tissa Sajoto , Robert Walters
IPC分类号： C09K11/06 , H01L51/00 , H01L51/50 , H05B33/14
CPC分类号： C09K11/06 , C09K2211/1044 , C09K2211/185 , H01L51/0059 , H01L51/0078 , H01L51/0081 , H01L51/0085 , H01L51/5016 , H05B33/14 , Y10S428/917
摘要： An organic light emitting device having an anode, a cathode and an organic layer between the anode and the cathode is provided. The organic layer comprises a carbene-metal complex having the structure: where R may be halo, hydrogen, alkyl, alkenyl, alkynyl, aralkyl, aryl, heteroaryl, substituted aryl, substituted heteroaryl, or a heterocyclic group; and additionally or alternatively, two or more R groups on the same ring form independently a 5 or 6-member cyclic group, which may be cycloalkyl, cycloheteroalkyl, aryl or heteroaryl; and which may be substituted by one or more substituents J; and J may be R′, CN, CF3, C(O)OR′, C(O)R′, C(O)NR′2, NR′2, NO2, OR′, SR′, SO2, SOR′, or SO3R′, and additionally or alternatively, two J groups on adjacent ring atoms form a fused 5- or 6-membered aromatic group; each R′ may be halo, H, alkyl, alkenyl, alkynyl, heteroalkyl, aralkyl, aryl and heteroaryl.
摘要翻译：提供了一种在阳极和阴极之间具有阳极，阴极和有机层的有机发光器件。有机层包含具有以下结构的卡宾金属络合物：其中R可以是卤素，氢，烷基，烯基，炔基，芳烷基，芳基，杂芳基，取代的芳基，取代的杂芳基或杂环基; 另外或替代地，相同环上的两个或更多个R基团独立地形成5或6元环基，其可以是环烷基，环杂烷基，芳基或杂芳基; 并且其可以被一个或多个取代基J取代; 并且J可以是R'，CN，CF 3，C（O）OR'，C（O）R'，C（O）NR'2，NR' 2'，2'，OR'，SR'，SO 2，SOR'或SO 3 R' ，另外或可选地，相邻环原子上的两个J基团形成稠合的5或6元芳族基团; 每个R'可以是卤素，H，烷基，烯基，炔基，杂烷基，芳烷基，芳基和杂芳基。

2. 发明申请

US20050258433A1 Carbene metal complexes as OLED materials 有权
标题翻译：碳烯金属络合物作为OLED材料
公开(公告)号：US20050258433A1
公开(公告)日：2005-11-24
申请号：US11032887
申请日：2005-01-10
申请人： Peter Djurovich , Jui-Yi Tsai , Chun Lin , Jason Brooks , Bert Alleyne , Mark Thompson , Peter MacKenzie , Bin Ma
发明人： Peter Djurovich , Jui-Yi Tsai , Chun Lin , Jason Brooks , Bert Alleyne , Mark Thompson , Peter MacKenzie , Bin Ma
IPC分类号： H01L27/15 , H01L29/08 , H01L35/24 , H01L51/00 , H01L51/50
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/1044 , C09K2211/185 , H01L51/0067 , H01L51/0069 , H01L51/0072 , H01L51/0077 , H01L51/0079 , H01L51/0081 , H01L51/5016 , H01L51/5036 , H01L2251/308 , Y10S428/917
摘要： An organic light emitting device having an anode, a cathode and an organic layer disposed between the anode and the cathode is provided. In one aspect, the organic layer comprises a compound having at least one zwitterionic carbon donor ligand. In another aspect, the organic layer comprises a carbene compound, including the following: In another aspect, the organic layer comprises a carbene compound, including: In another aspect, the organic layer comprises a carbene compound that includes a triazole ring and has the structure: In another aspect, the organic layer comprises a carbene compound that includes a tetrazole ring and has the structure:
摘要翻译：提供一种具有设置在阳极和阴极之间的阳极，阴极和有机层的有机发光器件。一方面，有机层包括具有至少一个两性离子碳供体配体的化合物。另一方面，有机层包括卡宾化合物，其包括以下：另一方面，有机层包含卡宾化合物，其包括：另一方面，有机层包含含有三唑环的卡宾化合物，其结构另一方面，有机层包含含有四唑环的卡宾化合物，其结构如下：

