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1. 发明申请

US20050143543A1 Water-soluble copolymers based on olefinic sulfonic acids, method for the production thereof and use of the same 有权
标题翻译：基于烯烃磺酸的水溶性共聚物，其制备方法和用途
公开(公告)号：US20050143543A1
公开(公告)日：2005-06-30
申请号：US10510855
申请日：2003-04-09
申请人： Christian Spindler , Johann Plank , Andrea Fenchl , Uwe Huber
发明人： Christian Spindler , Johann Plank , Andrea Fenchl , Uwe Huber
IPC分类号： C08F220/58 , C08F228/02 , C08F12/30
CPC分类号： C08F220/58 , C08F228/02
摘要： Water-soluble copolymers based on olefinic sulfonic acids, olefinic dicarboxylic acids, vinyl amides and vinyl ethers and/or allyl ethers and/or bisacryl derivatives are described as well as processes for their production and the use of these copolymers as water retention agents, thickeners or anti-segregation agents for aqueous building material systems that contain hydraulic binding agents such as cement, lime, gypsum, anhydrite etc. or for clay suspensions preferably based on bentonite.
摘要翻译：描述了基于烯烃磺酸，烯属二羧酸，乙烯基酰胺和乙烯基醚和/或烯丙基醚和/或双丙烯酰基衍生物的水溶性共聚物及其制备方法和这些共聚物作为保水剂，增稠剂或含有水泥粘合剂如水泥，石灰，石膏，无水石膏等的水性建筑材料体系的抗偏析剂或用于优选基于膨润土的粘土悬浮液。

2. 发明授权

US07202319B2 Water-soluble copolymers based on olefinic sulfonic acids, method for the production thereof and use of the same 有权
标题翻译：基于烯烃磺酸的水溶性共聚物，其制备方法和用途
公开(公告)号：US07202319B2
公开(公告)日：2007-04-10
申请号：US10510855
申请日：2003-04-09
申请人： Christian Spindler , Johann Plank , Andrea Fenchl , Uwe Huber
发明人： Christian Spindler , Johann Plank , Andrea Fenchl , Uwe Huber
IPC分类号： C08F26/08
CPC分类号： C08F220/58 , C08F228/02
摘要： Water-soluble copolymers based on olefinic sulfonic acids, olefinic dicarboxylic acids, vinyl amides and vinyl ethers and/or allyl ethers and/or bisacryl derivatives are described as well as processes for their production and the use of these copolymers as water retention agents, thickeners or anti-segregation agents for aqueous building material systems that contain hydraulic binding agents such as cement, lime, gypsum, anhydrite etc. or for clay suspensions preferably based on bentonite.
摘要翻译：描述了基于烯烃磺酸，烯属二羧酸，乙烯基酰胺和乙烯基醚和/或烯丙基醚和/或双丙烯酰基衍生物的水溶性共聚物及其制备方法和这些共聚物作为保水剂，增稠剂或含有水泥粘合剂如水泥，石灰，石膏，无水石膏等的水性建筑材料体系的抗偏析剂或用于优选基于膨润土的粘土悬浮液。

3. 发明申请

US20100062952A1 Copolymer based on olefinic sulphonic acids 审中-公开
标题翻译：基于烯烃磺酸的共聚物
公开(公告)号：US20100062952A1
公开(公告)日：2010-03-11
申请号：US12590673
申请日：2009-11-12
申请人： Andrea Fenchl , Christian Spindler , Jürgen Heidlas , Johann Plank
发明人： Andrea Fenchl , Christian Spindler , Jürgen Heidlas , Johann Plank
IPC分类号： C09K8/02 , C09K8/44
CPC分类号： C09K8/42 , C04B24/166 , C04B24/42 , C04B2103/46 , C08F216/1416 , C08F220/26 , C08F220/56 , C08F220/58 , C08F228/02 , C08F230/08 , C09K8/035 , C09K8/467 , C09K8/487
摘要： A copolymer based on olefinic sulphonic acids as monomer component a) and an organosilicone-containing compound as reactive component b) is proposed, for which in particular 2-acrylamido-2-methylpropanesulphonic acid (AMPS®) is suitable as component a) and vinyltrimethoxysilane, vinyltriethoxysilane and trichlorosilane as component b). This copolymer, which may have a molecular weight of from 5,000 to 5,000,000 g/mol, may also comprise further reaction components c) and d) in addition to the two main components for which further reaction components (meth)acrylamides or vinyl ethers are suitable. These copolymers, which are obtainable in particular by precipitation or gel polymerizations, are used in particular in applications in construction chemistry and here especially as water retention agents and fluid loss additives in drilling fluids and for well cementing. The novel copolymers are distinguished by pronounced thermal stability, which is displayed especially under difficult pressure conditions and at high salinities.
摘要翻译：提出了基于烯烃磺酸作为单体组分a）和含有机硅氧烷化合物作为反应组分b）的共聚物，其中特别是2-丙烯酰胺基-2-甲基丙磺酸（AMPS）适合作为组分a）和乙烯基三甲氧基硅烷乙烯基三乙氧基硅烷和三氯硅烷作为组分b）。除了其它反应组分（甲基）丙烯酰胺或乙烯基醚是合适的两种主要成分之外，该共聚物可以具有5,000至5,000,000g / mol的分子量的其它反应组分c）和d）。特别是通过沉淀或凝胶聚合可获得的这些共聚物特别用于建筑化学应用中，尤其用于钻井液中的保水剂和流体损失添加剂以及用于固井的物质。新型共聚物的特征在于明显的热稳定性，其特别在困难的压力条件下和高盐度下显示。

