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1. 发明授权

US07754491B2 Sensor for measuring syngas ratios under high temperature and pressure conditions 有权
标题翻译：用于在高温和高压条件下测量合成气比的传感器
公开(公告)号：US07754491B2
公开(公告)日：2010-07-13
申请号：US11299030
申请日：2005-12-09
申请人： Chan Seung Park , Colin E. Hackett , Nora A. Hackett, legal representative , Joseph M. Norbeck
发明人： Chan Seung Park , Colin E. Hackett , Joseph M. Norbeck
IPC分类号： G01N33/00 , G01N33/22 , G01N31/12 , G01N25/18
CPC分类号： G01N27/18 , G01N33/0013 , G01N33/004 , Y10T436/204998 , Y10T436/205831 , Y10T436/208339 , Y10T436/22
摘要： An assembly and method for gas analysis. The assembly comprises a catalyst compartment for catalytically reacting a component of a gas sample, producing one or more gas species as products. A product compartment receives the gas species, and a sensing element within the compartment senses the amount of one or more of the gas species. This amount is compared to the amount of the same gas species present in a reference compartment containing a non-catalyzed gas sample, providing the amount of the gas species produced by catalysis. Using this value, the content of the gas component in the gas sample is calculated based upon the stoichiometry of the catalyzed reaction. In preferred embodiments, the gas for analysis is a process gas for fuel production, and the catalyst is a high temperature shift catalyst that catalyzes the reaction of carbon monoxide and water into hydrogen and carbon dioxide.
摘要翻译：气体分析装配和方法。组件包括用于催化气体样品组分的催化剂室，产生一种或多种气体物质作为产物。产品隔室接收气体种类，并且隔室内的感测元件感测一种或多种气体种类的量。将该量与含有非催化气体样品的参考室中存在的相同气体物质的量进行比较，提供通过催化产生的气体种类的量。使用该值，基于催化反应的化学计量来计算气体样品中气体组分的含量。在优选实施例中，用于分析的气体是用于燃料生产的工艺气体，并且催化剂是催化一氧化碳和水与氢气和二氧化碳的反应的高温变换催化剂。

2. 发明授权

US08435448B2 Sensor for measuring syngas ratio in the high temperature and pressure condition 失效
标题翻译：用于在高温和高压条件下测量合成气比的传感器
公开(公告)号：US08435448B2
公开(公告)日：2013-05-07
申请号：US12756407
申请日：2010-04-08
申请人： Chan Seung Park , Colin E. Hackett , Joseph M. Norbeck
发明人： Chan Seung Park , Colin E. Hackett , Joseph M. Norbeck
IPC分类号： G01N31/10 , G01N27/16 , G01N33/00
CPC分类号： G01N27/18 , G01N33/0013 , G01N33/004 , Y10T436/204998 , Y10T436/205831 , Y10T436/208339 , Y10T436/22
摘要： An assembly and method for gas analysis. The assembly comprises a catalyst compartment for catalytically reacting a component of a gas sample, producing one or more gas species as products. A product compartment receives the gas species, and a sensing element within the compartment senses the amount of one or more of the gas species. This amount is compared to the amount of the same gas species present in a reference compartment containing a non-catalyzed gas sample, providing the amount of the gas species produced by catalysis. Using this value, the content of the gas component in the gas sample is calculated based upon the stoichiometry of the catalyzed reaction. In preferred embodiments, the gas for analysis is a process gas for fuel production, and the catalyst is a high temperature shift catalyst that catalyzes the reaction of carbon monoxide and water into hydrogen and carbon dioxide.
摘要翻译：气体分析装配和方法。组件包括用于催化气体样品组分的催化剂室，产生一种或多种气体物质作为产物。产品隔室接收气体种类，并且隔室内的感测元件感测一种或多种气体种类的量。将该量与含有非催化气体样品的参考室中存在的相同气体物质的量进行比较，提供通过催化产生的气体种类的量。使用该值，基于催化反应的化学计量来计算气体样品中气体组分的含量。在优选实施例中，用于分析的气体是用于燃料生产的工艺气体，并且催化剂是催化一氧化碳和水与氢气和二氧化碳的反应的高温变换催化剂。

