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1. 发明授权

US3935100A Process for the treatment of waste waters containing sulfuric acid and/or ammonium sulfate 失效
标题翻译：处理含硫酸和/或硫酸铵废水的方法
公开(公告)号：US3935100A
公开(公告)日：1976-01-27
申请号：US484228
申请日：1974-06-28
申请人： Jacques Alagy , Christian Busson , Maurice Cessou
发明人： Jacques Alagy , Christian Busson , Maurice Cessou
IPC分类号： C01B17/16 , C01B17/58 , C02F1/52 , C02F1/58 , C02F1/66 , C02B1/34 , C02C5/06
CPC分类号： C02F1/66 , C01B17/58 , C02F1/5236 , C02F1/586
摘要： Process for treating a waste water containing sulfuric acid and/or ammonium sulfate comprising (1) reacting said water with barium sulfide to form barium sulfate, (2) reacting the latter with carbon containing inorganic impurities, at high temperature, thereby forming barium sulfide, at least a major portion of which is recycled to step (1), and a gas which is separated, (3) dissolving in water a minor portion of the barium sulfide produced in step (2), separating the insoluble impurities therefrom and recycling at least one portion of the resulting purified solution to step (1).
摘要翻译：包括（1）使所述水与硫化钡反应形成硫酸钡，（2）使其与含碳的无机杂质在高温下反应，从而形成硫化钡，其至少大部分被再循环到步骤（1），和分离的气体，（3）将在步骤（2）中生产的少量硫化钡溶解在水中，将不溶性杂质从其中分离出来，并在将所得纯化溶液的至少一部分至步骤（1）。

2. 发明授权

US4126638A Process for purifying benzene dicarboxylic acids 失效
标题翻译：净化苯甲酸二羧酸的方法
公开(公告)号：US4126638A
公开(公告)日：1978-11-21
申请号：US676714
申请日：1976-04-14
申请人： Jacques Alagy , Christian Busson , Maurice Cessou
发明人： Jacques Alagy , Christian Busson , Maurice Cessou
IPC分类号： C07C63/15 , C07C51/00 , C07C51/48 , C07C51/487 , C07C67/00 , C07C51/42
CPC分类号： C07C51/487 , C07C51/48
摘要： A benzene dicarboxylic acid is purified by heating a solution thereof to 110.degree. - 350.degree. C in the presence of a hydrogenation catalyst; the solvent is a mixture of water with a secondary or tertiary alcohol.

3. 发明授权

US4058591A Process for purifying waste water containing ammonium sulfate 失效
标题翻译：净化含硫酸铵废水的工艺
公开(公告)号：US4058591A
公开(公告)日：1977-11-15
申请号：US607802
申请日：1975-08-26
申请人： Christian Busson , Jacques Alagy , Maurice Cessou
发明人： Christian Busson , Jacques Alagy , Maurice Cessou
IPC分类号： C01B17/02 , C01B17/05 , C01B17/06 , C02F1/58 , C02B1/34 , C02C5/06
CPC分类号： C02F1/586 , C01B17/05 , C01B17/06
摘要： This process for purifying waste-water containing ammonium sulfate comprises reacting said waste-water with calcium oxide, calcium sulfide and ammonium sulfite; roasting the resulting precipitate to regenerate calcium oxide and calcium sulfide; and reacting sulfur dioxide with hydrogen sulfide obtained in a prior step to yield sulfur.
摘要翻译：用于净化含有硫酸铵的废水的方法包括使所述废水与氧化钙，硫化钙和亚硫酸铵反应; 焙烧所得沉淀物以再生氧化钙和硫化钙; 并且使二氧化硫与前面步骤中获得的硫化氢反应以产生硫。

4. 发明授权

US4039649A Process for removing sulfur from waste waters containing sulfuric acid 失效
标题翻译：从含有硫酸的废水中清除硫的方法
公开(公告)号：US4039649A
公开(公告)日：1977-08-02
申请号：US603621
申请日：1975-08-11
申请人： Jacques Alagy , Christian Busson , Maurice Cessou
发明人： Jacques Alagy , Christian Busson , Maurice Cessou
IPC分类号： C02F1/58 , C01B17/05 , C01B17/58 , C01B17/50 , B01D5/00 , C01B17/96 , C01C1/02
CPC分类号： C01B17/58 , C01B17/05 , Y10S423/02
摘要： Process for recovering sulfur from waste waters containing sulfuric acid, comprising reacting in a first step, the waste water with an aqueous solution of ammonium sulfite, separating the formed sulfur dioxide from the solution, reacting the resulting solution in a second step with calcium oxide to form calcium sulfate and an aqueous ammonia solution, vaporizing ammonia therefrom, reducing the calcium sulfate by means of carbon to form calcium oxide and sulfur dioxide, contacting said vaporized ammonia with said sulfur dioxide and with water, thereby forming an aqueous solution of ammonium sulfite, which is joined to that used in the first step and recycling at least a part of the calcium oxide obtained by reduction of the calcium sulfate to the second step.