4. 发明申请

US20070100102A1 COPOLYMER BASED ON OLEFINIC SULPHONIC ACIDS 审中-公开
标题翻译：基于烯丙基磺酸的共聚物
公开(公告)号：US20070100102A1
公开(公告)日：2007-05-03
申请号：US11551490
申请日：2006-10-20
申请人： Andrea Fenchl , Christian Spindler , Jurgen Heidlas , Johann Plank
发明人： Andrea Fenchl , Christian Spindler , Jurgen Heidlas , Johann Plank
IPC分类号： C08F230/08 , C08F228/02
CPC分类号： C09K8/42 , C04B24/166 , C04B24/42 , C04B2103/46 , C08F216/1416 , C08F220/26 , C08F220/56 , C08F220/58 , C08F228/02 , C08F230/08 , C09K8/035 , C09K8/467 , C09K8/487
摘要： A copolymer based on olefinic sulphonic acids as monomer component a) and an organosilicone-containing compound as reactive component b) is proposed, for which in particular 2-acrylamido-2-methylpropanesulphonic acid (AMPS®) is suitable as component a) and vinyltrimethoxysilane, vinyltriethoxysilane and trichlorosilane as component b). This copolymer, which may have a molecular weight of from 5,000 to 5,000,000 g/mol, may also comprise further reaction components c) and d) in addition to the two main components for which further reaction components (meth)acrylamides or vinyl ethers are suitable. These copolymers, which are obtainable in particular by precipitation or gel polymerizations, are used in particular in applications in construction chemistry and here especially as water retention agents and fluid loss additives in drilling fluids and for well cementing. The novel copolymers are distinguished by pronounced thermal stability, which is displayed especially under difficult pressure conditions and at high salinities.
摘要翻译：提出了基于烯属磺酸作为单体组分a）和含有机硅氧烷化合物作为反应组分b）的共聚物，其中特别是2-丙烯酰胺基-2-甲基丙烷磺酸（AMPS）适合作为组分a）乙烯基三甲氧基硅烷，乙烯基三乙氧基硅烷和三氯硅烷作为组分b）。除了其它反应组分（甲基）丙烯酰胺或乙烯基醚是合适的两种主要成分之外，该共聚物可以具有5,000至5,000,000g / mol的分子量的其它反应组分c）和d）。特别是通过沉淀或凝胶聚合可获得的这些共聚物特别用于建筑化学应用中，尤其用于钻井液中的保水剂和流体损失添加剂以及用于固井。新型共聚物的特征在于明显的热稳定性，其特别在困难的压力条件下和高盐度下显示。

