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    • 1. 发明授权
    • Organic EL device
    • 有机EL器件
    • US06280861B1
    • 2001-08-28
    • US09194424
    • 1999-01-21
    • Chishio HosokawaMasahide MatsuuraHiroshi Tokailin
    • Chishio HosokawaMasahide MatsuuraHiroshi Tokailin
    • H05B3314
    • H05B33/28H01L51/5206H01L51/5209H01L51/5215Y10S428/917Y10T428/24479Y10T428/24537Y10T428/24917Y10T428/31
    • An amorphous electrically conductive oxide such as In—Zn—O-containing amorphous oxide or amorphous ITO is used alone, or a laminate having a two- or three-layer structure constituted of the amorphous electrically conductive oxide and at least a thin metal layer is used, to form a transparent electrode whose side surface has a tapered form and whose top layer is formed of a layer of the above amorphous electrically conductive oxide, an organic single-layer portion or an organic multi-layer portion containing at least an organic light-emitting material is formed on the above transparent electrode, and further, an opposing electrode is formed on the above organic single-layer portion or the above organic multi-layer portion, whereby an organic EL device is obtained. A flattening layer is optionally provided so as to abut on the side surface of the transparent electrode for moderating a height-level difference between the above transparent electrode and the surface of the above substrate. Further, the above organic EL device is used to form an organic EL display panel.
    • 单独使用无定形导电氧化物,例如含In-Zn-O的无定形氧化物或非晶ITO,或由非晶导电氧化物和至少一薄层金属层构成的二层或三层结构的层压体 用于形成其侧表面具有锥形并且其顶层由上述非晶导电氧化物层形成的透明电极,有机单层部分或至少含有有机光的有机多层部分 在上述透明电极上形成发光材料,并且在上述有机单层部分或上述有机多层部分上形成相对电极,从而获得有机EL器件。 可选地设置平坦化层以邻接透明电极的侧表面,以缓和上述透明电极与上述基板的表面之间的高度差。 此外,使用上述有机EL器件来形成有机EL显示面板。
    • 2. 发明授权
    • Organic electroluminescent device
    • 有机电致发光器件
    • US06284393B1
    • 2001-09-04
    • US08980345
    • 1997-11-28
    • Chishio HosokawaMasahide MatsuuraHiroshi Tokailin
    • Chishio HosokawaMasahide MatsuuraHiroshi Tokailin
    • H05B3326
    • H05B33/28H01L51/5092H01L51/5234H01L2251/5315Y10S428/917
    • Transparent, organic EL devices comprising an positive electrode, a negative electrode and an organic layer including an organic light-emitting layer as sandwiched between the two electrodes, in which the negative electrode is comprised of an electron injection electrode layer and an amorphous transparent conductive film, and the electron injection electrode layer is adjacent to the organic layer, or in which the negative electrode is comprised of an electron injection electrode layer, a transparent conductive film and a thin metal film having a specific resistance of not larger than 1×10−5 &OHgr;·cm, as laminated in that order with the electron injection electrode layer being adjacent to the organic layer, and a thin transparent film is formed outside the negative electrode. Preferably, the transparent conductive film is an amorphous one. The devices have a negative electrode with low resistance and high transparency, and have high luminous efficiency and good durability (wet heat resistance). The light emission can be taken out through the side of the negative electrode of the devices. The devices are usable for high-resolution display.
    • 透明的有机EL器件包括正电极,负电极和包含夹在两电极之间的有机发光层的有机层,其中负电极由电子注入电极层和非晶透明导电膜 ,并且电子注入电极层与有机层相邻,或者其中负极由电子注入电极层,透明导电膜和电阻率不大于1×10 -5Ω的金属薄膜组成 cm,电子注入电极层与有机层相邻地依次层叠,在负极外侧形成薄的透明膜。 优选地,透明导电膜是非晶形导电膜。 这些器件具有低电阻和高透明度的负极,并且具有高发光效率和良好的耐久性(耐湿热性)。 可以通过器件的负极侧取出发光。 这些设备可用于高分辨率显示。
    • 3. 发明授权
    • Method for producing organic electroluminescent device
    • 生产有机电致发光器件的方法
    • US06001413A
    • 1999-12-14
    • US36000
    • 1998-03-06
    • Masahide MatsuuraHiroshi TokailinChishio Hosokawa
    • Masahide MatsuuraHiroshi TokailinChishio Hosokawa
    • C23C14/56H01L51/50H01L51/56H05B33/10B05D5/06
    • H05B33/10H01L51/56
    • Disclosed is a method for producing organic EL devices stably having intended capabilities. The method comprises cleaning an electrode-mounted substrate 17 followed by forming a plurality of film layers including organic layers and a counter electrode layer, on the electrode mounted on the substrate, successively one after another in vacuum, wherein the time just after the finish of cleaning the electrode-mounted substrate 17 and before the start of forming the first film layer on the electrode 12 is shorter than the time within which the value of the contact angle with water of the surface of the electrode 12 just after the finish of cleaning it increases by 30.degree. in vacuum. In producing organic EL devices having a plurality, n=1, 2, 3, . . . , of film layers on an electrode-mounted substrate, the time just after the finish of forming the n'th film layer and before the start of forming the next (n+1)'th film layer is shorter than the time within which the value of the contact angle with water of the surface of the n'th film layer just after having been formed increases by 30.degree. in vacuum. In the organic EL devices produced, the interfaces between the adjacent layers are protected from being contaminated with impurities.
    • 公开了一种稳定地具有预期能力的有机EL器件的制造方法。 该方法包括清洁电极安装的基板17,随后在真空中依次连续地在安装在基板上的电极上形成包括有机层和对电极层的多个膜层,其中刚刚完成之后的时间 清洁电极安装基板17,并且在电极12上开始形成第一膜层之前,比刚刚完成清洁之后电极12的表面与水的接触角的值的时间短 在真空中增加30°。 在制造具有多个n = 1,2,3的有机EL器件时。 。 。 在电极安装基板上的薄膜层,形成第n薄膜层之后的时间和形成下一个(n + 1)薄膜层之前的时间短于其中 刚刚形成第n层的表面与水接触角的值在真空中增加30°。 在所生产的有机EL器件中,相邻层之间的界面被保护以免被杂质污染。