5. 发明授权

US4738769A Process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions 失效
$Process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions$
标题翻译：将液体或半液体碳氢化合物装料转化为较轻馏分的方法
公开(公告)号：US4738769A
公开(公告)日：1988-04-19
申请号：US478428
申请日：1983-03-24
申请人： Christian Busson , Jacques Alagy , Jean-Paul Euzen , Pierre Galtier
发明人： Christian Busson , Jacques Alagy , Jean-Paul Euzen , Pierre Galtier
IPC分类号： B01J8/12 , C10G9/28 , C10G47/24
CPC分类号： B01J8/12 , C10G2400/20
摘要： A process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions comprises a first step (a) heating droplets jets of the charge introduced into a pyrolysis chamber by surrounding them with parallel jets of hot solid particles, of relatively large size, of a heat carrier material, not substantially in contact with the droplet jets, so as to maintain a temperature of 700.degree.-1600.degree. C., and introducing a gas so as to obtain a pressure from 1 to 150 bars. A second step involves (b) separating the gaseous fraction from the solid particles. Thereafter (c) at least a portion of the solid particles are heated and fed back to step (a). The gaseous fraction is (d) cooled by means of a cold gas so as to recover light hydrocarbons therefrom.
摘要翻译：将液体或半液体碳氢化合物装料转化成轻馏分的方法包括第一步骤（a）通过用相当大尺寸的热固体颗粒的平行射流包围引入到热解室中的电荷的液滴射流，热载体材料，基本上不与液滴射流接触，以保持700〜-1600℃的温度，并引入气体以获得1至150巴的压力。第二步涉及（b）从固体颗粒中分离气态馏分。此后（c）将至少一部分固体颗粒加热并反馈到步骤（a）。气态馏分（d）通过冷气体冷却，以从其中回收轻质烃。

6. 发明授权

US5270016A Apparatus for the thermal conversion of methane 失效
标题翻译：用于甲烷热转化的装置
公开(公告)号：US5270016A
公开(公告)日：1993-12-14
申请号：US913336
申请日：1992-07-15
申请人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
发明人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
IPC分类号： B01J12/00 , B01J19/24 , C07C2/76
CPC分类号： C07C2/76 , B01J12/005 , B01J19/24 , B01J2219/00135 , Y10S585/913
摘要： Apparatus suitable for the thermal conversion of methane to hydrocarbons of higher molecular weight, comprising an elongated reactor 1 provided with an inlet 5 for supplying a gas mixture containing methane (process gas) and an outlet at the opposite end, the reactor over a first part towards the inlet end having a plurality of electric heaters 3 surrounded by sheaths 4. The heaters, e.g., electric resistors, which are spaced apart and are substantially parallel with respect to one another, are arranged in substantially parallel rows perpendicular to the axis of the reactor so as to permit circulation of the process gas and/or effluent between the sheaths and/or between the sheaths and walls 22 separating two consecutive rows. The heaters heat the passages by successive independent cross sections substantially perpendicular to the axis of the reaction. Towards the outlet end, the reactor further comprises an injector for supplying cooling fluid, which cools the effluent. The reactor also has a hydrogen inlet for introducing a gas containing hydrogen into the space surrounding the heaters inside the sheaths 4 at an appropriate pressure. The reactor and the sheaths 4 are designed so that hydrogen is diffused from inside the sheaths to outside them and can then be diluted in the process gas.
摘要翻译：适用于将甲烷热转化成较高分子量的烃的装置，包括一个细长的反应器1，该反应器1设有一个入口5，入口5用于提供含有甲烷（工艺气体）的气体混合物和另一端的出口，第一部分朝向入口端具有由护套4围绕的多个电加热器3。间隔开并且相对于彼此大致平行的加热器，例如电阻器，被布置成垂直于反应器，以允许工艺气体和/或流出物在护套之间和/或分离两个连续的行的护套和壁22之间循环。加热器通过基本上垂直于反应轴线的连续的独立横截面来加热通道。朝向出口端，反应器还包括用于供应冷却流体的喷射器，其冷却流出物。反应器还具有氢气入口，用于以适当的压力将含氢的气体引入护套4内的加热器周围的空间。反应器和护套4被设计成使得氢气从鞘内部扩散到外部，然后可以在工艺气体中稀释。