3. 发明申请

US20100197035A1 Sensor for measuring syngas ratio in the high temperature and pressure condition 失效
标题翻译：用于在高温和高压条件下测量合成气比的传感器
公开(公告)号：US20100197035A1
公开(公告)日：2010-08-05
申请号：US12756407
申请日：2010-04-08
申请人： Chan Seung Park , Colin E. Hackett , Nora A. Hackett , Joseph M. Norbeck
发明人： Chan Seung Park , Colin E. Hackett , Nora A. Hackett , Joseph M. Norbeck
IPC分类号： G01N33/00 , G01N33/22 , G01N27/16 , G01N27/10 , G01N27/07
CPC分类号： G01N27/18 , G01N33/0013 , G01N33/004 , Y10T436/204998 , Y10T436/205831 , Y10T436/208339 , Y10T436/22
摘要： An assembly and method for gas analysis. The assembly comprises a catalyst compartment for catalytically reacting a component of a gas sample, producing one or more gas species as products. A product compartment receives the gas species, and a sensing element within the compartment senses the amount of one or more of the gas species. This amount is compared to the amount of the same gas species present in a reference compartment containing a non-catalyzed gas sample, providing the amount of the gas species produced by catalysis. Using this value, the content of the gas component in the gas sample is calculated based upon the stoichiometry of the catalyzed reaction. In preferred embodiments, the gas for analysis is a process gas for fuel production, and the catalyst is a high temperature shift catalyst that catalyzes the reaction of carbon monoxide and water into hydrogen and carbon dioxide.
摘要翻译：气体分析装配和方法。组件包括用于催化气体样品组分的催化剂室，产生一种或多种气体物质作为产物。产品隔室接收气体种类，并且隔室内的感测元件感测一种或多种气体种类的量。将该量与含有非催化气体样品的参考室中存在的相同气体物质的量进行比较，提供通过催化产生的气体种类的量。使用该值，基于催化反应的化学计量来计算气体样品中气体组分的含量。在优选实施例中，用于分析的气体是用于燃料生产的工艺气体，并且催化剂是催化一氧化碳和水与氢气和二氧化碳的反应的高温变换催化剂。

4. 再颁专利

USRE40419E1 Production of synthetic transportation fuels from carbonaceous material using self-sustained hydro-gasification 有权
标题翻译：使用自持式加氢气化从碳质材料生产合成运输燃料
公开(公告)号：USRE40419E1
公开(公告)日：2008-07-01
申请号：US11805576
申请日：2003-02-04
申请人： Joseph M. Norbeck , Colin E. Hackett
发明人： Joseph M. Norbeck , Colin E. Hackett
IPC分类号： C07C27/00 , C01B31/18 , C01B3/24 , C01B3/32
CPC分类号： C01B3/34 , C01B2203/00 , C01B2203/0233 , C01B2203/04 , C01B2203/0495 , C01B2203/06 , C01B2203/062 , C01B2203/0827 , C01B2203/0833 , C01B2203/0838 , C01B2203/0883 , C01B2203/0894 , C01B2203/1205 , C01B2203/1258 , C01B2203/1276 , C01B2203/146 , C01B2203/148 , C01B2203/84 , C10G1/002 , C10G2/30 , C10G2/32 , C10J3/00 , C10J3/54 , C10J3/66 , C10J3/721 , C10J3/723 , C10J2300/06 , C10J2300/0903 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/092 , C10J2300/093 , C10J2300/0943 , C10J2300/0946 , C10J2300/0966 , C10J2300/0973 , C10J2300/0976 , C10J2300/0983 , C10J2300/1253 , C10J2300/165 , C10J2300/1659 , C10J2300/1671 , C10J2300/1675 , C10J2300/1693 , C10J2300/1807 , C10J2300/1853 , C10J2300/1884 , C10J2300/1892 , Y02E20/16 , Y02E50/32 , Y02P20/145 , Y02P20/52
摘要： A process and apparatus for producing a synthesis gas for use as a gaseous fuel or as feed into a Fischer-Tropsch reactor to produce a liquid fuel in a substantially self-sustaining process. A slurry of particles of carbonaceous material in water, and hydrogen from an internal source, are fed into a hydro-gasification reactor under conditions whereby methane rich producer gases are generated and fed into a steam pyrolytic reformer under conditions whereby synthesis gas comprising hydrogen and carbon monoxide are generated. A portion of the hydrogen generated by the steam pyrolytic reformer is fed through a hydrogen purification filter into the hydro-gasification reactor, the hydrogen therefrom constituting the hydrogen from an internal source. The remaining synthesis gas generated by the steam pyrolytic reformer is either used as fuel for a gaseous fueled engine to produce electricity and/or process heat or is fed into a Fischer-Tropsch or similar reactor under conditions whereby a liquid fuel is produced.
摘要翻译：用于生产用作气体燃料的合成气或作为进料到费 - 托反应器以在基本上自持的方法中产生液体燃料的方法和装置。将碳质材料在水中的浆料和来自内部源的氢气的浆料在产生富含甲烷的生产气体并在蒸气热解重整机中供入氢气和碳的合成气的条件下进料到加氢气化反应器中产生一氧化碳。由蒸汽热解重整器产生的一部分氢气通过氢气净化过滤器进料到加氢气化反应器中，其中的氢气从内部源构成氢气。由蒸气热解重整器产生的剩余合成气既可用作气体燃料发动机的燃料，以产生电力和/或加热功能，或者在产生液体燃料的条件下进入费 - 托或类似反应器。

