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1. 发明申请

US20060205974A1 Processes for producing aromatic dicarboxylic acids 审中-公开
标题翻译：制备芳族二羧酸的方法
公开(公告)号：US20060205974A1
公开(公告)日：2006-09-14
申请号：US11075008
申请日：2005-03-08
申请人： Gino Lavoie , Robert Hembre , Charles Sumner , Joseph Bays , Daniel Compton , Brent Tennant , Bryan Davenport , David Lange , Thomas Floyd , Stephan Schunk , Oliver Busch
发明人： Gino Lavoie , Robert Hembre , Charles Sumner , Joseph Bays , Daniel Compton , Brent Tennant , Bryan Davenport , David Lange , Thomas Floyd , Stephan Schunk , Oliver Busch
IPC分类号： C07C51/16 , C07C51/255
CPC分类号： C07C51/265 , C07C63/26 , C07C63/24
摘要： Processes for the liquid phase oxidation of one or more of a para- or a meta-substituted dialkyl aromatic compound are disclosed, the processes including a step of combining in a reaction medium the one or more para- or meta-substituted dialkyl aromatic compound, a solvent mixture comprising water and a saturated organic acid having from 2-4 carbon atoms, and an oxygen-containing gas, at a temperature from about 130° C. to about 180° C., in the presence of a catalyst composition comprising cobalt, manganese, bismuth, and bromine. The processes produce the corresponding aromatic dicarboxylic acid product with improved conversion, while reducing the formation of carbon oxides.
摘要翻译：公开了一种或多种对位或间位取代的二烷基芳族化合物的液相氧化方法，所述方法包括在反应介质中将一种或多种对位或间位取代的二烷基芳族化合物，包含水和具有2-4个碳原子的饱和有机酸和含氧气体的溶剂混合物在约130℃至约180℃的温度下，在催化剂组合物存在下，包含钴，锰，铋和溴。该方法产生具有改进转化率的相应芳族二羧酸产物，同时减少碳氧化物的形成。

2. 发明申请

US20060205977A1 Processes for producing terephthalic acid 审中-公开
标题翻译：生产对苯二甲酸的方法
公开(公告)号：US20060205977A1
公开(公告)日：2006-09-14
申请号：US11214406
申请日：2005-08-29
申请人： Charles Sumner , Robert Hembre , David Lange , Gino Lavoie , Brent Tennant , Thomas Floyd , Bryan Davenport , Daniel Compton , Joseph Bays
发明人： Charles Sumner , Robert Hembre , David Lange , Gino Lavoie , Brent Tennant , Thomas Floyd , Bryan Davenport , Daniel Compton , Joseph Bays
IPC分类号： C07C51/16 , C07C51/255
CPC分类号： C07C51/265 , C07C63/26
摘要： Processes for producing terephthalic acid are disclosed, the processes comprising combining in a reaction medium p-xylene, a solvent comprising water and one or more saturated organic acids having from 2-4 carbon atoms, and an oxygen-containing gas, at a temperature from about 135° C. to about 165° C., in the presence of a catalyst composition comprising cobalt atoms and manganese atoms, with bromine atoms provided as a promoter. The amount of cobalt used may be from about 1,800 ppm to about 6,000 ppm, with respect to the total weight of the liquid in the reaction medium, and the weight ratio of cobalt to manganese may be from about 40 to about 400. The processes according to the invention produce terephthalic acid as a precipitated reaction product, with typically no more than about 10 ppm 2,6-dicarboxyfluorenone produced, with respect to the weight of the terephthalic acid produced, or no more than about 20 ppm 2,6-dicarboxyfluorenone, with respect to the total weight of the reaction medium, per batch or upon one pass through a reactor. The terephthalic acid so produced may be further purified by one or more additional oxidation reactions, without the need for expensive hydrogenation purification processes.
摘要翻译：公开了制备对苯二甲酸的方法，该方法包括在反应介质中混合对二甲苯，包含水和一种或多种具有2-4个碳原子的饱和有机酸的溶剂和含氧气体，约135℃至约165℃，在包含钴原子和锰原子的催化剂组合物存在下，提供溴原子作为助催化剂。相对于反应介质中的液体的总重量，所使用的钴的量可以为约1,800ppm至约6,000ppm，并且钴与锰的重量比可以为约40至约400.根据本发明产生对苯二甲酸作为沉淀反应产物，相对于所生产的对苯二甲酸的重量，通常不超过约10ppm的2,6-二羧基芴酮，或不超过约20ppm的2,6-二羧基芴酮，相对于反应介质的总重量，每批次或一次通过反应器。如此生产的对苯二甲酸可以通过一个或多个另外的氧化反应进一步纯化，而不需要昂贵的氢化纯化方法。