5. 发明申请

US20080227667A1 Fluid Loss Control Additive and Cement Compositions Comprising Same 审中-公开
标题翻译：流体损失控制添加剂和包含其的水泥组合物
公开(公告)号：US20080227667A1
公开(公告)日：2008-09-18
申请号：US12129189
申请日：2008-05-29
申请人： Michael J. Szymanski , Samuel J. Lewis , Christian Spindler , Andrea Fenchl
发明人： Michael J. Szymanski , Samuel J. Lewis , Christian Spindler , Andrea Fenchl
IPC分类号： C09K8/88 , C09K8/60 , C09K8/86
CPC分类号： C09K8/46 , C04B24/2623 , C04B28/04 , C04B2103/46 , C08K5/55 , C09K8/487 , C04B24/08 , C04B24/10 , C04B24/32 , C08L29/04
摘要： A fluid loss control additive comprising a crosslinked polymer and sugar and cement compositions comprising the same. In one embodiment, the fluid loss control additive comprises a polymer and a sugar connected by a pH-sensitive crosslink. In some embodiments, the polymer is a polyvinyl alcohol, and the sugar is a sugar alcohol such as sorbitol.
摘要翻译：一种流体损失控制添加剂，其包含交联聚合物和糖和包含其的水泥组合物。在一个实施方案中，流体损失控制添加剂包括聚合物和通过pH敏感性交联连接的糖。在一些实施方案中，聚合物是聚乙烯醇，并且糖是糖醇，例如山梨糖醇。

6. 发明授权

US07399355B2 Fluid loss control additive and cement compositions comprising same 有权
标题翻译：流体损失控制添加剂和包含其的水泥组合物
公开(公告)号：US07399355B2
公开(公告)日：2008-07-15
申请号：US11063006
申请日：2005-02-22
申请人： Michael J. Szymanski , Samuel J. Lewis , Christian Spindler , Andrea Fenchl
发明人： Michael J. Szymanski , Samuel J. Lewis , Christian Spindler , Andrea Fenchl
IPC分类号： C04B24/00
CPC分类号： C09K8/46 , C04B24/2623 , C04B28/04 , C04B2103/46 , C08K5/55 , C09K8/487 , C04B24/08 , C04B24/10 , C04B24/32 , C08L29/04
摘要： A fluid loss control additive comprising a crosslinked polymer and sugar and cement compositions comprising the same. In one embodiment, the fluid loss control additive comprises a polymer and a sugar connected by a pH-sensitive crosslink. In some embodiments, the polymer is a polyvinyl alcohol, and the sugar is a sugar alcohol such as sorbitol.
摘要翻译：一种流体损失控制添加剂，其包含交联聚合物和糖和包含其的水泥组合物。在一个实施方案中，流体损失控制添加剂包括聚合物和通过pH敏感性交联连接的糖。在一些实施方案中，聚合物是聚乙烯醇，并且糖是糖醇，例如山梨糖醇。

7. 发明申请

US20060189487A1 Fluid loss control additive and cement compositions comprising same 有权
标题翻译：流体损失控制添加剂和包含其的水泥组合物
公开(公告)号：US20060189487A1
公开(公告)日：2006-08-24
申请号：US11063006
申请日：2005-02-22
申请人： Michael Szymanski , Samuel Lewis , Christian Spindler , Andrea Fenchl
发明人： Michael Szymanski , Samuel Lewis , Christian Spindler , Andrea Fenchl
IPC分类号： C09K17/10 , C09K17/40
CPC分类号： C09K8/46 , C04B24/2623 , C04B28/04 , C04B2103/46 , C08K5/55 , C09K8/487 , C04B24/08 , C04B24/10 , C04B24/32 , C08L29/04
摘要： A fluid loss control additive comprising a crosslinked polymer and sugar and cement compositions comprising the same. In one embodiment, the fluid loss control additive comprises a polymer and a sugar connected by a pH-sensitive crosslink. In some embodiments, the polymer is a polyvinyl alcohol, and the sugar is a sugar alcohol such as sorbitol.
摘要翻译：一种流体损失控制添加剂，其包含交联聚合物和糖和包含其的水泥组合物。在一个实施方案中，流体损失控制添加剂包括聚合物和通过pH敏感性交联连接的糖。在一些实施方案中，聚合物是聚乙烯醇，并且糖是糖醇，例如山梨糖醇。