5. 发明授权

US07500997B2 Steam pyrolysis as a process to enhance the hydro-gasification of carbonaceous materials 有权
标题翻译：蒸汽热解作为加强碳质材料加氢气化的过程
公开(公告)号：US07500997B2
公开(公告)日：2009-03-10
申请号：US10911348
申请日：2004-08-03
申请人： Joseph M. Norbeck , Colin E. Hackett
发明人： Joseph M. Norbeck , Colin E. Hackett
IPC分类号： C10L3/00 , C10J3/54
CPC分类号： C01B3/34 , C01B2203/00 , C01B2203/0233 , C01B2203/04 , C01B2203/0495 , C01B2203/06 , C01B2203/062 , C01B2203/0827 , C01B2203/0833 , C01B2203/0838 , C01B2203/0883 , C01B2203/0894 , C01B2203/1205 , C01B2203/1258 , C01B2203/1276 , C01B2203/146 , C01B2203/148 , C01B2203/84 , C10G1/002 , C10G2/30 , C10G2/32 , C10G2300/1003 , C10G2300/1011 , C10G2300/807 , C10G2400/04 , C10J3/00 , C10J3/54 , C10J3/66 , C10J3/721 , C10J3/723 , C10J2300/06 , C10J2300/0903 , C10J2300/0906 , C10J2300/0916 , C10J2300/092 , C10J2300/093 , C10J2300/0946 , C10J2300/0966 , C10J2300/0973 , C10J2300/0983 , C10J2300/165 , C10J2300/1659 , C10J2300/1671 , C10J2300/1675 , C10J2300/1693 , C10J2300/1807 , C10J2300/1853 , C10J2300/1884 , C10J2300/1892 , Y02E20/16 , Y02E50/32 , Y02E60/324 , Y02P20/145 , Y02P20/582 , Y02P30/20 , Y02P30/30
摘要： A process and apparatus for producing a synthesis gas for use as a gaseous fuel or as feed into a Fischer-Tropsch reactor to produce a liquid fuel in a substantially self-sustaining process. In one embodiment, a slurry of carbonaceous material in water, and hydrogen from an internal source, are fed into a hydro-gasification reactor to generate methane rich producer gases which are fed into a steam pyrolytic reformer to generate synthesis gas comprising hydrogen and carbon monoxide. A portion of the hydrogen is used as the internal hydrogen source. The remaining synthesis gas is either used as fuel to produce electricity and/or process heat or is fed into a Fischer-Tropsch reactor to produce liquid fuel. In another embodiment of the invention, carbonaceous material can be heated simultaneously in the presence of both hydrogen and steam to undergo steam pyrolysis and hydro-gasification in a single step.
摘要翻译：用于生产用作气体燃料的合成气或作为进料到费 - 托反应器以在基本上自持的方法中产生液体燃料的方法和装置。在一个实施方案中，将碳质材料在水中的浆料和来自内部源的氢气进料到加氢气化反应器中以产生富含甲烷的生产气体，其被输送到蒸气热解重整器中以产生包含氢气和一氧化碳的合成气。一部分氢被用作内部氢源。剩余的合成气被用作燃料以产生电和/或加工热，或者被供给到费 - 托反应器以产生液体燃料。在本发明的另一个实施方案中，碳质材料可以在氢和蒸汽的存在下同时加热，以在一个步骤中进行蒸气热解和加氢气化。