3. 发明申请

US20050260447A1 Cyclometallated iridium carbene complexes for use as hosts 有权
标题翻译：用作主体的环金属铱卡宾配合物
公开(公告)号：US20050260447A1
公开(公告)日：2005-11-24
申请号：US11032836
申请日：2005-01-10
申请人： Jason Brooks , Xiao-Chang Li , Bert Alleyne , Mark Thompson , Peter Djurovich , Arnold Tamayo
发明人： Jason Brooks , Xiao-Chang Li , Bert Alleyne , Mark Thompson , Peter Djurovich , Arnold Tamayo
IPC分类号： C09K11/06 , C25B3/00 , H01L51/00 , H01L51/30 , H01L51/50 , H05B33/14
CPC分类号： H05B33/14 , C09K11/06 , C09K2211/1044 , C09K2211/185 , H01L51/0059 , H01L51/0078 , H01L51/0081 , H01L51/0085 , H01L51/5016
摘要： An organic light emitting device is provided. The device has an anode, a cathode and an organic layer disposed between the anode and the cathode. The organic layer comprises a host and a dopant, and the host comprises a compound having at least one carbene atom coordinated to iridium, and the compound has the structure:
摘要翻译：提供有机发光装置。该器件具有阳极，阴极和设置在阳极和阴极之间的有机层。有机层包括主体和掺杂剂，并且主体包含具有与铱配位的至少一个卡宾原子的化合物，该化合物具有以下结构：

4. 发明申请

US20050260441A1 Luminescent compounds with carbene ligands 有权
标题翻译：具有卡宾配体的发光化合物
公开(公告)号：US20050260441A1
公开(公告)日：2005-11-24
申请号：US10849301
申请日：2004-05-18
申请人： Mark Thompson , Arnold Tamayo , Peter Djurovich , Tissa Sajoto
发明人： Mark Thompson , Arnold Tamayo , Peter Djurovich , Tissa Sajoto
IPC分类号： C07F15/00 , C09K11/06 , H01L51/00 , H01L51/50 , H05B33/14
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H05B33/14
摘要： An organic light emitting device is provided. The device has an anode, a cathode and an organic layer disposed between the anode and the cathode. The organic layer comprises a compound further comprising one or more carbene ligands coordinated to a metal center.
摘要翻译：提供有机发光装置。该器件具有阳极，阴极和设置在阳极和阴极之间的有机层。有机层包含进一步包含与金属中心配位的一个或多个卡宾配体的化合物。

5. 发明申请

US20060269785A1 Binuclear compounds 有权
标题翻译：双核化合物
公开(公告)号：US20060269785A1
公开(公告)日：2006-11-30
申请号：US11435210
申请日：2006-05-15
申请人： Mark Thompson , Bert Alleyne , Peter Djurovich
发明人： Mark Thompson , Bert Alleyne , Peter Djurovich
IPC分类号： H01L51/54 , H05B33/14
CPC分类号： H01L51/009 , H01L51/006 , H01L51/0071 , H01L51/0077 , H01L51/0087 , H01L51/5016 , H01L51/5036 , Y10S428/917
摘要： Devices are provided having an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode. The emissive layer includes an emissive material having more than one metal center. In one embodiment, first and second metal centers are independently selected from the group consisting of d7, d8, and d9 metals. A bridging ligand is coordinated to the first metal center and to the second metal center. In one embodiment, the first and second metal centers each have coordination numbers of at least 3, and more preferably each have coordination numbers of 4. In one embodiment, photoactive ligands are coordinated to the first and second metal centers. In one embodiment, there are no photoactive ligands. In one embodiment, a charge neutral bi-nuclear emissive material is provided. In one embodiment the first and metal centers have a co-facial configuration, and preferably a square planar co-facial configuration. In one embodiment, the metal centers are selected from metals having an atomic number greater than or equal to 40.
摘要翻译：提供了具有阳极，阴极和布置在阳极和阴极之间并与之电连接的发射层的器件。发射层包括具有多于一个金属中心的发光材料。在一个实施方案中，第一和第二金属中心独立地选自d7，d8和d9金属。桥连配体与第一金属中心和第二金属中心配位。在一个实施方案中，第一和第二金属中心各自具有至少3的配位数，并且更优选地各自具有4的配位数。在一个实施方案中，光活性配体与第一和第二金属中心配位。在一个实施方案中，不存在光活性配体。在一个实施例中，提供电荷中性双核发射材料。在一个实施例中，第一和金属中心具有共面配置，并且优选地是正方形平面协同配置。在一个实施方案中，金属中心选自原子序数大于或等于40的金属。

