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    • 3. 发明申请
    • Method for producing chlorine from hydrochloric from hydrochloric aid
    • 从盐酸辅助的盐酸生产氯的方法
    • US20060099138A1
    • 2006-05-11
    • US10532725
    • 2003-10-27
    • Christian WalsdorffMartin FieneChristian KuhrsEckhard StroeferKlaus Harth
    • Christian WalsdorffMartin FieneChristian KuhrsEckhard StroeferKlaus Harth
    • C01B7/00
    • C01B7/0718C01B7/04C01B7/0743C07C263/10C07C265/14C07C265/06
    • Process for preparing chlorine from hydrochloric acid, which comprises the steps: a) providing a hydrochloric acid feed stream I; b) providing a hydrochloric acid recycle stream II; c) separating off a hydrogen chloride stream IV from the hydrochloric acid feed stream I and the hydrochloric acid recycle stream II in a distillation step; d) feeding the hydrogen chloride stream IV, an oxygen-containing steam V and, if desired, an oxygen-containing recycle stream Va into an oxidation zone and oxidizing hydrogen chloride to chlorine in the presence of a catalyst to give a product gas stream VI comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor; e) separating off hydrogen chloride and water from the product gas stream VI in an absorption step to give a gas stream VII and the hydrochloric acid recycle stream II; f) if desired, drying the gas stream VII; g) separating off an oxygen-containing stream from the gas stream VII and, if desired, recirculating at least part of this as oxygen-containing recycle stream Va to the oxidation zone, leaving a chlorine-containing product stream VIII; h) if desired, further purifying the chlorine-containing product stream VIII.
    • 从盐酸制备氯的方法,其包括以下步骤:a)提供盐酸进料流I; b)提供盐酸循环流II; c)在蒸馏步骤中,从盐酸进料流I和盐酸循环流II中分离出氯化氢料流IV; d)将氯化氢流IV,含氧蒸汽V以及如果需要的话将含氧再循环流Va加入氧化区,并在催化剂存在下将氯化氢氧化成氯,得到产物气流VI 包括氯,未反应的氧,未反应的氯化氢和水蒸气; e)在吸收步骤中从产物气流VI中分离氯化氢和水,得到气流VII和盐酸再循环流II; f)如果需要,干燥气流VII; g)从气流VII中分离含氧物流,如果需要,将其至少部分再循环为含氧再循环流Va至氧化区,留下含氯产物流VIII; h)如果需要,进一步纯化含氯产物流VIII。
    • 9. 发明申请
    • Catalyst composition for oxychlorination
    • 用于氧氯化的催化剂组合物
    • US20050020864A1
    • 2005-01-27
    • US10502056
    • 2003-02-04
    • Christian KuhrsRuprecht Meissner
    • Christian KuhrsRuprecht Meissner
    • B01J21/04B01J23/89B01J27/122B01J27/138B01J35/02B01J35/10B01J37/02C07B61/00C07C17/156C07C19/045C07C17/00C07C22/00
    • B01J27/138B01J21/04B01J23/8946B01J27/122B01J35/1014B01J35/1019B01J35/1038B01J35/1042B01J37/0201C07C17/156C07C19/045
    • The present invention relates to a catalyst composition for the oxychlorination of ethylene, comprising a mixture of metal salts on a support, where said metal salts are applied to the support in such ratios that the catalyst composition comprises a) from 3 to 12% by weight of copper as copper salt, b) from 0 to 3% by weight of an alkaline earth metal as alkaline earth metal salt, c) from 0 to 3% by weight of an alkaline metal as alkaline metal salt, d) from 0.001 to 0.1% by weight, preferably from 0.005 to 0.05% by weight, of at least one metal selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum, and/or from 0.0001 to 0.1% by weight, preferably from 0.001 to 0.05% by weight, of gold, as corresponding metal salt or tetrachloroauric acid, where all percentages by weight are based on the total weight of the catalyst including support material. The invention further provides a process for preparing 1,2-dichloroethane by oxychlorination of ethylene in the presence of the above catalyst composition as catalyst.
    • 本发明涉及用于乙烯氧氯化的催化剂组合物,其包含在载体上的金属盐的混合物,其中所述金属盐以这样的比例施加到载体上,使得催化剂组合物包含a)3至12重量% 的铜作为铜盐,b)0-3重量%的碱土金属作为碱土金属盐,c)0-3重量%的作为碱金属盐的碱金属,d)0.001至0.1 至少一种选自钌,铑,钯,锇,铱和铂的金属,和/或0.0001至0.1重量%,优选为0.001重量%,优选0.005至0.05重量% 至0.05重量%的金,作为相应的金属盐或四氯月桂酸,其中所有的重量百分数都是基于包括载体材料的催化剂的总重量。 本发明还提供了在上述催化剂组合物作为催化剂存在下,通过乙烯氧氯化制备1,2-二氯乙烷的方法。