6. 发明授权

US07208530B2 Production of synthetic transportation fuels from carbonaceous material using self-sustained hydro-gasification 有权
标题翻译：使用自持式加氢气化从碳质材料生产合成运输燃料
公开(公告)号：US07208530B2
公开(公告)日：2007-04-24
申请号：US10503435
申请日：2003-02-04
申请人： Joseph N. Norbeck , Colin E. Hackett , James E. Heumann , Uy Q. Ngo , Nguyen T. Tran , Bilge Yilmaz
发明人： Joseph N. Norbeck , Colin E. Hackett , James E. Heumann , Uy Q. Ngo , Nguyen T. Tran , Bilge Yilmaz
IPC分类号： C07C27/00 , C01B31/18 , C01B3/24 , C01B3/32
CPC分类号： C01B3/34 , C01B2203/00 , C01B2203/0233 , C01B2203/04 , C01B2203/0495 , C01B2203/06 , C01B2203/062 , C01B2203/0827 , C01B2203/0833 , C01B2203/0838 , C01B2203/0883 , C01B2203/0894 , C01B2203/1205 , C01B2203/1258 , C01B2203/1276 , C01B2203/146 , C01B2203/148 , C01B2203/84 , C10G1/002 , C10G2/30 , C10G2/32 , C10J3/00 , C10J3/54 , C10J3/66 , C10J3/721 , C10J3/723 , C10J2300/06 , C10J2300/0903 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/092 , C10J2300/093 , C10J2300/0943 , C10J2300/0946 , C10J2300/0966 , C10J2300/0973 , C10J2300/0976 , C10J2300/0983 , C10J2300/1253 , C10J2300/165 , C10J2300/1659 , C10J2300/1671 , C10J2300/1675 , C10J2300/1693 , C10J2300/1807 , C10J2300/1853 , C10J2300/1884 , C10J2300/1892 , Y02E20/16 , Y02E50/32 , Y02P20/145 , Y02P20/52
摘要： A process and apparatus for producing a synthesis gas for use as a gaseous fuel or as feed into a Fischer-Tropsch reactor to produce a liquid fuel in a substantially self-sustaining process. A slurry of particles of carbonaceous material in water, and hydrogen from an internal source, are fed into a hydro-gasification reactor under conditions whereby methane rich producer gases are generated and fed into a steam pyrolytic reformer under conditions whereby synthesis gas comprising hydrogen and carbon monoxide are generated. A portion of the hydrogen generated by the steam pyrolytic reformer is fed through a hydrogen purification filter into the hydro-gasification reactor, the hydrogen therefrom constituting the hydrogen from an internal source. The remaining synthesis gas generated by the steam pyrolytic reformer is either used as fuel for a gaseous fueled engine to produce electricity and/or process heat or is fed into a Fischer-Tropsch or similar reactor under conditions whereby a liquid fuel is produced.
摘要翻译：用于生产用作气体燃料的合成气或作为进料到费 - 托反应器以在基本上自持的方法中产生液体燃料的方法和装置。将碳质材料在水中的浆料和来自内部源的氢气的浆料在产生富含甲烷的生产气体并在蒸气热解重整机中供入氢气和碳的合成气的条件下进料到加氢气化反应器中产生一氧化碳。由蒸汽热解重整器产生的一部分氢气通过氢气净化过滤器进料到加氢气化反应器中，其中的氢气从内部源构成氢气。由蒸气热解重整器产生的剩余合成气既可用作气体燃料发动机的燃料，以产生电力和/或加热功能，或者在产生液体燃料的条件下进入费 - 托或类似反应器。

7. 发明授权

US07398681B2 Gas sensor based on dynamic thermal conductivity and molecular velocity 失效
标题翻译：基于动态热导率和分子速度的气体传感器
公开(公告)号：US07398681B2
公开(公告)日：2008-07-15
申请号：US11234511
申请日：2005-09-22
申请人： Joseph N. Norbeck , Chan Seung Park , Michael Mc Clanahan , Nora Hackett, legal representative
发明人： Colin E. Hackett
IPC分类号： G01F1/68
CPC分类号： G01P5/12 , G01N1/24 , G01N25/18 , G01N33/005
摘要： An apparatus and method for gas detection. The apparatus comprises a) a sample chamber for holding a gas sample, b) a sealable vacuum port in fluid communication with the sample chamber, for evacuating the sample chamber, c) a sealable inlet port in fluid communication with the sample chamber, for introducing the gas sample into the evacuated sample chamber, and d) a thermal conductivity sensing element at least partly disposed within the sample chamber, for measuring the thermal conductivity of the gas sample. A gas sample released into the evacuated sample chamber requires a time interval to contact the thermal conductivity sensing element. The time interval is a measure of gas speed. Thermal conductivity and temperature of the gas sample are measured following determination of gas speed. By determining three parameters in a single sample of gas, different gas mixtures having similar thermal conductivities can be distinguished.
摘要翻译：一种用于气体检测的装置和方法。该设备包括：a）用于保持气体样品的样品室，b）与样品室流体连通的可密封真空端口，用于抽空样品室; c）与样品室流体连通的可密封入口，用于引入气体样品进入抽真空的样品室，以及d）至少部分地设置在样品室内的热传感元件，用于测量气体样品的热导率。释放到抽空样品室中的气体样品需要与热敏感测元件接触的时间间隔。时间间隔是气体速度的量度。在确定气体速度后测量气体样品的导热系数和温度。通过确定单个气体样品中的三个参数，可以区分具有相似热导率的不同气体混合物。

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