6. 发明申请

US20060024526A1 Organic light emitting devices with electron blocking layers 有权
公开(公告)号：US20060024526A1
公开(公告)日：2006-02-02
申请号：US11230851
申请日：2005-09-19
申请人： Mark Thompson , Vadim Adamovich , Xiaofan Ren , Arnold Tamayo , Peter Djurovich
发明人： Mark Thompson , Vadim Adamovich , Xiaofan Ren , Arnold Tamayo , Peter Djurovich
IPC分类号： H05B33/12
CPC分类号： H01L51/0085 , C09K11/06 , C09K2211/1044 , C09K2211/185 , H01L51/0059 , H01L51/0062 , H01L51/0077 , H01L51/0081 , H01L51/0087 , H01L51/5096 , H01L2251/308 , H05B33/14 , Y10S428/917
摘要： The present invention relates to organic light emitting devices (OLEDs), and more specifically to efficient OLEDs having electron blocking layers. The devices of the present invention comprise at least one electron blocking layer which functions to confine electrons to specific regions of the light emitting devices. The present invention also relates to materials for use as electron blockers that show increased stability when incorporated into an organic light emitting device.

7. 发明申请

US20050260449A1 Complexes with tridentate ligands 有权
标题翻译：与三齿配体的配合物
公开(公告)号：US20050260449A1
公开(公告)日：2005-11-24
申请号：US11032950
申请日：2005-01-10
申请人： Robert Walters , Jui-Yi Tsai , Peter MacKenzie , Mark Thompson
发明人： Robert Walters , Jui-Yi Tsai , Peter MacKenzie , Mark Thompson
IPC分类号： C09K11/06 , H01L35/24 , H01L51/00 , H01L51/50 , H05B33/14
CPC分类号： H01L51/0088 , C09K11/06 , C09K2211/1044 , C09K2211/185 , H01L51/5016 , H05B33/14
摘要： The present invention relates to organic light emitting devices (OLEDs), and more specifically to phosphorescent organic materials used in such devices. More specifically, the present invention relates to emissive phosphorescent material which comprise at least one tridentate ligand bound to a metal center, wherein at least one of the bonds to the tridentate ligand is a carbon-metal bond.
摘要翻译：本发明涉及有机发光器件（OLED），更具体地涉及用于这种器件中的磷光有机材料。更具体地说，本发明涉及包含与金属中心结合的至少一个三齿配体的发射磷光材料，其中至少一个与三齿配体键的键为碳 - 金属键。

