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    • 2. 发明授权
    • Low monomer 1:1-monoadducts from hydroxy (meth) acrylates and diisocyanates and a process for their manufacture
    • 低级单体1:1-羟基(甲基)丙烯酸酯和二异氰酸酯的单加成物及其制备方法
    • US06548696B2
    • 2003-04-15
    • US09923316
    • 2001-08-08
    • Stephan KohlstrukLothar HayenEmmanouil Spyrou
    • Stephan KohlstrukLothar HayenEmmanouil Spyrou
    • C07C6952
    • C08G18/8175
    • A low monomer 1:1-monoadduct from a diisocyanate and a hydroxy(meth)acrylate with a free diisocyanate content of less than 0.7% by weight and a free NCO content of 10.4-16.4% by weight can be used as a starting material for an acrylic or NCO functionalized crosslinker; a bonding agent for coatings and adhesives; and a linker for solid-phase synthesis of oligo-nucleotides, polynucleotides or peptides. The monoadduct is obtained by converting 5-20 mol diisocyanate with 1 mol hydroxy(meth)acrylate at a temperature of 40-120° C. in the presence of at least one inhibitor; subsequently separating a non-converted diisocyanate from a reaction product by short-path distillation at 80-220° C./0.1-10 mbar; feeding air, nitrogen monoxide or oxygen or a mixture containing (a) air, oxygen or nitrogen monoxide and (b) a proportion of 1-90% by volume of carbon dioxide, nitrogen, an inert gas or a mixture thereof through a reaction apparatus.
    • 可以使用二异氰酸酯和游离二异氰酸酯含量小于0.7重量%且游离NCO含量为10.4-16.4重量%的二异氰酸酯和羟基(甲基)丙烯酸酯的低单体1:1-加成物作为起始原料 丙烯酸或NCO官能化交联剂; 用于涂料和粘合剂的粘合剂; 和用于固相合成寡核苷酸,多核苷酸或肽的接头。 通过在至少一种抑制剂的存在下,在40-120℃的温度下将5-20mol二异氰酸酯与1mol羟基(甲基)丙烯酸酯反应获得单加合物; 随后通过短程蒸馏在80-220℃/ 0.1-10毫巴下将未转化的二异氰酸酯与反应产物分离; 进料空气,一氧化氮或氧气或含有(a)空气,氧气或一氧化氮的混合物和(b)比例为1-90体积%的二氧化碳,氮气,惰性气体或其混合物的反应装置 。