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    • 9. 发明授权
    • Integrated circuit with improved contact barrier
    • 具有改善接触屏障的集成电路
    • US06291344B1
    • 2001-09-18
    • US09660738
    • 2000-09-13
    • De-Dul LiaoYih-Shung Lin
    • De-Dul LiaoYih-Shung Lin
    • H01L2144
    • H01L21/76846H01L21/28518H01L21/76843H01L21/76855H01L21/76856H01L21/76864H01L23/485H01L23/53223H01L2924/0002Y10S257/924H01L2924/00
    • Methods of forming, in an integrated circuit, aluminum-silicon contacts with a barrier layer is disclosed. The barrier layer is enhanced by the provision of titanium oxynitride layers adjacent the silicide film formed at the exposed silicon at the bottom of the contact. The titanium oxynitride may be formed by depositing a low density titanium nitride film over a titanium metal layer that is in contact with the silicon in the contact; subsequent exposure to air allows a relatively large amount of oxygen and nitrogen to enter the titanium nitride. A rapid thermal anneal (RTA) both causes silicidation at the contact location and also results in the oxygen and nitrogen being gettered to what was previously the titanium/titanium nitride interface, where the oxygen and nitrogen react with the titanium metal and nitrogen in the, atmosphere to form titanium oxynitride. The low density titanium nitride also densifies during the RTA. Alternative embodiments are also disclosed in which the silicide is formed first, prior to the formation of additional titanium oxynitride by air exposure and RTA, or by sputter deposition. Each of these processes produces a high-quality barrier contact structure overlying a silicide film, where the barrier structure includes titanium oxynitride and titanium nitride.
    • 在集成电路中形成具有阻挡层的铝 - 硅接触的方法被公开。 通过在接触底部的暴露的硅处形成的硅化物膜附近提供氧氮化钛层来增强阻挡层。 氮氧化钛可以通过在与接触中的硅接触的钛金属层上沉积低密度氮化钛膜而形成; 随后的空气暴露使得相对较大量的氧和氮进入氮化钛。 快速热退火(RTA)都在接触位置处引起硅化,并且还导致氧和氮被吸收到先前的钛/氮化钛界面,其中氧和氮与钛金属和氮气中的氮反应, 气氛形成氮氧化钛。 低密度钛氮化物也在RTA期间致密化。 还公开了另外的实施方案,其中在通过空气暴露和RTA形成额外的氮氧化钛之前,或通过溅射沉积,首先形成硅化物。 这些过程中的每一个产生覆盖硅化物膜的高质量的阻挡接触结构,其中阻挡结构包括氧氮化钛和氮化钛。
    • 10. 发明授权
    • Integrated circuit with a titanium nitride contact barrier having oxygen
stuffed grain boundaries
    • 具有氮氧化物接触屏障的集成电路具有氧填充晶界
    • US5652464A
    • 1997-07-29
    • US569392
    • 1995-12-08
    • De-Dui LiaoYih-Shung Lin
    • De-Dui LiaoYih-Shung Lin
    • H01L21/28H01L21/285H01L21/768H01L23/485H01L23/532H01L23/48H01L23/52H01L29/40
    • H01L21/76846H01L21/28518H01L21/76843H01L21/76855H01L21/76856H01L21/76864H01L23/485H01L23/53223H01L2924/0002Y10S257/924
    • Methods of forming, in an integrated circuit, aluminum-silicon contacts with a barrier layer is disclosed. The barrier layer is enhanced by the provision of titanium oxynitride layers adjacent the silicide film formed at the exposed silicon at the bottom of the contact. The titanium oxynitride may be formed by depositing a low density titanium nitride film over a titanium metal layer that is in contact with the silicon in the contact; subsequent exposure to air allows a relatively large amount of oxygen and nitrogen to enter the titanium nitride. A rapid thermal anneal (RTA) both causes silicidation at the contact location and also results in the oxygen and nitrogen being gettered to what was previously the titanium/titanium nitride interface, where the oxygen and nitrogen react with the titanium metal and nitrogen in the atmosphere to form titanium oxynitride. The low density titanium nitride also densifies during the RTA. Alternative embodiments are also disclosed in which the silicide is formed first, prior to the formation of additional titanium oxynitride by air exposure and RTA, or by sputter deposition. Each of these processes produces a high-quality barrier contact structure overlying a silicide film, where the barrier structure includes titanium oxynitride and titanium nitride.
    • 在集成电路中形成具有阻挡层的铝 - 硅接触的方法被公开。 通过在接触底部的暴露的硅处形成的硅化物膜附近提供氧氮化钛层来增强阻挡层。 氮氧化钛可以通过在与接触中的硅接触的钛金属层上沉积低密度氮化钛膜而形成; 随后的空气暴露使得相对较大量的氧和氮进入氮化钛。 快速热退火(RTA)都在接触位置处引起硅化,并且还导致氧和氮被吸收到先前的钛/氮化钛界面,其中氧和氮与大气中的钛金属和氮反应 以形成氮氧化钛。 低密度钛氮化物也在RTA期间致密化。 还公开了另外的实施方案,其中在通过空气暴露和RTA形成额外的氮氧化钛之前,或通过溅射沉积,首先形成硅化物。 这些过程中的每一个产生覆盖硅化物膜的高质量的阻挡接触结构,其中阻挡结构包括氧氮化钛和氮化钛。