7. 发明授权

US5321191A Process for the thermal pyrolysis of hydrocarbons using an electric furnace 失效
标题翻译：使用电炉对烃进行热解的方法
公开(公告)号：US5321191A
公开(公告)日：1994-06-14
申请号：US972782
申请日：1992-11-09
申请人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
发明人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
IPC分类号： C10G9/24 , C07C4/04
CPC分类号： C10G9/24 , Y10S585/921 , Y10S585/926
摘要： A process for the thermal pyrolysis of hydrocarbons in a reactor (1) of elongate shape comprising at a first end supply means (5) for a gaseous mixture containing at least one hydrocarbon, at the opposite end discharge means (10) for the effluents produced and between these two ends supply means (9) for effluent cooling fluid, the reactor comprising in a first part (first end side) a plurality of electric heating means (3) enclosed by casings (4) disposed in substantially mutually parallel layers perpendicular to the axis of the reactor, in such a way as to define between the casings and/or the casings and the walls (22), spaces or passages for circulation of the gaseous mixtures and/or effluents. The heating means heat the passages in successive, individual, transverse sections which are substantially perpendicular to the axis of the reactor. The reactor comprises means for introducing into the casings (4) a gas G known as a casing gas which preferably contains water vapour and/or hydrogen. The permeability of the casings is sufficient to permit diffusion, at least at certain points, of at least a part of the gas G from inside the casings to the outside of the casings, the gas G then being diluted in the gaseous mixture.
摘要翻译：一种用于在细长形状的反应器（1）中热解烃的方法，该方法包括在第一端供应装置（5），用于含有至少一种烃的气态混合物，在相对的端部排出装置（10）用于所产生的流出物并且在这两个端部之间，用于流出物冷却流体的供应装置（9），所述反应器包括在第一部分（第一端侧）中的多个电加热装置（3），所述多个电加热装置（3）由壳体（4）包围，反应器的轴线以限定壳体和/或壳体和壁（22）之间的方式，用于气态混合物和/或流出物循环的空间或通道。加热装置加热基本上垂直于反应器轴线的连续的，单独的横向部分中的通道。反应器包括用于将优选含有水蒸气和/或氢气的称为外壳气体的气体G引入壳体（4）的装置。壳体的渗透性足以允许至少在某些点处将气体G的至少一部分从壳体内部扩散到壳体的外部，然后将气体G稀释在气体混合物中。

8. 发明授权

US5186910A Method and reactor for oxidation with a pressure drop differential, and its use 失效
标题翻译：用于压力差异氧化的方法和反应器及其使用
公开(公告)号：US5186910A
公开(公告)日：1993-02-16
申请号：US582426
申请日：1990-09-12
申请人： Jacques Alagy , Paul Broutin , Christian Busson , Yves Gougne , Jerome Weill
发明人： Jacques Alagy , Paul Broutin , Christian Busson , Yves Gougne , Jerome Weill
IPC分类号： B01F3/02 , B01J4/04 , B01J8/04 , B01J12/00 , B01J19/00 , B01J19/24 , B01J35/04 , C01B3/36 , C01B3/38 , C01B32/40 , C01B32/50
CPC分类号： C01B3/363 , B01J12/005 , B01J19/2415 , B01J4/04 , C01B3/36 , B01J2208/00495 , B01J2219/00162
摘要： An oxidation reactor having elongated shape includes in combination, a mixing member including a pipe for feeding oxidizing gas and a pipe for feeding oxidizable charge; a reaction member, arranged subjacent the mixing member, and a discharge member associated with a discharge pipe for the products of the reaction. The reaction member includes a central zone which has a first lining and the reactor includes at least one peripheral zone which has a second lining, passages in the second lining being smaller than passages in the first lining so that the pressure loss in the second lining is greater than that of the first lining. The second lining forms a sleeve surround the first lining and this sleeve is formed of at least one refractory heat insulating material. The oxidation reactor is provided with an external sleeve steel jacket, a concrete wall and a steel element surrounding the mixing member arranged above the reaction member. The reaction member includes a series of single elements which form juxtaposed channels.
摘要翻译：具有细长形状的氧化反应器组合包括：混合构件，包括用于供给氧化气体的管和用于供给可氧化电荷的管; 布置在混合部件的下方的反应部件和与反应产物的排出管相关联的排出部件。反应构件包括具有第一衬里的中心区，反应器包括具有第二衬里的至少一个周边区，第二衬里中的通道小于第一衬里中的通道，使得第二衬里中的压力损失为大于第一衬里。第二衬里形成围绕第一衬里的套筒，并且该套筒由至少一个难熔绝热材料形成。氧化反应器设置有外部套筒钢护套，混凝土壁和围绕设置在反作用构件上方的混合构件的钢构件。反应构件包括形成并列通道的一系列单一元件。