8. 发明申请

US20050119485A1 Organometallic compounds for use in electroluminescent devices 有权
标题翻译：用于电致发光器件的有机金属化合物
公开(公告)号：US20050119485A1
公开(公告)日：2005-06-02
申请号：US11002188
申请日：2004-12-03
申请人： Cory Brown , David Knowles , Raymond Kwong , Yeh-Jiun Tung , Robert Walters , Peter Djurovich , Mark Thompson
发明人： Cory Brown , David Knowles , Raymond Kwong , Yeh-Jiun Tung , Robert Walters , Peter Djurovich , Mark Thompson
IPC分类号： C07F15/00 , C09K11/06 , H01L51/30 , H01L51/50 , H05B33/14
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1003 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/185 , H01L51/0085 , H01L51/5016 , Y10S428/917
摘要： An organic light emitting device is provided. The device has an anode, a cathode, and an emissive layer disposed between the anode and the cathode. The emissive layer further comprising an emissive material having the structure: M is a metal having an atomic weight greater than 40. R5 is an aromatic group. The emissive material itself is also provided. The emissive material provides an improved stability and efficiency.
摘要翻译：提供有机发光装置。该器件具有阳极，阴极和布置在阳极和阴极之间的发射层。发射层还包括具有以下结构的发射材料：M是原子量大于40的金属.R 5是芳族基团。还提供了发射材料本身。发光材料提供了改进的稳定性和效率。

9. 发明申请

US20050260446A1 Cationic metal-carbene complexes 有权
标题翻译：阳离子金属 - 卡宾络合物
公开(公告)号：US20050260446A1
公开(公告)日：2005-11-24
申请号：US11032721
申请日：2005-01-10
申请人： Peter Mackenzie , Robert Walters , Jason Brooks , Mark Thompson
发明人： Peter Mackenzie , Robert Walters , Jason Brooks , Mark Thompson
IPC分类号： C07F15/00 , C09K11/06 , H01L51/00 , H01L51/50 , H05B33/14
CPC分类号： H01L51/0087 , C07F15/002 , C07F15/0033 , C07F15/006 , C07F15/0073 , C07F15/0086 , C09K11/06 , C09K2211/1044 , C09K2211/185 , H01L51/0084 , H01L51/0085 , H01L51/5016 , H05B33/14 , Y10S428/917
摘要： The present invention relates to organic light emitting devices (OLEDs), and more specifically to phosphorescent organic materials used in such devices. More specifically, the present invention relates to emissive phosphorescent material comprising a carbene ligand bound to a metal center, wherein the resulting metal-carbene complex is cationic.
摘要翻译：本发明涉及有机发光器件（OLED），更具体地涉及用于这种器件中的磷光有机材料。更具体地，本发明涉及包含与金属中心结合的卡宾配体的发射磷光材料，其中所得金属 - 卡宾络合物是阳离子的。

10. 发明申请

US20060134465A1 Organic light emitting devices having carrier blocking layers comprising metal complexes 有权
公开(公告)号：US20060134465A1
公开(公告)日：2006-06-22
申请号：US11353338
申请日：2006-02-13
申请人： Mark Thompson , Xiaofan Ren , Vadim Adamovich , Steven Cordero , Brian D'Andrade , Bert Alleyne , Stephen Forrest
发明人： Mark Thompson , Xiaofan Ren , Vadim Adamovich , Steven Cordero , Brian D'Andrade , Bert Alleyne , Stephen Forrest
IPC分类号： H01L51/54 , H05B33/12
CPC分类号： H01L51/5096 , H01L51/0034 , H01L51/0035 , H01L51/0037 , H01L51/005 , H01L51/0059 , H01L51/0062 , H01L51/007 , H01L51/0077 , H01L51/0079 , H01L51/0081 , H01L51/0082 , H01L51/0084 , H01L51/0085 , H01L51/5016 , H01L51/5048 , Y10S428/917 , Y10T428/24942
摘要： Light emitting devices having blocking layers comprising one or more metal complexes are provided. The blocking layers may serve to block electrons, holes, and/or excitons. Preferably, the devices further comprise a separate emissive layer in which charge and/or excitons are confined. Metal complexes suitable for blocking layers can be selected by comparison of HOMO and LUMO energy levels of materials comprising adjacent layers in devices of the present invention.

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