8. 发明授权

US07612150B2 Polyamide-based water-soluble biodegradable copolymers and the use thereof 有权
标题翻译：聚酰胺类水溶性生物降解性共聚物及其用途
公开(公告)号：US07612150B2
公开(公告)日：2009-11-03
申请号：US10536596
申请日：2003-12-11
申请人： Christian Spindler , Johann Plank
发明人： Christian Spindler , Johann Plank
IPC分类号： C08L77/04
CPC分类号： C08G69/48 , C04B24/287 , C04B2103/0053 , C04B2103/0059 , C04B2103/0072 , C04B2103/0074 , C04B2103/30 , C04B2103/46 , C08H1/00 , C08H1/02 , C08H1/04 , C08H1/06
摘要： Water-soluble, biologically degradable copolymers based on polyamide are described which contain at least one grafted side chain composed of aldehydes and sulfur-containing acids and salts thereof and optionally at least one compound from the series ketones, aromatic alcohols, urea (derivatives) and amino-s-triazines. Natural polyamides such as caseins, gelatins, collagens, bone glues, blood albumins and soya proteins as well as degradation products thereof and synthetic polyamides such as polyaspartic acids and copolymers of aspartic and glutamic acid are used as preferred polyamide components. These copolymers are obtained primarily by graft polymerization at temperatures between −10 and 250° C., preferably in the presence of a solvent such as water or by thermal drying and they are used in particular as flow agents or water retention agents for inorganic binders and pigments especially in combination with hydraulic binders they only have a very slight setting-retardant effect.
摘要翻译：描述了基于聚酰胺的水溶性生物可降解共聚物，其含有至少一个由醛和含硫酸及其盐组成的接枝侧链，以及任选的至少一种来自串联酮，芳族醇，脲（衍生物）和氨基-s-三嗪。天然聚酰胺如酪蛋白，明胶，胶原，骨胶，血液白蛋白和大豆蛋白以及其降解产物和合成聚酰胺如聚天冬氨酸和天冬氨酸和谷氨酸的共聚物被用作优选的聚酰胺组分。这些共聚物主要通过在-10至250℃的温度下接枝聚合，优选在溶剂如水或通过热干燥的存在下获得，并且它们特别用作无机粘合剂的流动剂或保水剂，颜料特别是与水性粘合剂组合，它们只具有非常轻微的阻燃效果。

9. 发明申请

US20100240802A1 WATER-SOLUBLE AND BIODEGRADABLE COPOLYMERS ON A POLYAMIDE BASIS AND USE THEREOF 有权
标题翻译：聚酰胺基础上的水溶性和生物可降解共聚物及其用途
公开(公告)号：US20100240802A1
公开(公告)日：2010-09-23
申请号：US12376297
申请日：2007-08-09
申请人： Martin Matzinger , Roland Reichenbach-Klinke , Gregor Keilhofer , Johann Plank , Christian Spindler
发明人： Martin Matzinger , Roland Reichenbach-Klinke , Gregor Keilhofer , Johann Plank , Christian Spindler
IPC分类号： C09K8/44
CPC分类号： C09K8/487 , C04B24/14 , C04B24/2641 , C04B24/287 , C04B2103/0053 , C04B2103/0072 , C04B2103/0074 , C04B2103/302 , C04B2111/00724 , C08F283/04 , C09K8/467 , C08F222/06
摘要： Copolymers based on a polyamide containing at least one graft lateral chain consisting of ethylenic unsaturated compounds, in construction chemistry, as well as with the prospecting, exploiting and completion of oil-and gas deposits and with deep bore holes.
摘要翻译：基于聚酰胺的共聚物，其包含至少一种由烯键式不饱和化合物组成的接枝侧链，在建筑化学中，以及勘探，开采和完成油气沉积物以及深孔。

10. 发明申请

US20060074201A1 Polyamide-based water-soluble biodegradable copolymers and the use thereof 有权
公开(公告)号：US20060074201A1
公开(公告)日：2006-04-06
申请号：US10536596
申请日：2003-12-11
申请人： Christian Spindler , Johann Plank
发明人： Christian Spindler , Johann Plank
IPC分类号： C08G69/48
CPC分类号： C08G69/48 , C04B24/287 , C04B2103/0053 , C04B2103/0059 , C04B2103/0072 , C04B2103/0074 , C04B2103/30 , C04B2103/46 , C08H1/00 , C08H1/02 , C08H1/04 , C08H1/06
摘要： Water-soluble, biologically degradable copolymers based on polyamide are described which contain at least one grafted side chain composed of aldehydes and sulfur-containing acids and salts thereof and optionally at least one compound from the series ketones, aromatic alcohols, urea (derivatives) and amino-s-triazines. Natural polyamides such as caseins, gelatins, collagens, bone glues, blood albumins and soya proteins as well as degradation products thereof and synthetic polyamides such as polyaspartic acids and copolymers of aspartic and glutamic acid are used as preferred polyamide components. These copolymers are obtained primarily by graft polymerization at temperatures between −10 and 250° C., preferably in the presence of a solvent such as water or by thermal drying and they are used in particular as flow agents or water retention agents for inorganic binders and pigments especially in combination with hydraulic binders they only have a very slight setting-retardant effect.

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