3. 发明申请

US20060205975A1 Processes for producing aromatic dicarboxylic acids 有权
公开(公告)号：US20060205975A1
公开(公告)日：2006-09-14
申请号：US11075009
申请日：2005-03-08
申请人： Gino Lavoie , Robert Hembre , Charles Sumner , Joseph Bays , Daniel Compton , Brent Tennant , Bryan Davenport , David Lange , Thomas Floyd
发明人： Gino Lavoie , Robert Hembre , Charles Sumner , Joseph Bays , Daniel Compton , Brent Tennant , Bryan Davenport , David Lange , Thomas Floyd
IPC分类号： C07C51/16 , C07C51/255
CPC分类号： C07C51/265 , C07C63/26 , C07C63/15 , C07C63/16 , C07C63/24
摘要： Processes for producing aromatic dicarboxylic acids are disclosed, the processes including a step of combining in a reaction medium a dialkyl aromatic, a solvent comprising water and a saturated organic acid having from 2-4 carbon atoms, and an oxygen-containing gas, at a temperature from about 125° C. to about 155° C., in the presence of a catalyst composition comprising cobalt, manganese, zirconium, and bromine, wherein the weight ratio of cobalt to manganese in the reaction mixture is from about 10 to about 400. The processes provide improved conversion, while reducing the formation of carbon oxides and other by-products.

4. 发明申请

US20060030742A1 Process for alpha,beta-dihydroxyalkenes and derivatives 失效
标题翻译： α，β-二羟基烯醇和衍生物的方法
公开(公告)号：US20060030742A1
公开(公告)日：2006-02-09
申请号：US11204786
申请日：2005-08-16
申请人： Robert Hembre , Jonathan Penney
发明人： Robert Hembre , Jonathan Penney
IPC分类号： C07C33/02
CPC分类号： C07D301/14 , C07B2200/07 , C07B2200/09 , C07C29/172 , C07C29/44 , C07C31/20 , C07C33/025 , C07C31/22 , C07C31/24
摘要： Disclosed is a process wherein a first olefin selected from certain α,β-dihydroxyalkenes and 4-(alkenyl)ethylenecarbonates is reacted with a second olefin reactant to produce an olefin metathesis product. When the first olefin reactant is an optically enriched or enantiomerically pure α,β-dihydroxyalkene, cross metathesis reactions produce products possessing the same optical purity. The α,β-dihydroxyalkenes and the 4-(alkenyl)ethylene carbonates may be converted to hydrogenated products, and the 4-(alkenyl)ethylenecarbonates may be decarboxylated to provide the corresponding epoxides. The products of the disclosure may be used as monomers for the preparation of specialty polyesters and as intermediates in the manufacture pharmaceuticals and other chemicals.
摘要翻译：公开了一种方法，其中选自某种α，β-二羟基烯烃和4-（链烯基）亚乙基碳酸酯的第一种烯烃与第二种烯烃反应物反应以产生烯烃复分解产物。当第一种烯烃反应物是光学富集或对映体纯的α，β-二羟基亚油，交叉复分解反应产生具有相同光学纯度的产物。 α，β-二羟基烯烃和4-（烯基）亚乙基碳酸酯可以转化为氢化产物，并且4-（烯基）亚乙基碳酸酯可以脱羧以提供相应的环氧化物。本公开的产品可以用作制备特种聚酯的单体和作为制造药物和其它化学品的中间体。

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