9. 发明授权

US5160501A Method for thermal conversion of methane and reactor for carrying out the method 失效
标题翻译：甲烷和反应器热转化方法实施方法
公开(公告)号：US5160501A
公开(公告)日：1992-11-03
申请号：US700706
申请日：1991-05-16
申请人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
发明人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
IPC分类号： B01J12/00 , B01J19/24 , C07C2/76
CPC分类号： B01J19/24 , B01J12/005 , C07C2/76 , B01J2219/00135 , Y10S585/911 , Y10S585/913 , Y10S585/924 , Y10S585/926 , Y10S585/943
摘要： Method and apparatus for thermal conversion of methane to hydrocarbons of higher molecular weight, comprising a reactor 1 of elongated shape, connected at a first end to means 5 for supplying gas mixture containing methane (process gas), and connected at the opposite end to discharge means 10, the reactor having a plurality of electric heating means 3 surrounded by sheaths 4 over a first part (towards the first end). The heating means, which are substantially parallel, are arranged in sheets which are substantially parallel and perpendicular to the axis of the reactor, so that spaces or passages for circulation of the process gas and/or effluent are defined between the sheaths and/or between the sheaths and the walls 22 separating two consecutive sheets. The heating means are adapted to heat the passages by successive independent cross sections substantially perpendicular to the axis of the reactor. In a second part 8 (towards the opposite end) adjoining the first part, the reactor further comprises means 9 for cooling the effluent, connected to the means for supplying cooling fluid. The reactor also has means for introducing a gas containing hydrogen into the space surrounding the heating means inside the sheaths 4, at an appropriate pressure. The reactor and particularly the sheaths 4 are designed so that hydrogen is diffused from inside the sheaths to outside them and can then be diluted in the process gas.
摘要翻译：将甲烷热转化成较高分子量的烃的方法和装置，包括细长形状的反应器1，第一端连接到用于提供含有甲烷的气体混合物（工艺气体）的装置5，并在相对端连接以排出装置10，反应器具有在第一部分（朝向第一端）上被护套4包围的多个电加热装置3。基本上平行的加热装置被布置成基本上平行且垂直于反应器的轴线的片材，使得用于循环工艺气体和/或流出物的空间或通道限定在护套之间和/或之间护套和墙壁22分隔两个连续的片材。加热装置适于通过基本上垂直于反应器的轴线的连续的独立横截面来加热通道。在邻接第一部分的第二部分8（朝向相对端），反应器还包括用于冷却流出物的装置9，连接到用于供应冷却流体的装置。该反应器还具有用于在合适的压力下将含氢气体引入护套4内的加热装置周围空间的装置。反应器，特别是护套4被设计成使得氢气从鞘内部扩散到外部，然后可以在工艺气体中稀释。

10. 发明授权

US4780196A Hydrocarbon steam cracking method 失效
标题翻译：烃蒸汽裂化法
公开(公告)号：US4780196A
公开(公告)日：1988-10-25
申请号：US37353
申请日：1987-04-10
申请人： Jacques Alagy , Christian Busson , Pierre Chaverot
发明人： Jacques Alagy , Christian Busson , Pierre Chaverot
IPC分类号： C10G9/36 , B01J19/24 , C10G9/00 , C10G9/20 , F28F7/02
CPC分类号： C10G9/00 , B01J19/2425 , B01J19/2485 , C10G9/20 , F28F7/02 , B01J2219/00085 , B01J2219/00159
摘要： The invention relates to an improved hydrocarbon steam-cracking method intended to produce more particularly ethylene and propylene.The method is based on the utilization of a multi-channel system made of ceramic material, in which the charge and heat exchange fluids or refrigerants alternatively pass through the channels or rows of channels constituting the continuous assembly comprising a pyrolysis zone followed by a quenching zone.The method according to the invention is applicable to charges ranging from ethane to vacuum gas oils.
摘要翻译： PCT No.PCT / FR86 / 00215 Sec。 371日期：1987年4月10日 102（e）日期1987年4月10日PCT申请1986年6月20日PCT公开号公开号WO87 / 00546 日本1987年1月29日。本发明涉及旨在生产更特别是乙烯和丙烯的改进的烃蒸汽裂解方法。该方法基于利用由陶瓷材料制成的多通道系统，其中充电和热交换流体或制冷剂交替地通过构成连续组件的通道或排的通道，其包括热解区，随后是淬火区。根据本发明的方法适用于从乙烷到减压瓦斯油的电荷。

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